SEARCH
Search DetailsGUAN KechengResearch Center for Membrane and Film TechnologyAssistant Professor
Researcher basic information
■ Research Keyword■ Research Areas
- Manufacturing technology (mechanical, electrical/electronic, chemical engineering) / Transfer phenomena and unit operations
- Jul. 2025 - Present, Journal of Membrane Science, Early Career Editorial Board Member
- 2025 - Present, ACS Applied Nano Materials, Early Career Board Member, https://pubs.acs.org/page/aanmf6/editors.html
- Dec. 2024 - Present, Process Safety and Environmental Protection, Subject Editor, https://www.sciencedirect.com/journal/process-safety-and-environmental-protection/about/editorial-board
- Apr. 2024 - Dec. 2024, Desalination, Co-Guest Editor, https://www.sciencedirect.com/special-issue/297524/green-membranes-for-desalination
Research activity information
■ Award- Sep. 2026 Kobe University, Excellent Young Researcher Award
- Jun. 2026 Kao Foundation for Arts and Sciences, Kao Science Encouragement Award
- Dec. 2025 Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, The Global Separation Technology Youth Innovation Award (Nomination Award)
- Mar. 2025 Desalination, Rising Stars in Desalination (2024)
- Jul. 2024 Kobe University, Maenosono Memorial Young Researcher Excellent Paper Award
- May 2024 The North American Membrane Society (NAMS), Young Membrane Scientist Award
- 2018 American Chemical Society Shanghai Chapter, ACS Shanghai Chapter Outstanding Graduate Student Research Award
- Elsevier BV, Sep. 2026, Desalination, 634, 120311 - 120311[Refereed]Scientific journal
- Lead, Springer Science and Business Media LLC, May 2026, Nature Communications[Refereed]Scientific journal
- Elsevier BV, May 2026, Journal of Membrane Science, 749, 125456 - 125456[Refereed]Scientific journal
- Apr. 2026, SEPARATION AND PURIFICATION TECHNOLOGY, 388, English[Refereed]Scientific journal
- Mar. 2026, JOURNAL OF MEMBRANE SCIENCE, 741, English[Refereed]Scientific journal
- Corresponding, Mar. 2026, JOURNAL OF MEMBRANE SCIENCE, 741, English[Refereed]Scientific journal
- ABSTRACT Precise separation of Li + /Mg 2+ with similar ionic size remains a critical challenge for two‐dimensional (2D) membranes, largely due to the inherently tortuous and poorly regulated transport channels in the 2D interlayer. Herein, we propose a heterogeneity‐guided interlayer engineering strategy to reprogram the lamellar ion transport pathways of vermiculite (Vm) membranes through the incorporation of ultrathin ZrBTB (Zr) metal organic framework nanosheets. Owing to the intrinsic electrostatic environment and sub‐nanometer apertures, the resulting vermiculite/ZrBTB heterolamina membranes exhibit reorganized interlayer nanochannels without changing the average interlayer spacing. Systematic structural analysis reveals that ZrBTB incorporation suppresses long‐range lamellar ordering while enriching sub‐nanoconfinement domains and partially reversing the channel‐wall charge. These synergistic modifications generate enhanced Li + transport pathways and a strengthened electrostatic/steric exclusion environment for Mg 2+ . As a result, the optimum membrane achieves a Li + permeation rate of 0.379 mol m −2 h −1 and an outstanding Li + /Mg 2+ selectivity of ∼46.2, surpassing most diffusion‐based separation membranes. Comparative studies using CuTCPP nanosheets further confirm that channel size, charge, and energy barriers can be effectively tuned through rational selection of 2D MOF building blocks. This work establishes interlayer heterogeneity as a powerful and generalizable design parameter for constructing next‐generation 2D membranes for efficient ion sieving under mild conditions.Corresponding, Wiley, Feb. 2026, Advanced Science, 13(26) (26)[Refereed]Scientific journal
