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検索詳細MAI Zhaohuan先端膜工学研究センター准教授
研究活動情報
■ 受賞- 2025年08月 The 15th conference of the Aseanian Membrane Society (AMS15), AMS15 Best Oral Presentation Award
- Elsevier BV, 2026年09月, Desalination, 634, 120311 - 120311研究論文(学術雑誌)
- Elsevier BV, 2026年05月, Journal of Membrane Science, 749, 125456 - 125456研究論文(学術雑誌)
- 2026年, Journal of Membrane Science, 738研究論文(学術雑誌)
- 2026年, Journal of Membrane Science, 739研究論文(学術雑誌)
- 2025年12月, Journal of the American Chemical Society, 英語[査読有り]研究論文(学術雑誌)
- 2025年08月, Small, 英語[査読有り]研究論文(学術雑誌)
- Abstract Pliable integration of metal‐organic frameworks (MOFs) with polymers enables precise separations, advancing circular economy initiatives. Maximizing the pore functionality of MOFs is critical for rapid ion sieving but necessitates a uniform and stable distribution to expose their interpenetrated nanochannels. Here, this work reports a controlled approach for integrating an ultrathin Zr‐MOF monolayer with a flexible polyamide film using a coupled cathode electrophoretic deposition and interfacial polymerization (CED‐IP) strategy. By tuning the electric field intensity, this work achieves uniform monolayer coverage of diverse MOFs (UiO‐66, MOF‐808, and NU‐1000) with varying pore apertures on porous supports, followed by the formation of a thin‐film nanocomposite (TFN) configuration via confined IP. The exposed functional groups within these MOF pores enhance interaction with aqueous‐phase diamines, which polymerize with acyl chlorides, resulting in TFN membranes with a moderately reduced crosslinking degree, improved hydrophilicity and enhanced surface electronegativity. Experimental and simulation data reveal that the large‐pore NU‐1000 offers the lowest transport resistance in polyamide membranes, leading to an exceptional 186.3% increase in water permeance compared to control membranes. The resulting Zr‐MOF‐integrated polyamide membrane demonstrates outstanding selectivity for WO42−/Cl− (50.6) and MoO42−/Cl− (53.7), outperforming most MOF‐based nanofiltration membranes. These results underscore the potential of a mesoporous MOF‐monolayer based TFN membranes for low‐energy extraction of critical rare metals.Wiley, 2025年06月, Advanced Functional Materials, 英語[査読有り]研究論文(学術雑誌)
- 2025年04月, Water Research, 274[査読有り]研究論文(学術雑誌)
- 2025年04月, Desalination, 601[査読有り]研究論文(学術雑誌)
- Abstract The development of advanced membranes with switchable superwettability has attracted considerable attention for the efficient treatment of oily wastewater. However, challenges persist in designing and fabricating such membranes through straightforward methods. In this study, a novel strategy is presented to design switchable superwettable membranes based on micro/nano‐structured porous surfaces and surface chemical composition reorganization. A commercial amphiphilic polymer, polyamide‐imide (Torlon), is fabricated into a porous symmetric membrane with a hierarchical surface structure using a one‐step non‐solvent‐induced phase separation method. By leveraging the surface reorganization capability of amphiphilic polymers and the hierarchically porous structure, the resulting membranes demonstrate exceptional superamphiphilicity in air, underwater superoleophobicity, and underoil superhydrophobicity. These properties enable ultrahigh permeance and separation efficiency for oil‐in‐water, water‐in‐oil, and crude oil/water emulsions through a gravity‐driven process, eliminating the need for external energy. Furthermore, the membranes exhibit excellent antifouling and self‐cleaning performance, maintaining stable operation over multiple cycles. This work provides an innovative and scalable approach to next‐generation switchable superwettable membranes with broad potential applications in oily wastewater treatment and beyond.Wiley, 2025年03月, Advanced Materials[査読有り]研究論文(学術雑誌)
- 2025年02月, Journal of Membrane Science, 715[査読有り]研究論文(学術雑誌)
- 2025年01月, Desalination, 594[査読有り]研究論文(学術雑誌)
