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OKAMOTO YasunaoResearch Center for Membrane and Film TechnologyAssistant Professor
Researcher basic information
■ Research Keyword■ Research Areas
Research activity information
■ Award- May 2019 粉体工学会2019年度春季研究発表会, ベストプレゼンテーション賞, リキッドマーブルを用いたマイクロ空間における BZ 反応の挙動
- Nov. 2018 13th Japan-Korea Symposium on Materials & Interfaces, Poster Award, Quantification of mixing state in solutions with chemical waves induced by Belousov-Zhabotinsky reaction
- Nov. 2016 12th Japan-Korea Symposium on Materials & Interfaces, Poster Award, Effects of mixing in solutions on chemical waves formed by Belousov-Zhabotinsky reaction
- Elsevier BV, Jan. 2025, Journal of Membrane Science, 713, 123309 - 123309[Refereed]Scientific journal
- Elsevier BV, Jan. 2025, Separation and Purification Technology, 352, 128159 - 128159[Refereed]Scientific journal
- Abstract Covalent organic networks (CONs) are considered ideal for precise molecular separation compared with traditional polymer membranes because their pores have a sharp molecular weight cut‐off and a robust structure. However, challenges remain with regard to tuning pores as a prerequisite for facile membrane fabrication to a defect‐free layer. Herein, a highly conjugated amino‐porphyrin is used and exploited its tunable stacking behavior to fabricate porphyrin‐based polyamide CONs with ordered structures through interfacial polymerization with acyl chlorides. Controlling the self‐aggregation behavior of the porphyrin and the conformation of the acyl chlorides can create different covalent networks. Acid‐triggered porphyrin protonation offsets stacking to reduce the pore in the network from mesopore to micropore, enabling selective molecule transport. Furthermore, different acyl chloride ligands are used to control the interlayer bonding in CONs. Accordingly, the tailored pore diameters (0.48–0.78 nm) are confirmed by the molecule rejections with performance stability over 25 days of operation, as well as under various conditions. This study leverages porphyrin chemistry and interfacial polymerization to fabricate a defect‐free CON layer with a significantly lower molecular weight cut‐off (< 330 Da) than previously reported porphyrin‐based membranes (>800 Da). This will pave the way for the development of ideal topological membranes.Wiley, Nov. 2024, SmallScientific journal
- Elsevier BV, Oct. 2024, Journal of Membrane Science, 710, 123115 - 123115[Refereed]Scientific journal
- Jun. 2024, Colloids and Surfaces A, 698, 134580, English, International magazine[Refereed]Scientific journal
- Jun. 2024, Separation and Purification Technology, 337[Refereed]Scientific journal
- MDPI AG, Mar. 2024, Processes, 12(3) (3), 514 - 514[Refereed]Scientific journal
- Nov. 2023, Industrial and Engineering Chemistry Research, 62(46) (46), 19845 - 19854[Refereed]Scientific journal
- Oct. 2023, Separation and Purification Technology, 322[Refereed]Scientific journal
- Jul. 2023, Scientific Reports, 13(1) (1), 12377 - 12377, English, International magazine[Refereed]Scientific journal
- Jun. 2023, Separation and Purification Technology, 315[Refereed]Scientific journal
- Apr. 2023, Small (Weinheim an der Bergstrasse, Germany), 19(33) (33), e2300672, English, International magazine[Refereed]Scientific journal
- Springer Science and Business Media LLC, Aug. 2022, Scientific Reports, 12(1) (1), 14141 - 14141, English, International magazine[Refereed]Scientific journal
