ASAHI Shigeo | ![]() |
Graduate School of Engineering / Department of Electrical and Electronic Engineering | |
Associate Professor | |
Electro-Communication Engineering |
Sep. 2022 9th International Symposium on Control of Semiconductor Interfaces (ISCSI-XI), Young Researcher Award, Photoluminescence Characteristics of InAs Quantum Dots in the Doubled-heterointerface of AlGaAs/GaAs-based Two-step Photon Up-conversion Solar Cells
Jun. 2020 47th IEEE Photovoltaic Specialists Conference (PVSC47), PVSC 47 Best Student Paper Award, Up-converted photocurrent enhancement in modulation-doped two-step photon up-conversion
Dec. 2015 第26回光物性研究会, 奨励賞
Aug. 2014 日本材料学会半導体エレクトロニクス部門委員会, 平成26年度第1回研究会学生優秀講演賞
[Refereed]
Photon upconversion (PU) is a process where an electron is excited from the valence band to the conduction band of a wide-gap semiconductor by the sequential absorption of two or more photons via real states. For example, two-step PU can generate additional photocurrent in the so-called intermediate-band solar cells. In this work, we consider two- and three-step processes; we study multi-step PU in a quantum dot (QD)-based single-junction solar cell with a double-heterointerface structure. The solar cell consists of three different absorber layers: Al0.7Ga0.3As, Al0.3Ga0.7As, and GaAs, which form two heterointerfaces. Just beneath each heterointerface, an InAs/GaAs QD layer was inserted. After band-to-band excitation, electrons accumulate at each heterointerface, and then, below-bandgap photons excite a certain fraction of these electrons above the barrier energy. The photoluminescence spectra of the InAs QDs reveal slightly different QD size distributions at the two heterointerfaces. We show that the external quantum efficiency is improved by additional irradiation with below-bandgap infrared photons, which suggests a multi-step PU process that involves the two heterointerfaces. The dependence of the photocurrent on the infrared excitation power density only shows a superlinear behavior when the GaAs layer is excited but the Al0.3Ga0.7As layer is not. These data demonstrate a multi-step PU process that consists of one intraband transition at each of the two heterointerfaces and one interband transition in GaAs.
AIP Publishing, 28 Mar. 2023, Journal of Applied Physics, 133 (12), 124503 - 124503[Refereed]
Scientific journal
Abstract We elucidate a photocarrier collection mechanism in intermediate band solar cells (IBSCs) with InAs-quantum dots (QDs)-in-an-Al0.3Ga0.7As/GaAs-quantum well structures. When the Al0.3Ga0.7As barrier is excited, the device electrical output can be varied by additional infrared light for the electron intraband optical transition in QDs. The photocurrent in IBSC with a single QDs-in-a-well structure shows a monotonic increase with the intraband-excitation density. Conversely, IBSC with a multilayered QDs-in-a-well structure exhibits a photocurrent reduction when electrons in QDs are optically pumped out. The simultaneously measured photoluminescence spectra proved that the polarity of QD states changes depending on the intraband-excitation density. We discuss the drift and diffusion current components and point out that the hole diffusion current is significantly influenced by carriers inside the confinement structure. Under strong intraband excitations, we consider an increased hole diffusion current occurs by blocking hole-capture in the quantum structures. This causes unexpected photocurrent reduction in the multilayered device.
IOP Publishing, 01 Jul. 2022, Japanese Journal of Applied Physics, 61 (7), 074002 - 074002, English[Refereed]
Scientific journal
The generation of two-photon photocurrent plays an essential role in realizing intermediate-band solar cells (IBSCs) with high conversion efficiencies. This current generation process strongly depends on the photocarrier dynamics in the intermediate levels, which can sometimes give rise to a deficient output current unexpectedly. In this work, we investigated the two-photon photocurrent generation process in InAs quantum dot (QD)-in-well intermediate-band solar cells. The two-photon photocurrent is generated by an interband transition in the structure (for example, in the well or the QD) and a subsequent intraband transition in the QD, and we used two different light sources to separately control these transitions. We found that, in the case of QD interband excitation in a sample with multiple wells, the carrier collection efficiency does not simply increase with the intraband excitation intensity; in the range from about 0.08 to 0.5 W/cm2, the collection efficiency decreases with increasing intraband excitation density. A comparison between samples with different numbers of wells revealed that the repetition of carrier trapping and detrapping during the transport in a multi-well structure can effectively modulate the recombination rate. This modulation induces a reduction of the current yield under certain illumination conditions. We propose a model to explain this phenomenon and verify it by investigating the bias dependence of the two-photon photocurrent from the QD.
