KITA Takashi | ![]() |
Graduate School of Engineering / Department of Electrical and Electronic Engineering | |
Professor | |
Applied Science |
Sep. 2022 9th International Symposium on Control of Semiconductor Interfaces (ISCSI-XI), ISCSI-XI Young Researcher Award, Photoluminescence Characteristics of InAs Quantum Dots in the Doubled-heterointerface of AlGaAs/GaAs-based Two-step Photon Up-conversion Solar Cells
Jun. 2020 47TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC 47), PVSC 47 Best Student Paper Award, Up-converted photocurrent enhancement in modulation-doped two-step photon up-conversion
Mar. 2020 日本材料学会, 令和元年度日本材料学会論文賞, デュアルヘテロダイン干渉計により光源起因のノイズを低減したサブナノメートル精度ウエハフラットネス計測システム
Oct. 2019 電子材料シンポジウム, EMS賞, Efficient Laser Cooling in Rare-Earth Doped Oxides at High Temperature
Sep. 2019 SemiconNano, SemiconNano2019 Best Poster Award, Laser Cooling Utilizing Anti-Stokes Photoluminescence in Yb-Doped Yttrium Aluminum Garnet
Jul. 2018 日本材料学会半導体エレクトロニクス部門委員会, 日本材料学会半導体エレクトロニクス部門委員会平成30年度第1回研究会 学生優秀講演賞, Yb添加Yttrium-Aluminum化合物による固体レーザー冷却
Jul. 2017 日本材料学会半導体エレクトロニクス部門委員会, 日本材料学会半導体エレクトロニクス部門委員会 平成29年度第1回研究会 学生優秀講演賞, 低温キャップInAs/GaAs量子ドット超格子中間バンド型太陽電池における2段階光吸収の増強
Sep. 2015 応用物理学会, 応用物理学会フェロー表彰 第9回(2015年度), 半導体ナノ電子材料の構造制御と電子状態・光物性に関する研究
Dec. 2014 第25回光物性研究会, 光物性研究会奨励賞, InAs/GaAs量子ドット超格子太陽電池における高効率2段階光吸収過程
Nov. 2014 日本材料学会半導体エレクトロニクス部門委員会, 日本材料学会半導体エレクトロニクス部門委員会 平成24年度第3回研究会 学生優秀講演賞, 低次元量子構造を利用したホットキャリア型太陽電池の提案
Sep. 2014 応用物理学会, APEX/JJAP編集貢献賞, 2014年度(第13回)
Jul. 2014 平成26年度第2回半導体エレクトロニクス部門委員会第1回研究会, 日本材料学会半導体エレクトロニクス部門委員会平成26年度第1回研究会学生優秀講演賞, Dot-in-Well構造を用いた量子ドット太陽電池の室温二段階光吸収
Jun. 2014 40th IEEE Photovoltaic Special Conference, PVSC40 Best Student Paper Award, Carrier Time-of-Flight Measurement Using a Probe Structure for DirectEvaluation of Carrier Transport in Quantum Structure Solar Cells
Mar. 2014 第36回(2014年春季)応用物理学会, 応用物理学会講演奨励賞, プローブ構造を用いた量子構造太陽電池におけるキャリア走行時間の測定” トープラサートポン カシディット
Dec. 2011 The 18th International Display Workshops, IDW'11 Outstanding Poster Paper Award, Effects of Argon Plasma Irradiation on Amorphous In-Ga-Zu-Ofilm Evaluated by Microwave Photoconductivity Decay Method
Dec. 2010 第21回光物性研究会, 第21回光物性研究会奨励賞, 希土類化合物半導体GdNにおけるバンド端光吸収の磁気光学特性
Oct. 2010 6th International Workshop on Nano-Scale Spectroscopy \Nanotechnology, NSS6 Student Award, Band-Edge Structure Induced by Ferromagnetic Spin Ordering in GdN Thin Films
Dec. 2009 日本材料学会半導体エレクトロニクス部門委員会, 日本材料学会半導体エレクトロニクス部門学生優秀講演賞, 希土類窒化物半導体GdNヘテロ構造の基礎物性
Mar. 2009 財団法人エレクトロニクス実装学会, 第22回エレクトロニクス実装学会学術講演会優秀講演賞, 周期加熱サーモリフレクタンス法による銅めっき膜の熱伝導率評価
Dec. 2008 8th International Conference on Nano-Molecular Electronics 2008, ICNME2008 Outstanding Poster Presentation Award, Side Electron Emission Device Using A Composite of Carbon Nanofibers and Aluminum
Jul. 2008 ICOOPMA組織委員会, Best Poster Award, Lengthening of photoluminescence decay time owing to expansion of electron envelope functions in stacked quantum dots
Apr. 2008 電気関係学会関西支部連合大会実行委員会, 平成19年電気関係学会関西支部連合大会奨励賞, コラムナ量子ドットによる広帯域発光特性制御
Sep. 2007 応用物理学会, 応用物理学会講演奨励賞, InAs/GaAs量子ドット自己形成過程のRHEEDシェブロン構造のその場解析とIn拡散効果
Mar. 2007 日本金属学会, 金属学会写真奨励賞, 単一量子ドットの三次元微細構造解析
Nov. 2006 第67回応用物理学会学術講演会, 応用物理学会講演奨励賞, 高分解能断面TEMによる埋め込み量子ドット形状のマルチアングル直接観測
May 2005 神戸大学, 神戸大学工学部優秀教育賞
Nov. 2004 はりま産学交流会主催, シーズコンペ入賞, 超省電力次世代ディスプレイ材料の開発
Sep. 2000 第46回応用物理学関係連合講演会, 応用物理学会講演奨励賞, Ga0.5In0.5P/GaAsヘテロ界面における自然超格子の影響 - 偏光ラマンスペクトル -
Sep. 1999 第60回応用物理学会学術講演会, 応用物理学会講演奨励賞, 反射率差分光法によるInAs自己形成量子ドット成長表面の観察
Jul. 1998 電子材料シンポジウム運営委員会, EMS賞, Time-Resolved Up-Converted Photoluminescence at Semicoductor Heterointerface
Jul. 1995 The Material Research Society of Japan, 日本MRS若手研究者アワード, AlGaInP混晶半導体自然超格子の電子状態制御