- 2025年01月, Desalination, 593[査読有り]研究論文(学術雑誌)
- 2025年01月, Desalination, 593[査読有り]研究論文(学術雑誌)
- 2025年, Advanced Science, 12(23) (23)研究論文(学術雑誌)
- 2025年, Journal of Membrane Science, 736研究論文(学術雑誌)
- 2025年, Advanced Functional Materials[査読有り]研究論文(学術雑誌)
- 2025年01月, Separation and Purification Technology, 352[査読有り]研究論文(学術雑誌)
- Elsevier BV, 2024年12月, Desalination, 592, 118118 - 118118[査読有り]研究論文(学術雑誌)
- Abstract Covalent organic networks (CONs) are considered ideal for precise molecular separation compared with traditional polymer membranes because their pores have a sharp molecular weight cut‐off and a robust structure. However, challenges remain with regard to tuning pores as a prerequisite for facile membrane fabrication to a defect‐free layer. Herein, a highly conjugated amino‐porphyrin is used and exploited its tunable stacking behavior to fabricate porphyrin‐based polyamide CONs with ordered structures through interfacial polymerization with acyl chlorides. Controlling the self‐aggregation behavior of the porphyrin and the conformation of the acyl chlorides can create different covalent networks. Acid‐triggered porphyrin protonation offsets stacking to reduce the pore in the network from mesopore to micropore, enabling selective molecule transport. Furthermore, different acyl chloride ligands are used to control the interlayer bonding in CONs. Accordingly, the tailored pore diameters (0.48–0.78 nm) are confirmed by the molecule rejections with performance stability over 25 days of operation, as well as under various conditions. This study leverages porphyrin chemistry and interfacial polymerization to fabricate a defect‐free CON layer with a significantly lower molecular weight cut‐off (< 330 Da) than previously reported porphyrin‐based membranes (>800 Da). This will pave the way for the development of ideal topological membranes.Wiley, 2024年11月, Small, 英語[査読有り]研究論文(学術雑誌)
- 2024年10月, Process Safety and Environmental Protection, 190, 794 - 820[査読有り]
- 2024年09月, Membranes, 14(9) (9)[査読有り]研究論文(学術雑誌)
- 2024年09月, Journal of Membrane Science, 709[査読有り]研究論文(学術雑誌)
- 2024年08月, Environmental Chemistry Letters, 22(4) (4), 1615 - 1621[査読有り]研究論文(学術雑誌)
- 2024年07月, ACS Applied Materials and Interfaces, 16(29) (29), 38723 - 38732[査読有り]研究論文(学術雑誌)
- 2024年07月, Desalination, 581[査読有り]研究論文(学術雑誌)
- 2024年07月, Journal of Membrane Science, 706[査読有り]研究論文(学術雑誌)
- 2024年05月, Journal of Membrane Science, 702[査読有り]研究論文(学術雑誌)
- 2024年03月, ACS Omega, 9(12) (12), 14187 - 14197[査読有り]研究論文(学術雑誌)
- 2024年, Advanced Functional Materials[査読有り]研究論文(学術雑誌)
- 2024年, Nano Letters, 24(43) (43), 13686 - 13694[査読有り]研究論文(学術雑誌)
- 2024年, Nano Letters, 24(40) (40), 12382 - 12389, 英語, 国際誌[査読有り]研究論文(学術雑誌)
- 2024年, Journal of Membrane Science, 693[査読有り]研究論文(学術雑誌)
- 2024年, Journal of Hazardous Materials, 465[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 682[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 686[査読有り]研究論文(学術雑誌)
- 2023年, Desalination, 566[査読有り]研究論文(学術雑誌)
- 2023年, Water Research, 244[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 688[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Materials Chemistry A, 11(16) (16), 8836 - 8844[査読有り]研究論文(学術雑誌)
- 2023年, Nano Letters, 23(13) (13), 6095 - 6101[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 672[査読有り]研究論文(学術雑誌)
- 2023年, Chemical Engineering Research and Design, 191, 578 - 589[査読有り]研究論文(学術雑誌)
- 2023年, Resources, Conservation and Recycling, 198[査読有り]研究論文(学術雑誌)
- 2023年, Desalination, 565[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 688[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 687[査読有り]研究論文(学術雑誌)
- 2023年, ACS ES and T Engineering, 3(11) (11), 1738 - 1747[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 668[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 670[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 679, 英語[査読有り]研究論文(学術雑誌)
- 2023年, Science Advances, 9(18) (18)[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 675[査読有り]研究論文(学術雑誌)
- 2023年, Journal of Membrane Science, 678[査読有り]研究論文(学術雑誌)