AIP Publishing, 28 Sep. 2021, Journal of Applied Physics, 130 (12), 124505 - 124505, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
Scientific journal
We studied the dynamics of electrons generated by two-step photoexcitation in an intermediate-band solar cell (IBSC) comprising InAs/GaAs/Al0.3Ga0.7As dot-in-well (DWELL) structure using time-resolved photocurrent (TRPC) measurement. The examined IBSC exhibited considerably slower photocurrent decay than a conventional InAs/GaAs quantum dot IBSC, which is due to the extraordina
Lead, Nature Publishing Group, May 2019, Scientific Reports, 9, 7859 - 1-8, English[Refereed]
Scientific journal
[Refereed]
[Refereed]
Scientific journal
[Refereed]
Development of high-efficiency solar cells is one of the attractive challenges in renewable energy technologies. Photon up-conversion can reduce the transmission loss and is one of the promising concepts which improve conversion efficiency. Here we present an analysis of the conversion efficiency, which can be increased by up-conversion in a single-junction solar cell with a hetero-interface that boosts the output voltage. We confirm that an increase in the quasi-Fermi gap and substantial photocurrent generation result in a high conversion efficiency.
Lead, Nature Publishing Group, 01 Dec. 2018, Scientific Reports, 8 (1), pp. 872 - 1-8, English[Refereed]
Scientific journal
International conference proceedings
[Refereed]
Scientific journal
We have proposed a two-step photon up-conversion solar cell (TPU-SC), which is a single junction solar cell comprising a wide gap semiconductor (WGS) and a narrow gap semiconductor (NGS) to break through the Shockley-Queisser limit for the single-junction solar cells. In the TPU-SC, below-gap photons of WGS excite the NGS and accumulate electrons at the WGS / NGS hetero-interface. The accumulated electrons at the hetero-interface are easily excited towards the WGS barrier by the low-energy photons, resulting in the efficient two-step up-conversion (TPU). We have experimentally demonstrated highly efficient current generation by the TPU. In this paper, we present the concept of the TPU-SC, theoretical prediction of the conversion efficiency of the TPU-SC, and experimental result of efficient photocarrier collection attributable to the TPU phenomenon.
SPIE, 2018, Proceedings of SPIE - The International Society for Optical Engineering, 10527, English[Invited]
International conference proceedings
We studied intermediate-band solar cells (IBSCs) incorporating highly homogeneous InAs/GaAs quantum dot superlattices (QDSLs). The extra photocurrent generated by two-step photon absorption markedly increases at the fundamental state (FS) because the FS miniband has been successfully formed in the QDSL-IBSC by controlling the QD size homogeneity. Here, the carriers excited into the miniband spatially separate in the internal electric field, and the long-lived electrons in the intermediate states of the miniband increase the inter-subband absorption strength. The two-step photocurrent response, therefore, extends toward the longer-wavelength side corresponding to the QDSL-FS at approximately 1.2 mu m. (C) 2018 The Japan Society of Applied Physics
IOP PUBLISHING LTD, Jan. 2018, APPLIED PHYSICS EXPRESS, 11 (1), pp. 012301 - 1-4, English[Refereed]
Scientific journal
We studied the effects of the internal electric field on two-step photocarrier generation in InAs/GaAs quantum dot superlattice (QDSL) intermediate-band solar cells (IBSCs). The external quantum efficiency of QDSL-IBSCs was measured as a function of the internal electric field intensity, and compared with theoretical calculations accounting for interband and intersubband photoexcitations. The extra photocurrent caused by the two-step photoexcitation was maximal for a reversely biased electric field, while the current generated by the interband photoexcitation increased monotonically with increasing electric field intensity. The internal electric field in solar cells separated photogenerated electrons and holes in the superlattice (SL) miniband that played the role of an intermediate band, and the electron lifetime was extended to the microsecond scale, which improved the intersubband transition strength, therefore increasing the two-step photocurrent. There was a trade-off relation between the carrier separation enhancing the two-step photoexcitation and the electric-field-induced carrier escape from QDSLs. These results validate that long-lifetime electrons are key to maximising the two-step photocarrier generation in QDSL-IBSCs.