Abstract We elucidate a photocarrier collection mechanism in intermediate band solar cells (IBSCs) with InAs-quantum dots (QDs)-in-an-Al0.3Ga0.7As/GaAs-quantum well structures. When the Al0.3Ga0.7As barrier is excited, the device electrical output can be varied by additional infrared light for the electron intraband optical transition in QDs. The photocurrent in IBSC with a single QDs-in-a-well structure shows a monotonic increase with the intraband-excitation density. Conversely, IBSC with a multilayered QDs-in-a-well structure exhibits a photocurrent reduction when electrons in QDs are optically pumped out. The simultaneously measured photoluminescence spectra proved that the polarity of QD states changes depending on the intraband-excitation density. We discuss the drift and diffusion current components and point out that the hole diffusion current is significantly influenced by carriers inside the confinement structure. Under strong intraband excitations, we consider an increased hole diffusion current occurs by blocking hole-capture in the quantum structures. This causes unexpected photocurrent reduction in the multilayered device.
IOP Publishing, 01 Jul. 2022, Japanese Journal of Applied Physics, 61 (7), 074002 - 074002[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Invited]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
[Refereed]
International conference proceedings
APL Editor's Picks
AIP Publishing, 21 Feb. 2021, Journal of Applied Physics, 129 (7), 074503 - 074503, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
International conference proceedings
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
International conference proceedings
We studied the dynamics of electrons generated by two-step photoexcitation in an intermediate-band solar cell (IBSC) comprising InAs/GaAs/Al0.3Ga0.7As dot-in-well (DWELL) structure using time-resolved photocurrent (TRPC) measurement. The examined IBSC exhibited considerably slower photocurrent decay than a conventional InAs/GaAs quantum dot IBSC, which is due to the extraordina
Nature Publishing Group, May 2019, Scientific Reports, 9, 7859 - 1-8, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Development of high-efficiency solar cells is one of the attractive challenges in renewable energy technologies. Photon up-conversion can reduce the transmission loss and is one of the promising concepts which improve conversion efficiency. Here we present an analysis of the conversion efficiency, which can be increased by up-conversion in a single-junction solar cell with a hetero-interface that boosts the output voltage. We confirm that an increase in the quasi-Fermi gap and substantial photocurrent generation result in a high conversion efficiency.
Nature Publishing Group, 01 Dec. 2018, Scientific Reports, 8 (1), pp. 872 - 1-8, English[Refereed]
Scientific journal
[Refereed]
International conference proceedings
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
We present a Si-photonics-based quantum dot heterogeneous tunable lasers in the 1-μm band. Optical devices using Si-photonics-based PIC in the 1-μm band probably have not been reported yet.
OSA - The Optical Society, 2018, Optics InfoBase Conference Papers, 2018, English[Refereed]
International conference proceedings
We have proposed a two-step photon up-conversion solar cell (TPU-SC), which is a single junction solar cell comprising a wide gap semiconductor (WGS) and a narrow gap semiconductor (NGS) to break through the Shockley-Queisser limit for the single-junction solar cells. In the TPU-SC, below-gap photons of WGS excite the NGS and accumulate electrons at the WGS / NGS hetero-interface. The accumulated electrons at the hetero-interface are easily excited towards the WGS barrier by the low-energy photons, resulting in the efficient two-step up-conversion (TPU). We have experimentally demonstrated highly efficient current generation by the TPU. In this paper, we present the concept of the TPU-SC, theoretical prediction of the conversion efficiency of the TPU-SC, and experimental result of efficient photocarrier collection attributable to the TPU phenomenon.