- 2022年04月, Journal of Membrane Science, 647[査読有り]研究論文(学術雑誌)
- 2022年03月, Chemical Engineering Journal, 431[査読有り]研究論文(学術雑誌)
- American Chemical Society ({ACS}), 2022年01月, ACS Applied Materials & Interfaces, 14(2) (2), 3427 - 3436[査読有り]研究論文(学術雑誌)
- 2022年, Chinese Rare Earths, 43(2) (2), 82 - 90[査読有り]研究論文(学術雑誌)
- 2022年, Journal of Membrane Science, 644[査読有り]研究論文(学術雑誌)
- 2021年, Desalination, 501[査読有り]研究論文(学術雑誌)
- 2021年, Chinese Rare Earths, 42(2) (2), 16 - 24[査読有り]研究論文(学術雑誌)
- 2020年, ACS Applied Materials and Interfaces, 12(6) (6), 7539 - 7547[査読有り]研究論文(学術雑誌)
- 2020年, Sustainability (Switzerland), 12(15) (15)[査読有り]研究論文(学術雑誌)
- 2020年, Journal of Materials Chemistry A, 8(6) (6), 3238 - 3245[査読有り]研究論文(学術雑誌)
- 2019年, Abstracts of Papers of the American Chemical SocietyActivity Model of Membrane Transport for Volatile Solutes and Water: Concentration and Pressure Dependent Transport of Trace and High Concentrations研究論文(学術雑誌)
- Royal Society of Chemistry ({RSC}), 2019年, Journal of Materials Chemistry A, 7(34) (34), 20006 - 20012[査読有り]研究論文(学術雑誌)
- 2019年, Desalination, 469[査読有り]研究論文(学術雑誌)
- 2019年, Desalination and Water Treatment, 166, 1 - 8[査読有り]研究論文(学術雑誌)
- 2019年, Journal of Nanoparticle Research, 21(10) (10)[査読有り]研究論文(学術雑誌)
- 2019年, Journal of Membrane Science, 592[査読有り]研究論文(学術雑誌)
- 2019年, Ecotoxicology and Environmental Safety, 171, 460 - 466[査読有り]研究論文(学術雑誌)
- 2017年, International Journal of Hydrogen Energy, 42(38) (38), 24090 - 24098[査読有り]研究論文(学術雑誌)
- 2017年, Journal of Electroanalytical Chemistry, 791, 124 - 130[査読有り]研究論文(学術雑誌)
- 2016年, Journal of Membrane Science, 499, 257 - 268[査読有り]研究論文(学術雑誌)
- 2014年, Journal of Chemical Physics, 140(20) (20)[査読有り]研究論文(学術雑誌)
- 2014年, Journal of Membrane Science, 458, 111 - 119[査読有り]研究論文(学術雑誌)
- 2013年, Research Journal of Chemistry and EnvironmentA Multifactorial Study on Photodegradation of Sulfamethoxazole in Water Induced by Fe (III)-oxalate Complexes研究論文(学術雑誌)
- 2012年, Procedia Engineering, 44, 1751 - 1752[査読有り]研究論文(国際会議プロシーディングス)
- 2012年, Procedia Engineering, 44, 1753 - 1755[査読有り]研究論文(国際会議プロシーディングス)
- 2010年, Research Journal of Chemistry and Environment, 14(1) (1), 5 - 10[査読有り]研究論文(学術雑誌)
- the 15th conference of the Aseanian Membrane Society (AMS15), 2025年08月, 英語Unravelling Membrane Fouling Mechanisms in Reverse Osmosis of Rare Earth Wastewater: A Multiscale Perspective口頭発表(一般)
- 日本膜学会第47年会, 2025年06月Unraveling Membrane Fouling Mechanisms in Reverse Osmosis of Rare Earth Wastewater: A Multiscale Perspective口頭発表(一般)
- The 14th Aseanian Membrane Society (AMS), 2024年07月, 英語Polyamide Nanofilms with Fine-Tuning Crumpled Structures for Ion Separationポスター発表
- The 14th Aseanian Membrane Society, 2024年07月, 英語Molecular Insights into Liquid-Liquid Interface During Interfacial Polymerization of Polyamide Membranes口頭発表(一般)
- The 46th Annual Meeting of the Membrane Society of Japan, 2024年06月, 英語Molecular Insights into Liquid-Liquid Interface During Interfacial Polymerization of Polyamide Membranes口頭発表(一般)
- The Society of Chemical Engineers Japan 89th Annual Meeting, 2024年03月, 英語Preparation of crumpled polyamide membranes with high aspect ratio via interlayer-assisted interfacial polymerizationポスター発表
- The 45th Annual Meeting of the Membrane Society of Japan & Membrane Symposium 2023, 2023年11月, 英語Molecular dynamics simulations on nanoscale heterogeneity of polyamide membranes口頭発表(一般)
- The 54th Autumn Meeting of the Society of Chemical Engineers, Japan, 2023年09月, 英語Reversibly tunable pore sizes of polymeric membranes for multiple separations口頭発表(一般)
- The 54th Autumn Meeting of the Society of Chemical Engineers, Japan, 2023年09月, 英語Nanomorphogenesis of Polyamide Membranes with Confined Activator-Inhibitor Diffusivity Difference口頭発表(一般)
- The 13th International Congress on Membranes and Membrane Processes, 2023年07月, 英語Molecular insights into the pattern formation of interfacial polymerized desalination polyamide membranes口頭発表(一般)