- Feb. 2026, ADVANCED SCIENCE, English[Refereed]Scientific journal
- Feb. 2026, DESALINATION, 620, English[Refereed]Scientific journal
- Feb. 2026, JOURNAL OF MEMBRANE SCIENCE, 740, English[Refereed]Scientific journal
- Lead, Feb. 2026, SMALL, 22(7) (7), English
- Jan. 2026, ACS APPLIED NANO MATERIALS, 9(2) (2), 1284 - 1294, English[Refereed]Scientific journal
- Corresponding, Jan. 2026, WATER RESEARCH, 288, EnglishScientific journal
- Corresponding, Jan. 2026, ADVANCED SCIENCE, 13(3) (3), English[Refereed]Scientific journal
- Nov. 2025, NANOSCALE, 17(46) (46), 26798 - 26810, English[Refereed]Scientific journal
- Nov. 2025, JOURNAL OF MEMBRANE SCIENCE, 735, English[Refereed]Scientific journal
- Oct. 2025, SEPARATION AND PURIFICATION TECHNOLOGY, 370, English[Refereed]Scientific journal
- Corresponding, Oct. 2025, DESALINATION, 613, English[Refereed]Scientific journal
- Oct. 2025, JOURNAL OF MEMBRANE SCIENCE, 734, English[Refereed]Scientific journal
- Oct. 2025, JOURNAL OF MEMBRANE SCIENCE, 734, English[Refereed]Scientific journal
- Aug. 2025, WATER RESEARCH, 282, English[Refereed]Scientific journal
- Aug. 2025, SMALL, 21(33) (33), English[Refereed]Scientific journal
- Jul. 2025, DESALINATION, 607, English[Refereed]Scientific journal
- Jul. 2025, JOURNAL OF MATERIALS CHEMISTRY A, 13(28) (28), 22859 - 22870, English[Refereed]Scientific journal
- Corresponding, Jul. 2025, JOURNAL OF MEMBRANE SCIENCE, 730, English[Refereed]Scientific journal
- Jun. 2025, ADVANCED SCIENCE, 12(23) (23), English[Refereed]Scientific journal
- Jun. 2025, JOURNAL OF MEMBRANE SCIENCE, 729, English[Refereed]Scientific journal
- Corresponding, Jun. 2025, JOURNAL OF MEMBRANE SCIENCE LETTERS, 5(1) (1), English[Refereed]Scientific journal
- May 2025, Desalination, 602, English[Refereed]Scientific journal
- Apr. 2025, Water Research, 274, English[Refereed]Scientific journal
- Apr. 2025, Desalination, 601, English[Refereed]Scientific journal
- Apr. 2025, JOURNAL OF MEMBRANE SCIENCE, 723, English[Refereed]Scientific journal
- Mar. 2025, Advanced Materials, 37(19) (19), English[Refereed]Scientific journal
- Mar. 2025, Desalination, 597, English[Refereed]Scientific journal
- Corresponding, Mar. 2025, Desalination, 597, English[Refereed]Scientific journal
- Lead, Feb. 2025, ACS Nano, 19(5) (5), 5178 - 5192, English[Refereed]Scientific journal
- Feb. 2025, Journal of Membrane Science, 717, English[Refereed]Scientific journal
- Corresponding, Jan. 2025, Desalination, 594, English[Refereed]Scientific journal
- Corresponding, Jan. 2025, Chemical Engineering Journal, 506, English[Refereed]Scientific journal
- 2025, Journal of Membrane Science, 736, English[Refereed]Scientific journal
- 2025, Journal of Membrane Science, 737, English[Refereed]Scientific journal
- 2025, Journal of Membrane Science, 736, English[Refereed]Scientific journal
- Corresponding, 2025, Advanced Functional Materials, 35(23) (23), English[Refereed]Scientific journal
- Jan. 2025, Journal of Membrane Science, 713, English[Refereed]Scientific journal