SPIE, 2018, Proceedings of SPIE - The International Society for Optical Engineering, 10527, English[Refereed]
International conference proceedings
We studied intermediate-band solar cells (IBSCs) incorporating highly homogeneous InAs/GaAs quantum dot superlattices (QDSLs). The extra photocurrent generated by two-step photon absorption markedly increases at the fundamental state (FS) because the FS miniband has been successfully formed in the QDSL-IBSC by controlling the QD size homogeneity. Here, the carriers excited into the miniband spatially separate in the internal electric field, and the long-lived electrons in the intermediate states of the miniband increase the inter-subband absorption strength. The two-step photocurrent response, therefore, extends toward the longer-wavelength side corresponding to the QDSL-FS at approximately 1.2 mu m. (C) 2018 The Japan Society of Applied Physics
IOP PUBLISHING LTD, Jan. 2018, APPLIED PHYSICS EXPRESS, 11 (1), pp. 012301 - 1-4, English[Refereed]
Scientific journal
Small numbers of nitrogen dopants dramatically modify the electronic properties of GaAs, generating spatially localized resonant states within the conduction band, pair and cluster states in the band gap, and very large shifts in the conduction-band energies with nonlinear concentration dependence. Cross-sectional scanning tunneling microscopy provides the local electronic structure of single nitrogen dopants at the (110) GaAs surface, yielding highly anisotropic spatial shapes when the empty states are imaged. Measurements of the resonant states relative to the GaAs surface states and their spatial extent allow an unambiguous assignment of specific features to nitrogen atoms at different depths below the cleaved (110) surface. Multiband tight-binding calculations around the resonance energy of nitrogen in the conduction band match the imaged features, verifying that the Green's function method can accurately describe the isolated isovalent nitrogen impurity. The spatial anisotropy is attributed to the tetrahedral symmetry of the bulk lattice and will lead to a directional dependence for the interaction of nitrogen atoms. Additionally, the voltage dependence of the electronic contrast for two features in the filled state imaging suggests these features could be related to a locally modified surface state.
AMER PHYSICAL SOC, Oct. 2017, PHYSICAL REVIEW B, 96 (15), pp. 155210 - 1-8, English[Refereed]
Scientific journal
We demonstrated hot-carrier effects in a solar cell containing InAs/GaAs quantum-dots superlattice structure as a light absorber. The bandgap of the host semiconductor plays an important role as an energy-selective barrier for hot carriers created in quantum-dot superlattices. The short circuit current density increases linearly with the excitation photon density, suggesting that two photons absorption or Auger recombination processes can be ignorable. Furthermore, we found that the open circuit voltage of the quantum-dot superlattice solar cell increases drastically in contrast to a solar cell containing conventional quantum dots without a superlattice structure. These results clarify effects of hot carrier population in the one-dimensional energy dispersion of the quantum-dot superlattice.
Society of Materials Science Japan, 01 Sep. 2017, Zairyo/Journal of the Society of Materials Science, Japan, 66 (9), 629 - 633, Japanese[Refereed]
Scientific journal
Energy transfer from an inorganic substrate to a cyanine molecule thin film has been investigated as an excitation method for organic luminescent devices. Cyanine molecule thin films were fabricated on a Si substrate by layer-by-layer assembly and were excited from the back side of the substrate to observe the luminescence. The luminescence intensity depends on the excitation power and excitation energy. Moreover, the dependence of the luminescence intensity on the excitation energy clearly shows a profile similar to the absorption spectrum of Si. These results indicate that luminescence is not due to the direct optical excitation of cyanine by the light transmitted through the substrate but due to the energy transfer from the photoexcited carriers in the substrate. Our results demonstrate that such energy transfer can be used to excite organic molecules on inorganic substrates without energy matching between the electrodes and luminescent materials.
PHYSICAL SOC JAPAN, Sep. 2017, JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 86 (9), pp. 094710 - 1-4, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We studied the effects of the internal electric field on two-step photocarrier generation in InAs/GaAs quantum dot superlattice (QDSL) intermediate-band solar cells (IBSCs). The external quantum efficiency of QDSL-IBSCs was measured as a function of the internal electric field intensity, and compared with theoretical calculations accounting for interband and intersubband photoexcitations. The extra photocurrent caused by the two-step photoexcitation was maximal for a reversely biased electric field, while the current generated by the interband photoexcitation increased monotonically with increasing electric field intensity. The internal electric field in solar cells separated photogenerated electrons and holes in the superlattice (SL) miniband that played the role of an intermediate band, and the electron lifetime was extended to the microsecond scale, which improved the intersubband transition strength, therefore increasing the two-step photocurrent. There was a trade-off relation between the carrier separation enhancing the two-step photoexcitation and the electric-field-induced carrier escape from QDSLs. These results validate that long-lifetime electrons are key to maximising the two-step photocarrier generation in QDSL-IBSCs.
NATURE PUBLISHING GROUP, Jul. 2017, SCIENTIFIC REPORTS, 7, pp. 5865 - 1-10, English[Refereed]
Scientific journal
Using X-band Ferromagnetic Resonance (FMR) Spectroscopy, we demonstrate the microscopic ferromagnetic resonance features of degenerated GdN semiconductor. The FMR spectrum suggests a single resonance mode below 10 K; interestingly, this particular structure is found to exhibit a peculiar magnetic resonance (PMR) on the top of the uniform FMR while temperature increases from 12-36 K. The low field PMR mode attributed to the differently magnetized part of the film with an easy in-plane axis. The narrow-field gap between PMR and uniform FMR suggests the strong coupling owning to the differently magnetized part with easy in-plane axis and the magnetized part with an out-of-plane axis. The saturation magnetization, cubic magnetocrystalline anisotropy, and uniaxial anisotropy of GdN epitaxial film have been evaluated by the angular-dependence FMR. (C) 2017 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE BV, Jun. 2017, PHYSICS LETTERS A, 381 (22), 1905 - 1909, English[Refereed]
Scientific journal
We studied the effects of miniband formation on the photocurrent generated by two-step intersubband absorption in an intermediate-band solar cell incorporating an InAs/GaAs quantum dot superlattice (QDSL). The two-step photocarrier generation increases with the electronic state coupling of InAs QDSLs in the intrinsic layer. Because carriers that are excited into the superlattice minibands spatially separate in an internal electric field, the electron-hole recombination rate for the photoexcited carriers decreases, and therefore, the electron lifetime increases. The long-lived electrons in the intermediate states of the QDSL miniband increase the intersubband absorption strength. We confirmed a systematic sensitive change in the two-step photocurrent generation depending on the miniband formation controlled by the temperature. Published by AIP Publishing.