NATURE PUBLISHING GROUP, Jul. 2017, SCIENTIFIC REPORTS, 7, pp. 5865 - 1-10, English[Refereed]
Scientific journal
We studied the effects of miniband formation on the photocurrent generated by two-step intersubband absorption in an intermediate-band solar cell incorporating an InAs/GaAs quantum dot superlattice (QDSL). The two-step photocarrier generation increases with the electronic state coupling of InAs QDSLs in the intrinsic layer. Because carriers that are excited into the superlattice minibands spatially separate in an internal electric field, the electron-hole recombination rate for the photoexcited carriers decreases, and therefore, the electron lifetime increases. The long-lived electrons in the intermediate states of the QDSL miniband increase the intersubband absorption strength. We confirmed a systematic sensitive change in the two-step photocurrent generation depending on the miniband formation controlled by the temperature. Published by AIP Publishing.
Corresponding, AMER INST PHYSICS, May 2017, APPLIED PHYSICS LETTERS, 110 (19), pp. 193104 - 1-5, English[Refereed]
Scientific journal
Reducing the transmission loss for below-gap photons is a straightforward way to break the limit of the energy-conversion efficiency of solar cells (SCs). The up-conversion of below-gap photons is very promising for generating additional photocurrent. Here we propose a two-step photon up-conversion SC with a hetero-interface comprising different bandgaps of Al0.3Ga0.7As and GaAs. The below- gap photons for Al0.3Ga0.7As excite GaAs and generate electrons at the hetero-interface. The accumulated electrons at the hetero-interface are pumped upwards into the Al0.3Ga0.7As barrier by below- gap photons for GaAs. Efficient two-step photon up-conversion is achieved by introducing InAs quantum dots at the hetero-interface. We observe not only a dramatic increase in the additional photocurrent, which exceeds the reported values by approximately two orders of magnitude, but also an increase in the photovoltage. These results suggest that the two-step photon up-conversion SC has a high potential for implementation in the next-generation high-efficiency SCs.
NATURE PUBLISHING GROUP, Apr. 2017, NATURE COMMUNICATIONS, 8, pp. 14962 - 1-9, English[Refereed]
Scientific journal
[Refereed][Invited]
Scientific journal
We studied time-resolved photocarrier transport through InAs/GaAs quantum dot superlattice (QDSL) solar cells (SCs) using time-of-flight spectroscopy with an optical probe QD structure beneath the QDSL. Carriers optically pumped in the top p-GaAs layer were transported through the intrinsic layer, including the QDSLs, before arriving at the probe QDs. The photoexcited carrier density significantly influenced the time-resolved photoluminescence (PL) of the QDSLs and probe QDs. The time-resolved PL profile of the probe QDs indicated that excitation densities in excess of 25nJ/cm(2) drastically decreased the rise time, suggesting rapid carrier transport through the QDSLs. This was also confirmed by QDSL carrier transport dynamics, for which the PL intensity of the excited states decayed rapidly above this excitation power density, 25nJ/cm(2), while the ground state remained constant. These results demonstrate that filling the ground states of QDSLs and starting to populate the excited state miniband accelerates carrier transport in QDSL SCs. Furthermore, according to two-step photon absorption measurements taken with a 1.3-mu m infrared laser light source, electrons play a key role in the generation of extra photocurrent by sub-band-gap photon irradiation.
AMER PHYSICAL SOC, Nov. 2016, PHYSICAL REVIEW B, 94 (19), pp. 195313 - 1 -9, English[Refereed]
Scientific journal
We studied effects of the internal electric field on the two-step photocurrent generation in quantum dot superlattice (QDSL) solar cells. We calculated the quantum efficiency of intersubbad photoexcited carriers in QDSL as a function of the internal electric field. In our calculation, we proposed a model of a QDSL structure in which electrons created by the interband transition are excited by subbandgap photons corresponding to the intersubband transition. We found that extra photocurrent caused by the two-step photoexcitation shows the maximum at a reverse biased electric field, whereas current generated by only the interband photoexcitation increases monotonically with increasing the electric field. The internal electric field of the solar cell can separate photocreated electron and hole in the SL miniband, and electron lifetime is extended, which improve the intersubband transition strength, and, therefore, the two-step photocurrent increases. Thus, the calculated result unveils that there is a trade-off relation between carrier separation in the SL miniband and electric-field induced carrier escape from QDSL. These results clarify that long electron lifetime extended by carrier separation is a key maximizing the two-step photocurrent generation in a QDSL solar cell.