- Jan. 2025, Journal of Membrane Science, 713, English[Refereed]Scientific journal
- Dec. 2024, Desalination, 592, English[Refereed]Scientific journal
- Dec. 2024, Desalination, 592, 118118 - 118118, English[Refereed]Scientific journal
- Nov. 2024, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 701, English[Refereed]Scientific journal
- Nov. 2024, Small, 21(13) (13), English[Refereed]Scientific journal
- Aug. 2024, Environmental Chemistry Letters, 22(4) (4), 1615 - 1621, English[Refereed]Scientific journal
- Jul. 2024, ACS Applied Materials and Interfaces, 16(29) (29), 38723 - 38732, English[Refereed]Scientific journal
- Corresponding, Jul. 2024, Desalination, 581, English[Refereed]Scientific journal
- Jul. 2024, Journal of Membrane Science, 706, English[Refereed]Scientific journal
- Jun. 2024, Separation and Purification Technology, 338, English[Refereed]Scientific journal
- Jun. 2024, Desalination, 578, English[Refereed]Scientific journal
- Jun. 2024, Angewandte Chemie - International Edition, 63(24) (24), e202405676, English, International magazine[Refereed]Scientific journal
- Jun. 2024, Journal of Membrane Science, 704, 122901 - 122901, English[Refereed]Scientific journal
- May 2024, Journal of Membrane Science, 702, English[Refereed]Scientific journal
- Corresponding, Apr. 2024, Small, 20(34) (34), English[Refereed]Scientific journal
- Mar. 2024, ACS Omega, 9(12) (12), 14187 - 14197, English[Refereed]Scientific journal
- Mar. 2024, Journal of Membrane Science, 697, 122581 - 122581, English[Refereed]Scientific journal
- Mar. 2024, Journal of Membrane Science, 695, 122511 - 122511, English[Refereed]Scientific journal
- Feb. 2024, Journal of Membrane Science, 693, 122338 - 122338, English[Refereed]Scientific journal
- Corresponding, 2024, Advanced Functional Materials, 35(10) (10), English[Refereed]Scientific journal
- Corresponding, 2024, Nano Letters, 24(43) (43), 13686 - 13694, English[Refereed]Scientific journal
- Jan. 2024, Journal of Membrane Science, 689, 122176 - 122176, English[Refereed]Scientific journal
- Corresponding, Jan. 2024, Journal of Membrane Science, 689, 122185 - 122185, English[Refereed]Scientific journal
- Dec. 2023, Chemical Engineering Journal, 478, English[Refereed]Scientific journal
- Dec. 2023, Journal of Membrane Science, 688, 122133 - 122133, English[Refereed]Scientific journal
- Lead, Dec. 2023, Journal of Membrane Science, 688, 122104 - 122104, English[Refereed]Scientific journal
- Corresponding, Dec. 2023, Journal of Membrane Science, 687, 122048 - 122048, English[Refereed]Scientific journal
- Nov. 2023, Desalination, 565, English[Refereed]Scientific journal
- Nov. 2023, Desalination, 566, 116936 - 116936, English[Refereed]Scientific journal
- Nov. 2023, Journal of Membrane Science, 686, 121997 - 121997, English[Refereed]Scientific journal
- Corresponding, Oct. 2023, Water Research, 244, 120439 - 120439, English[Refereed]Scientific journal
- Sep. 2023, Journal of Membrane Science, 682, English[Refereed]Scientific journal
- Aug. 2023, Journal of Membrane Science, 679, 121711 - 121711, English[Refereed]Scientific journal
- Jul. 2023, Journal of Membrane Science, 678, 121687 - 121687, English[Refereed]Scientific journal
- Jul. 2023, Journal of Membrane Science, 677, 121639 - 121639, English[Refereed]Scientific journal
- Lead, Jun. 2023, Nano letters, 23(13) (13), 6095 - 6101, English, International magazine[Refereed]Scientific journal