AMER INST PHYSICS, May 2017, APPLIED PHYSICS LETTERS, 110 (19), pp. 193104 - 1-5, English[Refereed]
Scientific journal
Reducing the transmission loss for below-gap photons is a straightforward way to break the limit of the energy-conversion efficiency of solar cells (SCs). The up-conversion of below-gap photons is very promising for generating additional photocurrent. Here we propose a two-step photon up-conversion SC with a hetero-interface comprising different bandgaps of Al0.3Ga0.7As and GaAs. The below- gap photons for Al0.3Ga0.7As excite GaAs and generate electrons at the hetero-interface. The accumulated electrons at the hetero-interface are pumped upwards into the Al0.3Ga0.7As barrier by below- gap photons for GaAs. Efficient two-step photon up-conversion is achieved by introducing InAs quantum dots at the hetero-interface. We observe not only a dramatic increase in the additional photocurrent, which exceeds the reported values by approximately two orders of magnitude, but also an increase in the photovoltage. These results suggest that the two-step photon up-conversion SC has a high potential for implementation in the next-generation high-efficiency SCs.
NATURE PUBLISHING GROUP, Apr. 2017, NATURE COMMUNICATIONS, 8, pp. 14962 - 1-9, English[Refereed]
Scientific journal
[Refereed]
[Refereed]
Scientific journal
Quantum dot (QD) is one of the attractive materials. In this paper, we focus on advanced photonic devices using QD structure and its applications for the next generation access networks.
OSA - The Optical Society, 2017, Optics InfoBase Conference Papers, 2017, English[Refereed]
International conference proceedings
We proposed a tunable dual-mode heterogeneous quantum dot laser diode with a Siphotonics-based photonic integrated circuit, and successfully demonstrated dual-mode lasing oscillation by tuning the differential frequency from approximately 20 GHz to 200 GHz.
OSA - The Optical Society, 2017, Optics InfoBase Conference Papers, 2017, English[Refereed]
International conference proceedings
In this study, we report the effect of the excitation of non-exciton components caused by broadband pulses on quantum beat oscillation. Using a spectrally controlled pump pulse, a long-lived oscillation is clearly observed, and the pump-power dependence shows the suppression of the dephasing rate of the oscillation. Our results from incoherent carrier generation using a continuous wave laser demonstrate that the non-exciton components behaving as free carriers increase the oscillation dephasing rate.
NATURE PUBLISHING GROUP, Jan. 2017, Scientific Reports, 7, pp. 41496 - 1-7, English[Refereed]
Scientific journal
We studied time-resolved photocarrier transport through InAs/GaAs quantum dot superlattice (QDSL) solar cells (SCs) using time-of-flight spectroscopy with an optical probe QD structure beneath the QDSL. Carriers optically pumped in the top p-GaAs layer were transported through the intrinsic layer, including the QDSLs, before arriving at the probe QDs. The photoexcited carrier density significantly influenced the time-resolved photoluminescence (PL) of the QDSLs and probe QDs. The time-resolved PL profile of the probe QDs indicated that excitation densities in excess of 25nJ/cm(2) drastically decreased the rise time, suggesting rapid carrier transport through the QDSLs. This was also confirmed by QDSL carrier transport dynamics, for which the PL intensity of the excited states decayed rapidly above this excitation power density, 25nJ/cm(2), while the ground state remained constant. These results demonstrate that filling the ground states of QDSLs and starting to populate the excited state miniband accelerates carrier transport in QDSL SCs. Furthermore, according to two-step photon absorption measurements taken with a 1.3-mu m infrared laser light source, electrons play a key role in the generation of extra photocurrent by sub-band-gap photon irradiation.
AMER PHYSICAL SOC, Nov. 2016, PHYSICAL REVIEW B, 94 (19), pp. 195313 - 1 -9, English[Refereed]
Scientific journal
We studied the polarization anisotropy of electroluminescence (EL) and net modal gain characteristics of laser device structures containing 40 stacked InAs/GaAs quantum dot (QD) layers. The electronic coupling between the closely stacked QDs enhanced the transverse-magnetic (TM) polarization component owing to the heavy-and light-hole mixing. Thereby, the [110]-waveguide devices exhibited a laser oscillation of not only the transverse-electric (TE) but also the TM component. Laser oscillation occurred at 1137nm from the first excited state for the 300-mu m-long cavity, while it occurred at 1167 nm from the ground state for the 1000-mu m-long cavity. The polarization anisotropy of the EL intensity strongly depended on the injection current density. The polarized EL intensity was almost isotropic at low injection current density. As the injection current density was increased, the TE component was gradually enhanced, which resulted in a markedly TE-dominant anisotropy above the threshold current density for laser oscillation. The net modal gains evaluated using the Hakki-Paoli method also exhibited a TE-enhanced characteristic with increasing injection current density. As the EL spectra of the TE component have an inhomogeneous broadening narrower than that of the TM component, the TE-mode intensity is likely to be enhanced by the concentration of the injected carriers. Published by AIP Publishing.