- The 13th International Congress on Membranes and Membrane Processes, 2023年07月, 英語Development of nanofiltration membrane with crumpled polyamide nanofilm toward enhanced desalination performanceポスター発表
- The Society of Chemical Engineers Japan 88th Annual Meeting, 2023年03月, 英語High-performance crumpled polyamide membrane for antibiotic desalination via nanofiltrationポスター発表
- The Society of Chemical Engineers Japan 88th Annual Meeting, 2023年03月, 英語Molecular insights into the origin of membrane roughness in interfacial polymerization口頭発表(一般)
- The Membrane Society of Japan & Membrane Symposium, 2022年11月, 英語Micelle-Induced Reverse Osmosis membranes for ultrahigh performance desalination口頭発表(一般)
- The 53rd Autumn Meeting of the Society of Chemical Engineers, Japan, 2022年09月, 英語Self-assembly induced interfacial polymerization toward ultra-permeable desalination membranes口頭発表(一般)
- Proceedings of 2015 Engineering with Membranes (Beijing, China), 2015年05月, 英語Fouling of RO membranes by surfactants口頭発表(一般)
- Euromembrane 2012 Conference, 2012年09月, 英語Fouling of reverse osmosis membranes by hydrocarbonated and fluorinated surfactants contained in firefighting waterポスター発表
- Euromembrane 2012 Conference, 2012年09月, 英語Mechanisms of RO Membrane Fouling by Surfactants: A Combination of Experiments and Simulation Studiesポスター発表
■ 共同研究・競争的資金等の研究課題
- 日本学術振興会, 科学研究費助成事業, 基盤研究(C), 神戸大学, 2025年02月 - 2028年03月, 研究代表者Development of multiscale simulations on interfacial polymerization of polyamide desalination membranes
- Science and Technology Department of Jiangxi, China, Jiangxi Academy of Sciences, 2019年01月 - 2020年12月, 研究代表者Multiscale simulation on EfOM-RO membrane interactions and the mechanism of membrane fouling
- National Natural Science Foundation of China, Jiangxi Academy of Sciences, 2017年01月 - 2020年12月, 研究分担者The Structure and catalytic mechanism of high performance Pd-Fe-based catalysts on fuel cells
- National Natural Science Foundation of China, Jiangxi Academy of Sciences, 2016年01月 - 2019年12月, 研究代表者Fouling mechanisms of integrated membrane process for ammonia nitrogen removal from rare earth industry
- Jiangxi Association for Science and Technology, 2018年10月 - 2019年10月, 研究代表者Scholarship as a visiting scholar in KU Leuven
- Ministry of Science and Technology of the PR. China, Jiangxi Academy of Sciences, 2018年10月 - 2019年10月, 研究代表者Fouling mechanism and mass transport of solutes with nanofiltration/reverse osmosis membranes for industrial applications
- Foundation of Ministry of Human Resources and Social Security of the People’s Republic of China, Jiangxi Academy of Sciences, 2016年01月 - 2016年12月, 研究代表者Application of integrated membrane technology in rare earth industry
- Dissipative particle dynamics method for simulating reverse osmosis membrane fouling特許2019108585707, 2023年04月07日特許権
- Simulation method for analyzing diffusion property of water-soluble monomer in hydrogel membrane特許ZL201910859102.1, 2022年07月05日特許権
- Dissipative particle dynamics method for simulating interfacial polymerization process of composite membrane特許ZL201910858591.9, 2022年02月15日特許権
- Dissipative particle dynamics method for simulating interfacial polymerization process of hydrogel membrane特許US 2021/0074386 A1, 2021年03月11日特許権
- Simulation method for analyzing diffusion property of water-soluble monomer in hydrogel membrane特許US 2021/0074387 A1, 2021年03月11日特許権
- Siphon type composite vertical subsurface flow constructed wetland特許US10889516 B2, 2021年01月12日, Jiangxi Academy of Sciences, 特許US10889516 B2特許権
- A forcefield of dissipative particle dynamics特許ZL201910859103.6, 2020年05月08日特許権
- Dissipative particle dynamics method for simulating interfacial polymerization process of hydrogel membrane特許ZL201910859079.6, 2020年04月21日特許権
- Device for treating rare earth smelting high-ammonia nitrogen wastewater by using integrated membrane technology特許CN208762281U, 2019年04月19日実用新案権
- Method and device for treating rare earth smelting high-ammonia nitrogen wastewater by using integrated membrane technology特願CN201810156268.2, 2018年02月24日, CN201810156268.2, 2018年02月24日特許権