- Jun. 2023, Chemical Engineering Journal, 465, English[Refereed]Scientific journal
- Apr. 2023, Small (Weinheim an der Bergstrasse, Germany), 19(33) (33), e2300672, English, International magazine[Refereed]Scientific journal
- Mar. 2023, Journal of Membrane Science, 670, English[Refereed]Scientific journal
- Mar. 2023, Process Safety and Environmental Protection, 171, 555 - 560, English[Refereed]Scientific journal
- Lead, Feb. 2023, Nature communications, 14(1) (1), 1016 - 1016, English, International magazine[Refereed]Scientific journal
- Feb. 2023, Journal of Membrane Science, 668, English[Refereed]Scientific journal
- 2023, Science Advances, 9(18) (18), English[Refereed]Scientific journal
- 2023, Journal of Materials Chemistry A, 11(16) (16), 8836 - 8844, English[Refereed]Scientific journal
- Corresponding, Sep. 2022, Journal of Membrane Science, 657, English[Refereed]Scientific journal
- Aug. 2022, Desalination, 536, English[Refereed]Scientific journal
- Aug. 2022, Journal of Applied Polymer Science, 139(30) (30), English[Refereed]Scientific journal
- Lead, Jul. 2022, Journal of Membrane Science, 660, 120861 - 120861, English[Refereed]Scientific journal
- Mar. 2022, Journal of Membrane Science, 646, English[Refereed]Scientific journal
- Mar. 2022, Journal of Membrane Science, 645, English[Refereed]Scientific journal
- Mar. 2022, Journal of Membrane Science, 645, English[Refereed]Scientific journal
- Lead, The Membrane Society of Japan, 2022, MEMBRANE, 47(2) (2), 68 - 75[Refereed][Invited]
- Lead, Dec. 2021, Journal of Membrane Science, 640, English[Refereed]Scientific journal
- Dec. 2021, Journal of Materials Chemistry A, 9(46) (46), 26159 - 26171, English[Refereed]Scientific journal
- Nov. 2021, Desalination, 516, English[Refereed]Scientific journal
- Corresponding, Nov. 2021, ACS Sustainable Chemistry and Engineering, 9(43) (43), 14525 - 14536, English[Refereed]Scientific journal
- Oct. 2021, Journal of Membrane Science, 635, English[Refereed]Scientific journal
- Sep. 2021, CHEMICAL ENGINEERING JOURNAL, 420, English[Refereed]Scientific journal
- Jun. 2021, AICHE JOURNAL, 67(6) (6), English[Refereed]Scientific journal
- Lead, Apr. 2021, NANO LETTERS, 21(8) (8), 3495 - 3502, English[Refereed]Scientific journal
- Corresponding, Mar. 2021, JOURNAL OF MATERIALS CHEMISTRY A, 9(12) (12), 7924 - 7934, English[Refereed]Scientific journal
- Feb. 2021, JOURNAL OF MEMBRANE SCIENCE, 619, English[Refereed]Scientific journal
- 2021, Nano Letters, 21(15) (15), 6525 - 6532, English[Refereed]Scientific journal
- Corresponding, Jan. 2021, JOURNAL OF MEMBRANE SCIENCE, 618, English[Refereed]Scientific journal
- Lead, Dec. 2020, JOURNAL OF MATERIALS CHEMISTRY A, 8(48) (48), 25880 - 25889, English[Refereed]Scientific journal
- Nov. 2020, DESALINATION, 493, English[Refereed]Scientific journal
- Lead, Oct. 2020, JOURNAL OF MEMBRANE SCIENCE, 611, English[Refereed]Scientific journal
- Aug. 2020, ACS APPLIED MATERIALS & INTERFACES, 12(34) (34), 38662 - 38673, English[Refereed]Scientific journal
- Lead, Jul. 2020, CHINESE JOURNAL OF CHEMICAL ENGINEERING, 28(7) (7), 1755 - 1766, English[Refereed]
- Feb. 2020, JOURNAL OF MEMBRANE SCIENCE, 595, English[Refereed]Scientific journal
- Feb. 2020, AICHE JOURNAL, 66(2) (2), English[Refereed]Scientific journal
- 2020, Chemical Engineering Journal, 417, English[Refereed]Scientific journal
- Aug. 2019, ADVANCED FUNCTIONAL MATERIALS, 29(33) (33), English[Refereed]Scientific journal