AMER INST PHYSICS, Oct. 2016, JOURNAL OF APPLIED PHYSICS, 120 (13), pp. 134313 - 1-6, English[Refereed]
Scientific journal
We studied effects of the internal electric field on the two-step photocurrent generation in quantum dot superlattice (QDSL) solar cells. We calculated the quantum efficiency of intersubbad photoexcited carriers in QDSL as a function of the internal electric field. In our calculation, we proposed a model of a QDSL structure in which electrons created by the interband transition are excited by subbandgap photons corresponding to the intersubband transition. We found that extra photocurrent caused by the two-step photoexcitation shows the maximum at a reverse biased electric field, whereas current generated by only the interband photoexcitation increases monotonically with increasing the electric field. The internal electric field of the solar cell can separate photocreated electron and hole in the SL miniband, and electron lifetime is extended, which improve the intersubband transition strength, and, therefore, the two-step photocurrent increases. Thus, the calculated result unveils that there is a trade-off relation between carrier separation in the SL miniband and electric-field induced carrier escape from QDSL. These results clarify that long electron lifetime extended by carrier separation is a key maximizing the two-step photocurrent generation in a QDSL solar cell.
Society of Materials Science Japan, 01 Sep. 2016, Zairyo/Journal of the Society of Materials Science, Japan, 65 (9), 647 - 651, Japanese[Refereed]
Scientific journal
© 2016 The Society of Materials Science, Japan. Thin film solar cells using perovskite materials are very intensively studied since the perovskite materials such as CH3NH3PbI3 crystal have been found to show sensitizing effects on a TiO2 electron transport layer. This class of solar cell has made tremendous progress during the last few years, leading to a recently certified record power conversion efficiency (PCE) of 21.02%. In the perovskite /crystalline-Si (c-Si) tandem solar cell, furthermore, the theoretical value of PCE is expected as large as 35 %. Toward this application, the perovskite solar cell must be highly transparent at near-infrared wavelengths so that sufficient light is transmitted to the narrow-bandgap bottom cell. In this study, we fabricated the organic-lead halide perovskite solar cells comprising a transparent sputtered indium tin oxide (ITO) top electrode. We observed the PCE of 1.5% in transparent perovskite solar cells with a thin molybdenum oxide buffer layer and ITO electrode. Moreover, we obtained the PCE of 2% even in solar cells with ITO electrode sputtered directly on the organic charge transport layer. The photovoltaic property could be confirmed under the light irradiation from the ITO top electrode side.
Sep. 2016, Zairyo/Journal of the Society of Materials Science, Japan, 65 (9), 642 - 646[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
We report an increase in exciton decay rates because of long-range interaction based on surface charge between cyanine thin films. The dependence of the decay rate on the spatial separation between the cyanine molecule layers shows that the rate is almost constant, which is different from the well-known energy transfer process. The rate is hardly affected by the fluctuation of the film thickness, which is an advantage of using cyanine or organic molecules. (C) 2016 Author(s).
AMER INST PHYSICS, Jul. 2016, AIP ADVANCES, 6 (7), pp. 075209 - 1-7, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We studied the structural and photoluminescence (PL) characteristics of InAs quantum dots (QDs) grown on nitrogen (N) (5-doped GaAs(001). The emission wavelength for low-density N-delta doping exhibited a blueshift with respect to that for undoped GaAs and was redshifted with increasing N-sheet density. This behavior corresponded to the variation in the In composition of the QDs. N-delta doping has two opposite and competing effects on the incorporation of Ga atoms from the underlying layer into the QDs during the QD growth. One is the enhancement of Ga incorporation induced by the lattice strain, Which is due to the smaller radius of N atoms. The other is an effect blocking for Ga incorporation, which is due to the large bonding energy of Ga-N or In-N. At a low N-sheet density, the lattice-strain effect was dominant, while the blocking effect became larger with increasing N-sheet density, Therefore, the incorporation of Ga from the underlying layer depended on the N-sheet density. Since the In-Ga intermixing between the QDs and the GaAs cap layer during capping also depended on the size of the as-grown QDs, which was affected by the N-sheet density, the superposition of these three factors determined the composition of the QDs. in addition, the piezoelectric effect, which was induced with increased accumulation of lattice strain and the associated high In composition, also affected the PL properties of the QDs. As a result, tuning of the emission wavelength from 1. to 1.26 mu m was achieved at room temperature. Published by AIP Publishing.