- American Chemical Society (ACS), Jun. 2022, Biomacromolecules, 23(7) (7), 2941 - 2950, English, International magazine[Refereed]Scientific journal
- Lead, Frontiers Media SA, May 2022, Frontiers in Physics, 10(895824) (895824), 1 - 10, English[Refereed][Invited]Scientific journal
- The Society of Powder Technology, Japan, Mar. 2022, Journal of the Society of Powder Technology, Japan, 59(3) (3), 108 - 114[Refereed]Scientific journal
- Elsevier BV, Oct. 2021, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 627, 127197 - 127197[Refereed]Scientific journal
- Lead, Sep. 2021, JSST2021 The 40th JSST Annual International Conference on Simulation Technology Conference ProceedingsParticle layer effect of liquid marble on Belouzov–Zhabotinsky reaction[Refereed]International conference proceedings
- Frontiers Media SA, Jul. 2021, Frontiers in Chemistry, 9, 708633 - 708633, English, International magazine[Refereed]Scientific journal
- Springer Science and Business Media LLC, Jun. 2021, Scientific Reports, 11(1) (1), 11983 - 11983, English, International magazine[Refereed]Scientific journal
- The Chemical Society of Japan, Jan. 2021, Chemistry Letters, 50(4) (4), 661 - 663[Refereed]Scientific journal
- Lead, The Society of Powder Technology, Japan, Feb. 2020, Journal of the Society of Powder Technology, Japan, 57(2) (2), 74 - 79[Refereed][Invited]Scientific journal
- Lead, American Chemical Society (ACS), Nov. 2019, Langmuir, 35(44) (44), 14266 - 14271, English, International magazine[Refereed]Scientific journal
- Aug. 2019, Chemistry Letters, 48(8) (8), 847 - 850, English[Refereed]Scientific journal
- Lead, Hosokawa Powder Technology Foundation, 2018, Hosokawa Powder Technology Foundation ANNUAL REPORT, 26(0) (0), 161 - 165[Refereed]Scientific journal
- Joint work, The Royal Society of Chemistry, Jul. 2022, ISBN: 9781839162770Chemoresponsive Materials: Smart Materials for Chemical and Biological Stimulation: Edition 2
- 日本物理学会 第77回年次大会, Mar. 2022垂直振動を与えた水面上の歯車の運動
- 化学工学会第87年会, Mar. 2022BZ 反応による 一次元混合状態の推定
- 化学工学会関西大会2021, Dec. 2021Pt粒子の集団運動によって発現する物質の能動輸送
- 第31回 非線形反応と協同現象研究会, Dec. 2021ガラス基板上での自走性油水液滴の二次元的運動における履歴特性
- 化学工学会 関西支部大会 2021, Dec. 2021拡散混合を用いた様々な金属ナノ粒子の合成機構の解明
- JSST 2021 The 40th JSST Annual International Conference on Simulation Technology, Sep. 2021Particle layer effect of liquid marble on Belouzov–Zhabotinsky reactionOral presentation
- 化学工学会 第52回秋季大会, Sep. 2021上下振動を与えた粒子層上の歯車の回転運動
- 2021年度粉体工学会 春期研究発表会, Jun. 2021一方拡散を用いた金属微粒子の形成機構の解明Oral presentation
- 化学工学会 第86年会, Mar. 2021非線形同期を利用した吸脱着過程と巨視的運動状態の相互作用に関する研究
- 第23回化学工学会学生発表会, Mar. 2021様々な有機燃料下における自走性微粒子の集団運動
- 第2回 非線形科学オンライン研究会(若手の会)― 非平衡下で時空間発展する現象 ―, Jul. 2020pH振動反応下におけるpH応答性油滴の自律運動
■ Research Themes
- Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Research Activity Start-up, Doshisha University, 11 Sep. 2020 - 31 Mar. 2022Study of autonomous movement of pH-responsive oil droplet on pH oscillationThe autonomous moving system and its mechanism has been studied with pH-responsive dropllet (surfactant) on pH oscillation reaction. One system represents the autonomous and sustainable movement, and this can be caused by the surface surfactant gradient due to the limitation of the space and the solubility of the surfactant. Unlike this droplet, another droplet containing another surfactant on pH gradient travels autonomously along the boundary of pH.
- 公財)ホソカワ粉体工学振興財団, 研究者育成, 同志社大学, Apr. 2018 - Mar. 2019pH振動反応を用いたアクティブマターの創生と能動輸 送系の構築