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KUMABE YoshitakaCenter for Life Photonic InnovationAssistant Professor
Research activity information
■ Award- Mar. 2021 高知工科大学, 佐久間賞
- Oct. 2019 高知化学シンポジウム2019, 優秀ポスター発表賞
- Aug. 2018 6th International Solvothermal and Hydrothermal Association Conference, ISHA 2018 Graduate Student Awards
- Mar. 2018 平成29年度日本化学会中国四国支部, 支部長賞
- Sep. 2016 化学工学会第48回秋季大会 超臨界流体部会シンポジウム, 学生賞
- Lead, American Chemical Society (ACS), Jul. 2025, ACS Catalysis, 15, 11993 - 12004, English, International magazine[Refereed]Scientific journal
- American Chemical Society (ACS), Jun. 2025, ACS Applied Materials & Interfaces, 17(24) (24), 35552 - 35561[Refereed]Scientific journal
- Abstract Self-healing is a fundamental ability inherent in humans, plants, and other living organisms. To date, a variety of materials with self-healing properties have been developed. However, these materials usually require external inputs such as electric potentials or healing agents to initiate or promote self-healing reactions. Herein, we present a novel self-healing mechanism that operates without any external input, utilizing the dynamic equilibrium between the solid-state and dissolved materials. We employed organic–inorganic perovskites to validate our strategy. Single-particle spectroscopy and imaging demonstrated the spontaneous self-healing of perovskites after photodamage under dynamic equilibrium conditions. Furthermore, we found that perovskites can generate hydrogen in both healed and damaged states. Remarkably, the perovskites exhibited hydrogen generation over four cycles of photodamage and self-healing. The proposed concept and experimental results provide valuable insights for the development of energy conversion and storage systems with improved long-term durability.Springer Science and Business Media LLC, Apr. 2025, Communications Chemistry, 8(1) (1)[Refereed]Scientific journal
- Feb. 2025, The Journal of Physical Chemistry C[Refereed]Scientific journal
- Jun. 2023, Small[Refereed]Scientific journal
- Mar. 2023, The Journal of Physical Chemistry Letters[Refereed]Scientific journal
- Abstract Dopant segregation, frequently observed in ionic oxides, is useful for engineering materials and devices. However, due to the poor driving force for ion migration and/or the presence of substantial grain boundaries, dopants are mostly confined within a nanoscale region. Herein, we demonstrate that core–shell heterostructures are formed by oriented self-segregation using one-step thermal annealing of metal-doped hematite mesocrystals at relatively low temperatures in air. The sintering of highly ordered interfaces between the nanocrystal subunits inside the mesocrystal eliminates grain boundaries, leaving numerous oxygen vacancies in the bulk. This results in the efficient segregation of dopants (~90%) on the external surface, which forms their oxide overlayers. The optimized photoanode based on hematite mesocrystals with oxide overlayers containing Sn and Ti dopants realises high activity (~0.8 μmol min−1 cm−2) and selectivity (~90%) for photoelectrochemical H2O2 production, which provides a wide range of application for the proposed concept.Springer Science and Business Media LLC, Mar. 2022, Nature Communications, 13(1) (1), 1499, English[Refereed]Scientific journal
- Royal Society of Chemistry (RSC), Feb. 2021, RSC Advances, 11(10) (10), 5609 - 5617, English
Spherical porous ceria having high content of Ce3+ species was synthesized by the solvothermal method using acetonitrile as a solvent. The spherical porous ceria possesses superior oxygen storage capacity owing to its high Ce3+ contents.
[Refereed]Scientific journal - Lead, Royal Society of Chemistry (RSC), Apr. 2020, RSC Advances, 10(25) (25), 14630 - 14636, English
Nb2O5, TiO2–Nb2O5, and TiNb2O7 porous spheres with large surface area were synthesized by alcothermal reaction and calcination.
[Refereed]Scientific journal - Elsevier BV, Feb. 2020, Applied Surface Science, 504, 144193 - 144193, English[Refereed]Scientific journal
- Elsevier BV, May 2019, Applied Catalysis A: General, 577, 35 - 43, English[Refereed]Scientific journal
- Lead, Elsevier BV, May 2018, Microporous and Mesoporous Materials, 261, 207 - 213, English[Refereed]Scientific journal
- Lead, Feb. 2026, SPring-8/SACLA 利用研究成果集, 14(1) (1), 1 - 4, Japanese[Refereed]
- 化学工業社, May 2019, ケミカルエンジニヤリング, 64(5) (5), 319 - 325, Japaneseナノ凹凸多孔体の一段階大量合成と耐熱触媒担体への応用 (特集 ナノテクノロジーの探索)
- 日本化学会第98春季年会, Mar. 2018, EnglishRapid heating solvothermal synthesis of ultrafine nanoparticles and formation of their porous thin layer filmsPoster presentation
- Supergreen 2017 (The 10th International Conference on Supercritical Fluids), Dec. 2017, EnglishEffect of Acid Additives on Methanol Solvothermal Reaction of Titanium TetraalkoxidePoster presentation
- The 6th International Symposium on Frontier Technology, Nov. 2017, EnglishSynthesis of Titania Nanocrystals with Sub-5 nm Size and Conversion into Porous Thin Layer Transparent FilmsOral presentation
- ナノテク研シンポジウム2017, Nov. 2017, Japanese透明TiO2薄膜調製のための極小ナノ粒子ワンポット合成Poster presentation
- The 17th Congress of Asian Pacific Confederation of Chemical Engineering, Aug. 2017, EnglishRapid One-pot Synthesis of Titania Nanocrystals with Sub-5 nm SizeOral presentation
- 第5回 高知大学-高知工科大学ジョイントセミナー, Jun. 2017, Japaneseスクアリン酸-チタンナノ構造体の合成とその光触媒活性の評価Oral presentation
- ナノテク研シンポジウム2016, Nov. 2016, Japanese極小酸化チタンナノロッドを用いた透明半導体薄膜の形成Poster presentation
- 化学工学会第48回秋季大会, Sep. 2016, Japanese不飽和脂肪酸を用いた極小酸化チタンナノロッドの高温高圧合成Oral presentation
- 高知化学会第29回研究会, Aug. 2016, Japanese極小酸化チタンナノロッドの合成と薄膜形成Poster presentation
- 日本化学会第96春季年会, Mar. 2016, JapaneseSynthesis of Titanium Dioxide Assemblies with 2D Hexagonal NanostructurePoster presentation
- ナノテク研シンポジウム2015, Nov. 2015, Japaneseソルボサーマル粒子合成における有機カルボン酸の構造規定効果Poster presentation
- 高知化学会第28回研究会, Aug. 2015, Japanese有機カルボン酸を構造規定剤とする酸化チタンナノ粒子集合体の合成Poster presentation
■ Research Themes
- Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Fund for the Promotion of Joint International Research (International Collaborative Research), Kobe University, Sep. 2023 - Mar. 2027Development of Single-Molecule Reaction Imaging Techniques for Visualizing Carbon Resource Transformation