Society of Materials Science Japan, 01 Sep. 2016, Zairyo/Journal of the Society of Materials Science, Japan, 65 (9), 647 - 651, Japanese[Refereed]
Scientific journal
[Refereed]
Scientific journal
We studied in detail the photocurrent generation process in two-step photon absorption in intermediate-band solar cells, including InAs quantum dots embedded in Al0.3Ga0.7As/GaAs quantum wells at room temperature. The photocurrent generated by the two-step photon absorption exhibited saturation as the interband excitation intensity increased in strength. On the other hand, as the intersubband excitation intensity increased, the two-step photoexcitation current deviated from a power law. Furthermore, the two-step photoexcitation current exhibiting saturation and deviation strongly depended on both the interband and intersubband excitation intensities. To interpret these phenomena, we performed a theoretical simulation of the two-step photoexcitation current. The results suggest that the photocurrent saturation and deviation were caused by filling of the intermediate states with electrons. Furthermore, our calculated results indicate that the electron-recombination lifetime in the intermediate states is extremely long. The results of the temperature dependence of the two-step photoexcitation current and the excitation intensity dependence of photoluminescence suggest that efficient electron-hole separation extends electron lifetime.
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, Mar. 2016, IEEE JOURNAL OF PHOTOVOLTAICS, 6 (2), 465 - 472, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We systematically studied two-step photocurrent generation as functions of the excitation intensities for the interband and inter-subband transitions in an InAs/GaAs/Al0.3Ga0.7As dot-in-well (DWELL) intermediate-band solar cell. The two-step photoexcitation current shows saturation as the inter-band excitation intensity becomes strong, and we found that the inter-band excitation intensity showing the current saturation strongly depends on the inter-subband excitation intensity. To interpret the current-saturation behavior, we proposed a model and carried out theoretical simulation. Simulated results excellently reproduce the experimental observations. It has been clarified that the photocurrent saturation is caused by filling the intermediate states with electrons. Furthermore, the recombination lifetime in DWELL was pointed out to be extremely long. Our results suggest that this carrier lifetime is an important key to realize strong enhancement of two-step photoexcitation.
Society of Materials Science Japan, 01 Sep. 2015, Zairyo/Journal of the Society of Materials Science, Japan, 64 (9), 690 - 695, Japanese[Refereed]
Scientific journal
In this study, we propose a carrier time-of-flight technique to evaluate the carrier transport time across a quantum structure in an active region of solar cells. By observing the time-resolved photoluminescence signal with a quantum-well probe inserted under the quantum structure at forward bias, the carrier transport time can be efficiently determined at room temperature. The
{AIP} Publishing, Jul. 2015, Applied Physics Letters, 107 (4), 043901 - 043901, English[Refereed]
Scientific journal
We studied the two-step photon absorption (TSPA) process in InAs/GaAs quantum-dot superlattice (QDSL) solar cells. TSPA of subband-gap photons efficiently occurs when electrons are pumped from the valence band to the states above the inhomogeneously distributed fundamental states of QDSLs. The photoluminescence (PL)-excitation spectrum demonstrates an absorption edge attributed to the higher excited states of the QDSLs in between the InAs wetting layer states and the fundamental states of QDSLs. When the absorption edge of the excited state was resonantly excited, the superlinear excitation power dependence of the PL intensity demonstrated that the electron and hole created by the interband transition separately relax into QDSLs. Furthermore, time-resolved PL measurements demonstrated that the electron lifetime is extended by thereby inhibiting recombination with holes, enhancing the second subband-gap absorption.