- Lead, Jul. 2019, SCIENCE CHINA-MATERIALS, 62(7) (7), 925 - 935, English[Refereed]Scientific journal
- Mar. 2019, NATURE COMMUNICATIONS, 10(1) (1), English[Refereed]Scientific journal
- Jan. 2019, JOURNAL OF MEMBRANE SCIENCE, 572, 20 - 27, English[Refereed]Scientific journal
- Aug. 2018, ADVANCED FUNCTIONAL MATERIALS, 28(31) (31), English[Refereed]Scientific journal
- Lead, Jul. 2018, CHEMSUSCHEM, 11(14) (14), 2315 - 2320, English[Refereed]Scientific journal
- Lead, Apr. 2018, ACS APPLIED MATERIALS & INTERFACES, 10(16) (16), 13903 - 13913, English[Refereed]Scientific journal
- Lead, Nov. 2017, JOURNAL OF MEMBRANE SCIENCE, 542, 41 - 51, English[Refereed]Scientific journal
- Nov. 2017, AICHE JOURNAL, 63(11) (11), 5054 - 5063, English[Refereed]Scientific journal
- Sep. 2017, ACS APPLIED MATERIALS & INTERFACES, 9(35) (35), 30024 - 30034, English[Refereed]Scientific journal
- Aug. 2017, AICHE JOURNAL, 63(8) (8), 3501 - 3510, English[Refereed]Scientific journal
- Lead, Mar. 2017, SEPARATION AND PURIFICATION TECHNOLOGY, 174, 126 - 135, English[Refereed]Scientific journal
- Sep. 2016, JOURNAL OF MEMBRANE SCIENCE, 513, 155 - 165, English[Refereed]Scientific journal
- Aug. 2016, AICHE JOURNAL, 62(8) (8), 2843 - 2852, English[Refereed]Scientific journal
- Jul. 2016, JOURNAL OF MEMBRANE SCIENCE, 510, 338 - 347, English[Refereed]Scientific journal
- Aug. 2015, ACS APPLIED MATERIALS & INTERFACES, 7(30) (30), 16157 - 16160, English[Refereed]Scientific journal
- The 18th Annual Conference of the Global Chinese Chemical Engineering Scholars, Aug. 2026Membrane charge neutralization in nanofiltration for universal mono-/divalent ion sieving[Invited]Invited oral presentation
- The 12th China Congress on Membranes and Membrane Processes, Aug. 2026Membrane channel polarity control and solvent transport properties[Invited]Invited oral presentation
- The 4th Global Conference of Innovation Materials & MRS-K Spring Meeting, Jun. 2026Polarity-Regulated Transport in Nanoconfined Membranes for Solvent Separation[Invited]Invited oral presentation
- The Society of Chemical Engineers Japan 91st Annual Meeting, Mar. 2026Substrate control for improved interfacial polymerization of polyamide membranesOral presentation
- The 12th International Membrane Science & Technology Conference, Dec. 2025Polyamide membranes for efficient solvent mixture separationOral presentation
- Membrane Symposium 2025, Nov. 2025Polyamine-based polyamide membranes for reverse osmosis separation of organic solvent mixtures
- 2025 International Symposium on Advanced Membrane Materials and Separation Technologies, Oct. 2025Thin film composite polyamide membranes for solvent reverse osmosis[Invited]Keynote oral presentation
- 56th Autumn Meeting of the Society of Chemical Engineering Japan, Sep. 2025Zwitterionic nanofiltration membranes for charge-sign-independent separation of mono- and divalent ionsOral presentation
- 15th Conference of Aseanian Membrane Society, Aug. 2025Charge-sign-independent separation of mono- and divalent ions with nanofiltration membranesOral presentation
- The 47th Annual Meeting of the Membrane Society of Japan, Jun. 2025Graphene Oxide Coatings for Improved Membrane Distillation
- The Society of Chemical Engineers Japan 90th Annual Meeting, Mar. 2025Intercalation modifications of graphene oxide nanofiltration membranesOral presentation