AMER INST PHYSICS, May 2016, JOURNAL OF APPLIED PHYSICS, 119 (19), pp. 194306 - 1-8, English[Refereed]
Scientific journal
We studied in detail the photocurrent generation process in two-step photon absorption in intermediate-band solar cells, including InAs quantum dots embedded in Al0.3Ga0.7As/GaAs quantum wells at room temperature. The photocurrent generated by the two-step photon absorption exhibited saturation as the interband excitation intensity increased in strength. On the other hand, as the intersubband excitation intensity increased, the two-step photoexcitation current deviated from a power law. Furthermore, the two-step photoexcitation current exhibiting saturation and deviation strongly depended on both the interband and intersubband excitation intensities. To interpret these phenomena, we performed a theoretical simulation of the two-step photoexcitation current. The results suggest that the photocurrent saturation and deviation were caused by filling of the intermediate states with electrons. Furthermore, our calculated results indicate that the electron-recombination lifetime in the intermediate states is extremely long. The results of the temperature dependence of the two-step photoexcitation current and the excitation intensity dependence of photoluminescence suggest that efficient electron-hole separation extends electron lifetime.
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, Mar. 2016, IEEE JOURNAL OF PHOTOVOLTAICS, 6 (2), 465 - 472, English[Refereed]
Scientific journal
We report the time-resolved photoluminescence spectroscopy of nanoseconds-scale hot-carrier (HC) cooling dynamics in InAs/GaAs quantum dot superlattices (QDSLs). We demonstrate supra 1000-K time-averaged carrier temperature in the InAs/GaAs QDSLs from one-dimensional density of states restricting the phase space and energy-momentum conservation in the carrier scattering processes. The InAs/GaAs QDSLs HC energy dissipation rate was much smaller than that for InAs/GaAs multiple quantum wells and nearly excitation-photon-density independent, implying reduced efficiency of carrier-carrier scattering.
AMER PHYSICAL SOC, Mar. 2016, PHYSICAL REVIEW B, 93 (11), pp. 115303 - 1-5, English[Refereed]
Scientific journal
We have conducted rapid thermal annealing (RTA) for improving the two-dimensional (2D) arrangement of electronic states in the epitaxial nitrogen (N) delta-doped layer in GaAs. RTA rearranged the N-pair configurations in the GaAs (001) plane and reduced the number of non-radiative recombination centers. Furthermore, a Landau shift, representing the 2D delocalized electronic states in the (001) plane, was observed at around zero magnetic field intensity in the Faraday configuration. (C) 2016 AIP Publishing LLC.
AMER INST PHYSICS, Mar. 2016, APPLIED PHYSICS LETTERS, 108 (11), pp. 111905 - 1-4, English[Refereed]
Scientific journal
[Refereed]
[Refereed]
[Refereed]
[Refereed]
International conference proceedings
We studied electroluminescence and net-modal gain in 40-stacked InAs/GaAs quantum dot (QD) laser devices. Since the electronic coupling between the QDs enhanced the transverse-magnetic (TM) component, the [110] waveguide devices exhibited a laser oscillation in the TM component as well as the transverse-electric (TE) component.
IEEE, 2016, 2016 INTERNATIONAL SEMICONDUCTOR LASER CONFERENCE (ISLC), English[Refereed]
International conference proceedings
[Refereed]
International conference proceedings
[Refereed]
International conference proceedings
© 2016 SPIE. Multiple quantum well (MQW) solar cells have been explored as one promising next-generation solar cells toward high conversion efficiency. However, the dynamics of photogenerated carriers in MQWs are complicated, making it difficult to predict the device performance. Our purpose of this study is to investigate a model for the photocurrent component characteristics of MQW cells based on experimental findings. Using our proposed carrier time-of-flight technique, we have found that the carrier averaged drift velocity has linear dependence on the internal field regardless of complicated carrier cascade dynamics in MQW. This behavior is similar to carriers in bulk materials, allowing us to approximate the MQW region as a quasi-bulk material with specific effective drift mobility. With the effective drift mobility and equivalent material parameters such as effective density of states, the quasi-bulk approach reduces the device complexity, and the characteristics of such MQW cells can be simulated using the conventional drift-diffusion model. We have confirmed this model with experimentally obtained photocurrent characteristics. The simulation of carrier collection efficiency (CCE) - normalized photocurrent - based on the effective mobility approximation, or quasibulk approximation, agrees well with the experimental results when the carrier lifetime is set to be in the order of hundred nanoseconds. This simplified model enhances our understanding of the MQW cell operation and helps design the optimal structure for better performance.
2016, Proceedings of SPIE - The International Society for Optical Engineering, 9743 (974315), English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
We investigated the effects of the GaAs capping temperature on the morphological and photoluminescence (PL) properties of InAs quantum dots (QDs) on GaAs(001). The broadband tuning of the emission wavelength from 1.1 to 1.3 mu m was achieved at room temperature by only adjusting the GaAs capping temperature. As the capping temperature was decreased, the QD shrinkage due to In desorption and In-Ga intermixing during the capping process was suppressed. This led to QDs with a high aspect ratio, and resultantly, the emission wavelength shifted toward the longer-wavelength side. In addition, the linearly polarized PL intensity elucidated anisotropic characteristics reflecting the shape anisotropy of the embedded QDs, in which a marked change in polarization anisotropy occurred at capping temperatures lower than 460 degrees C. (C) 2015 AIP Publishing LLC.