AMER PHYSICAL SOC, May 2015, PHYSICAL REVIEW B, 91 (20), pp. 201303 - 1-6, English[Refereed]
Scientific journal
We studied time-resolved carrier transport through InAs/GaAs quantum dot superlattice (QDSL) solar cells, using time-of-flight spectroscopy with an optical probe structure lying beneath the QDSL. The density of photoexcited carriers in the top p-GaAs layer significantly influences the time-resolved photoluminescence (TRPL) of probe while TRPL of QDSL keeps unchanged. Also, the PL intensity of probe showed exponential increase as the excitation pulse energy increased, which may indicate that the dynamics of holes rule the dynamics observed in TRPL. The induced filling of QD states by strong excitation leads to the condition where carries travel over the QDSL and reach the probe faster.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
We have studied detailed photocurrent generation process in the two-step photon absorption in intermediate-band solar cells including InAs quantum dots embedded in Al0.3Ga0.7As/GaAs quantum wells and influence of thermal carrier escape at room temperature. The photocurrent generated by the two-step photon absorption shows saturation as the inter-band excitation intensity becomes strong. and the inter-band excitation intensity showing the saturation behavior strongly depends on the inter-subband excitation intensity. To interpret this phenomenon. we carried out a theoretical simulation based on carrier dynamics considering carrier generation. energy relaxation and thermal carrier escape. The results indicate that the photocurrent saturation is caused by filling the intermediate states with electrons. The shift of the saturation point depending on the inter-subband excitation intensity is caused by the shift of the quasi-Fermi level for the intermediate states.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
A difficulty of carrier transport in multiple quantum well ( MQW) solar cells is one critical issue that limits their cell performance. Here, direct measurement of electron and hole transport times across InGaAs/GaAsP MQWs has been carried out using our proposed time-of-flight measurement technique on p-on-n and n-on-p MQW structures, respectively. The corresponding effective mobilities are determined, allowing us to approximate the MQW region as a quasi-bulk material with smaller carrier mobilities than a bulk crystal. The result shows similar effective electron and hole mobilities. This results in the similar tendency of cell performance in p-on-n and n-on-p MQW solar cells.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
We studied the two-step photon absorption (TSPA) process in InAs/GaAs quantum-dot superlattice (QDSL) solar cells. The photoluminescence (PL) and its excitation spectrum (PLE) showed the contribution of the higher excited states (ESs) forming the miniband of the QDSLs above the in homogeneously distributed ground states (GSs). TSPA of subbandgap photons efficiently occurs when electrons are pumped from the valence band (VB) to the higher ESs. When the higher ESs were resonantly excited, the superlinear excitation power dependence of the PL intensity appeared. Moreover, time-resolved PL showed that the electron lifetime is extended. These results demonstrate that the excited electron and hole separately relax into QDSLs, and thereby, enhancing the second sub-bandgap absorption.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
We have studied detailed carrier generation process in the two-step photon absorption and influence of thermal carrier escape in quantum-dot intermediate-band solar cells (QD-IBSC). The photocurrent created by the two-step photon absorption shows saturation as the inter-band excitation intensity becomes strong, and the inter-band excitation intensity showing the saturation behavior strongly depends on the inter-subband excitation intensity. To interpret this phenomenon, we carried out a theoretical simulation based on carrier dynamics considering carrier generation, energy relaxation and thermal carrier escape. The results indicate that the photocurrent saturation is caused by filling the intermediate states. The shift of the saturation point depending on the inter-subband excitation intensity is caused by the shift of the quasi-Fermi level for the intermediate states.
SPIE-INT SOC OPTICAL ENGINEERING, 2015, PHYSICS SIMULATION AND PHOTONIC ENGINEERING OF PHOTOVOLTAIC DEVICES IV, 9358, EnglishInternational conference proceedings
[Refereed]
Scientific journal
We investigated the effects of an increase in the barrier height on the enhancement of the efficiency of two-step photo-excitation in InAs quantum dot (QD) solar cells with a dot-in-well structure. Thermal carrier escape of electrons pumped in QD states was drastically reduced by sandwiching InAs/GaAs QDs with a high potential barrier of Al0.3Ga0.7As. The thermal activation energy increased with the introduction of the barrier. The high potential barrier caused suppression of thermal carrier escape and helped realize a high electron density in the QD states. We observed efficient two-step photon absorption as a result of the high occupancy of the QD states at room temperature. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Aug. 2014, JOURNAL OF APPLIED PHYSICS, 116 (6), pp. 063510 - 1-5, English[Refereed]
Scientific journal
Book review
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Poster presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
IEEE Electron Devices Society Membership
Jan. 2018 - PresentIEEE Membership
Jan. 2018 - Present応用物理学会 正会員
Jan. 2017 - PresentCompetitive research funding
Competitive research funding