- Membrane Society of Australasia (MSA) Annual Meeting and Conference 2024, Dec. 2024Stability of two-dimensional graphene oxide membrane nanochannels[Invited]Invited oral presentation
- Membrane Symposium 2024, Nov. 2024Nanochannel stability of graphene oxide membranes
- 55th Autumn Meeting of the Society of Chemical Engineering Japan, Sep. 2024Controlled formation of polyethylenimine-based polyamide membranes for lithium extraction
- 14th Conference of Aseanian Membrane Society (AMS), Jul. 2024Membrane coatings for robust seawater distillation[Invited]Invited oral presentation
- The 46th Annual Meeting of the Membrane Society of Japan, Jun. 2024Thin film composite membrane with improved permeance for general reverse osmosisOral presentation
- The North American Membrane Society (NAMS) Annual Meeting 2024, May 2024Surface coatings for fouling-resistant membrane distillation[Invited]Invited oral presentation
- International Conference on Future Membranes 2024, Apr. 2024Confined and mediated intercalation modification of graphene oxide membranes[Invited]Invited oral presentation
- The 45th Annual Meeting of the Membrane Society of Japan & Membrane Symposium 2023, Nov. 2023Confined and mediated intercalation modification of graphene oxide membranes
- 54th Autumn Meeting of the Society of Chemical Engineering Japan, Sep. 2023Surface coatings for fouling-resistant membrane distillation
- The 13th International Congress on Membranes and Membrane Processes, Jul. 2023Confined graphene oxide nanochannel membranes for desalinationOral presentation
- The Society of Chemical Engineers Japan 88th Annual Meeting, Mar. 2023Deformation constraints of graphene oxide nanochannels under reverse osmosis
- The 11th International Membrane Science & Technology Conference, Dec. 2022Composite membrane structure with asymmetric wetting properties for membrane distillation
- The Society of Chemical Engineers Japan 53rd Autumn Meeting, Sep. 2022Asymmetric superwetting Janus membrane for membrane distillation
- 13th Conference of the Aseanian Membrane Society, Jul. 2022Polyketone enabled membranes materials for water purificationOral presentation
- 44th Annual Meeting of the Membrane Society of Japan, Jun. 2022Thin film composite reverse osmosis membrane with polyketone substrates
- Membrane Symposium 2021, Nov. 2021Microstructured coating for superwetting membrane surfaces
- 5th International Conference on Membrane Desalination 2021, Nov. 2021Multilayered graphene oxide membranes with confined nanochannels for ion exclusion
- 52rd Autumn Meeting of the Society of Chemical Engineering Japan, Sep. 2021Superwetting polyketone membranes for oil/water separation
- 43rd Annual Meeting of the Membrane Society of Japan, Jun. 2021Chemically converted graphene membrane with ion-exclusion nanochannels
- 86th Annual Meeting of the Society of Chemical Engineering Japan, Mar. 2021Nanochannel-confined charge repulsion of ions in a reduced graphene membraneOral presentation
- 12th International Congress on Membranes and Membrane Processes, Dec. 2020, EnglishControlling the formation of porous polyketone membrane by a cross-linkable alginate additivePoster presentation
- Membrane Symposium 2020, Nov. 2020, EnglishNanochannel-confined charge repulsion of ions in a reduced graphene membraneOral presentation
- the Society of Chemical Engineering Japan 51st Autumn Meeting, Sep. 2020, EnglishControlling the formation of porous polyketone membranes via a cross-linkable alginate additive for oil-in-water emulsion separationsOral presentation