AMER INST PHYSICS, Oct. 2015, JOURNAL OF APPLIED PHYSICS, 118 (15), pp. 154301 - 1-6, English[Refereed]
Scientific journal
We systematically studied two-step photocurrent generation as functions of the excitation intensities for the interband and inter-subband transitions in an InAs/GaAs/Al0.3Ga0.7As dot-in-well (DWELL) intermediate-band solar cell. The two-step photoexcitation current shows saturation as the inter-band excitation intensity becomes strong, and we found that the inter-band excitation intensity showing the current saturation strongly depends on the inter-subband excitation intensity. To interpret the current-saturation behavior, we proposed a model and carried out theoretical simulation. Simulated results excellently reproduce the experimental observations. It has been clarified that the photocurrent saturation is caused by filling the intermediate states with electrons. Furthermore, the recombination lifetime in DWELL was pointed out to be extremely long. Our results suggest that this carrier lifetime is an important key to realize strong enhancement of two-step photoexcitation.
Society of Materials Science Japan, 01 Sep. 2015, Zairyo/Journal of the Society of Materials Science, Japan, 64 (9), 690 - 695, Japanese[Refereed]
Scientific journal
We performed modal analysis for 40-stacked InAs/GaAs quantum dot semiconductor optical amplifiers (QDSOAs) as a function of the waveguide width using an equivalent refractive index technique. QDSOAs with 5- and 11-μm-waveguide widths show multi-mode operations. The theoretical simulation reproduced well the experimental electroluminescence spectrum and unveiled that the output signals comprise several transverse modes. Besides, we confirmed a waveguide width less than 1.28 μm is essential to realize single-mode QDSOAs. The modal gain spectra were analyzed by using the Hakki-Paoli method. Multi peaks arisen from the multi-mode operation were also observed in the gain spectrum, suggesting precise control of the transverse mode is important for a practical realization of the single-mode device.
Society of Materials Science Japan, 01 Sep. 2015, Zairyo/Journal of the Society of Materials Science, Japan, 64 (9), 685 - 689, Japanese[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
We systematically studied two-step photocurrent generation as functions of the excitation intensities for the interband and inter-subband transitions in an InAs/GaAs/Al0.3Ga0.7As dot-in-well (DWELL) intermediate-band solar cell. The two-step photoexcitation current shows saturation as the inter-band excitation intensity becomes strong, and we found that the inter-band excitation intensity showing the current saturation strongly depends on the inter-subband excitation intensity. To interpret the current-saturation behavior, we proposed a model and carried out theoretical simulation. Simulated results excellently reproduce the experimental observations. It has been clarified that the photocurrent saturation is caused by filling the intermediate states with electrons. Furthermore, the recombination lifetime in DWELL was pointed out to be extremely long. Our results suggest that this carrier lifetime is an important key to realize strong enhancement of two-step photoexcitation.
Society of Materials Science Japan, 01 Sep. 2015, Zairyo/Journal of the Society of Materials Science, Japan, 64 (9), 690 - 695, Japanese[Refereed]
Scientific journal
[Refereed]
Scientific journal
In this study, we propose a carrier time-of-flight technique to evaluate the carrier transport time across a quantum structure in an active region of solar cells. By observing the time-resolved photoluminescence signal with a quantum-well probe inserted under the quantum structure at forward bias, the carrier transport time can be efficiently determined at room temperature. The
{AIP} Publishing, Jul. 2015, Applied Physics Letters, 107 (4), 043901 - 043901, English[Refereed]
Scientific journal
We report the optical properties of the cyanine dye molecule thin film fabricated by a layer-by-layer method. While the absorbance and the film thickness increase with the dipping time, the use of a multilayer structure enables fabrication of the thin film without the creation of the molecule bundle that suppresses light scattering and the large absorbance obtained for the shorter dipping time. Exciton dynamics are studied by using a pump-probe technique; the signal shows two decay components in the multilayer sample that originate from the fast intramolecular relaxation and from the slow exciton relaxation. The temporal profiles show at the high signal-to-noise ratio. These results indicate that the thin film without the creation of the molecule bundle fabricated by the layer-by-layer method can be used for ultrafast all-optical switches.
IOP PUBLISHING LTD, Jul. 2015, MATERIALS RESEARCH EXPRESS, 2 (7), pp. 076402 - 1-7, English[Refereed]
Scientific journal
Extensive literature and publications on intermediate band solar cells (IBSCs) are reviewed. A detailed discussion is given on the thermodynamics of solar energy conversion in IBSCs, the device physics, and the carrier dynamics processes with a particular emphasis on the two-step inter-subband absorption/recombination processes that are of paramount importance in a successful implementation high-efficiency IBSC. The experimental solar cell performance is further discussed, which has been recently demonstrated by using highly mismatched alloys and high-density quantum dot arrays and superlattice. IBSCs having widely different structures, materials, and spectral responses are also covered, as is the optimization of device parameters to achieve maximum performance. (C) 2015 AIP Publishing LLC.