- 11th International Congress on Membranes and Membrane Processes, Jul. 2017, English3D porous nanocrystals embedded graphene membrane for water purificationPoster presentation
- The Membrane Society of JapanOct. 2024 - Present
- The Society of Chemical Engineers, Japan2019 - Present
- The North American Membrane SocietyMay 2024 - Apr. 2025
- American Chemical Society2023 - 2024
- Japan Society for the Promotion of Science, Bilateral Collaborations, Joint Research with South Korea (NRF), Apr. 2026 - Mar. 2028, Principal investigatorCharged microporous membranes via interfacial polymerization for energy-efficient lithium extraction
- The Japan Society for the Promotion of Science (JSPS), Kakenhi, Grant-in-Aid for Scientific Research(C), Kobe University, Feb. 2025 - Mar. 2028Development of multiscale simulations on interfacial polymerization of polyamide desalination membranes
- The Kao Foundation for Arts and Sciences, Kao Science Encouragement Award, Apr. 2026 - Mar. 2027, Principal investigatorInterfacial polymerization of fluorous covalent organic framework membranes for crude oil fractionation
- Hyogo Science and Technology Association, Academic Research Grant Project, Apr. 2025 - Mar. 2026, Principal investigatorPolyamide nanofiltration membranes made from mixed amine monomers for lithium extraction
- Japan society for the promotion of science (JSPS), Grants-in-Aid for Scientific Research, Grant-in-Aid for Early-Career Scientists, Kobe University, Apr. 2023 - Mar. 2026Development of continuous layer coated membrane for fouling-resistant membrane distillation
- Kawanishi Memorial ShinMaywa Education Foundation, Research grant program, Jun. 2024 - Jun. 2025, Principal investigatorImproving lithium separation of polyamide membranes fabricated via controlled interfacial polymerization reaction
- Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Kobe University, 01 Apr. 2022 - 31 Mar. 2025Development of ultrathin laminar nanosheet membranes with controlled 2-D channel structure for organic solvent filtration本研究では種々のナノシート材料を支持膜上に積層することによって超薄型有機溶剤ろ過膜を作製し,2-Dチャネル内での有機溶剤透過メカニズムの解明および溶剤―溶質,溶剤―溶剤分離の検証を行う.有機架橋分子を層間に導入し,2-Dチャネル内での化学的相互作用を評価することで積層構造を精密に制御し,透過性や阻止性に寄与する因子を明らかにする.これにより革新的な高透過性ナノシート積層型有機溶剤ろ過膜を実現し,膜工学分野における新たな基礎学理を構築する. R5年度の研究では,GOナノシート積層膜のチャネル構造の制御を目的として,GO層間における金属有機構造体(MOF)ナノシートの形成,またGO層間への二次元物質であるポルフィリン分子の導入に関する検討を行った. 1. MOF-GO複合積層膜は,GO層間におけるZnOナノ粒子のソルボサーマル合成とGO層間の制限された2-Dチャネル内でのZnOからZn-TCPPへのin-situ変換を利用した2段階の方法で作製した.ZnOの合成時間や担持量を最適化することにより,2-Dチャネル内でZn-TCPPの優先配向が示され,水分子の透過パスが短くなり,19.0 L m-2 h-1 bar -1という高い透水性と高いアニオン性色素阻止率を達成した.またメタノールなどアルコール系溶媒への応用も可能であることを確認した. 2. GO積層膜へのポルフィリン(TPP: 5,10,15,20-Tetraphenylporphyrin)分子の導入によるOSN性能への影響について検討した.GO+TPP積層膜において,X線回折測定により積層構造に由来する回折ピークが観察され,TPP修飾により層間隔がわずかに増加することが確認された.またOSN性能を評価したところ,メタノール透過性が増加し,メタノール中のビタミンB12の阻止率は90%以上に向上した.TPP修飾により層間隔の拡大による流量の増加と,2Dチャネル内に部分的な立体障害が生まれたことによる分子ふるい効果の向上によるものと考えられる.
- The Sumitomo Foundation, Grant for Basic Science Research Projects, Nov. 2023 - Nov. 2024, Principal investigatorResearch on membranes with asymmetric wettability for brine treatment
- New Energy and Industrial Technology Development Organization (NEDO), Joint Research Project for Young Researchers, NEDO 官民による若手研究者発掘支援事業/マッチングサポートフェーズ(環境・エネルギー分野), Jan. 2022 - Mar. 2023, Coinvestigatorナノシート積層型有機溶剤ナノろ過膜の開発による省エネルギー溶剤回収