AMER INST PHYSICS, Jun. 2015, APPLIED PHYSICS REVIEWS, 2 (2), pp. 021302 - 1-48, English[Refereed]
Scientific journal
We studied the two-step photon absorption (TSPA) process in InAs/GaAs quantum-dot superlattice (QDSL) solar cells. TSPA of subband-gap photons efficiently occurs when electrons are pumped from the valence band to the states above the inhomogeneously distributed fundamental states of QDSLs. The photoluminescence (PL)-excitation spectrum demonstrates an absorption edge attributed to the higher excited states of the QDSLs in between the InAs wetting layer states and the fundamental states of QDSLs. When the absorption edge of the excited state was resonantly excited, the superlinear excitation power dependence of the PL intensity demonstrated that the electron and hole created by the interband transition separately relax into QDSLs. Furthermore, time-resolved PL measurements demonstrated that the electron lifetime is extended by thereby inhibiting recombination with holes, enhancing the second subband-gap absorption.
AMER PHYSICAL SOC, May 2015, PHYSICAL REVIEW B, 91 (20), pp. 201303 - 1-6, English[Refereed]
Scientific journal
We studied energy transfer from AlN to doped Gd3+ ions as a function of the post-thermal annealing temperature. Gd-doped AlN thin films were deposited on fused-silica substrates using a reactive radio-frequency magnetron sputtering technique. The film is a c-axis oriented polycrystal. The intra-orbital electron transition in Gd3+ showed an atomically sharp luminescence at 3.9 eV (318nm). The photoluminescence (PL) excitation spectrum exhibited a resonant peak, indicating efficient energy transfer from the host AlN crystal to Gd3+ ions. The PL intensity increases approximately ten times by thermal annealing. The PL decay lifetime becomes long with annealing, and mid-gap luminescence relating to the crystal defects in AlN was also found to be reduced by annealing. These results suggest that energy dissipation of excited carriers in AlN was suppressed by annealing, and the efficiency of energy transfer into Gd3+ was improved. (C) 2015 AIP Publishing LLC.
AMER INST PHYSICS, Apr. 2015, JOURNAL OF APPLIED PHYSICS, 117 (16), pp. 193105 - 1-5, English[Refereed]
Scientific journal
We discuss the dephasing of quantum beat oscillation related to the intersubband transition between heavy-hole and light-hole excitons in a GaAs/AlAs multiple quantum well as measured by a pump-probe technique. We investigate the dependence of dephasing on temperature and pump energy. The analysis of the time-domain signals reveals that a strong quantum beat induces the rapid dephasing related to intersubband transition; the dependencies of the dephasing rate correspond to those of the amplitude. This implies that a quantum beat is useful in applications utilizing an ultrafast optical response.
AMER PHYSICAL SOC, Mar. 2015, PHYSICAL REVIEW B, 91 (12), pp. 125307 - 1-4, English[Refereed]
Scientific journal
[Refereed]
[Refereed]
[Refereed]
[Refereed]
We studied time-resolved carrier transport through InAs/GaAs quantum dot superlattice (QDSL) solar cells, using time-of-flight spectroscopy with an optical probe structure lying beneath the QDSL. The density of photoexcited carriers in the top p-GaAs layer significantly influences the time-resolved photoluminescence (TRPL) of probe while TRPL of QDSL keeps unchanged. Also, the PL intensity of probe showed exponential increase as the excitation pulse energy increased, which may indicate that the dynamics of holes rule the dynamics observed in TRPL. The induced filling of QD states by strong excitation leads to the condition where carries travel over the QDSL and reach the probe faster.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
We have studied detailed photocurrent generation process in the two-step photon absorption in intermediate-band solar cells including InAs quantum dots embedded in Al0.3Ga0.7As/GaAs quantum wells and influence of thermal carrier escape at room temperature. The photocurrent generated by the two-step photon absorption shows saturation as the inter-band excitation intensity becomes strong. and the inter-band excitation intensity showing the saturation behavior strongly depends on the inter-subband excitation intensity. To interpret this phenomenon. we carried out a theoretical simulation based on carrier dynamics considering carrier generation. energy relaxation and thermal carrier escape. The results indicate that the photocurrent saturation is caused by filling the intermediate states with electrons. The shift of the saturation point depending on the inter-subband excitation intensity is caused by the shift of the quasi-Fermi level for the intermediate states.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
A difficulty of carrier transport in multiple quantum well ( MQW) solar cells is one critical issue that limits their cell performance. Here, direct measurement of electron and hole transport times across InGaAs/GaAsP MQWs has been carried out using our proposed time-of-flight measurement technique on p-on-n and n-on-p MQW structures, respectively. The corresponding effective mobilities are determined, allowing us to approximate the MQW region as a quasi-bulk material with smaller carrier mobilities than a bulk crystal. The result shows similar effective electron and hole mobilities. This results in the similar tendency of cell performance in p-on-n and n-on-p MQW solar cells.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
GaAsSbN is an alloy that can achieve 1 eV bandgap lattice-matched to GaAs. The alloy may be an interesting alternative to the more common GaInNAs(Sb) used in high efficiency multi-junction solar cells, as GaAsSbN shows enhanced nitrogen incorporation. We present photoluminescence (PL) and time-resolved photoluminescence (TRPL) measurements taken using a streak camera for a range of double-heterostructure samples. Layers of different thickness and doping are investigated. Effective minority carrier lifetimes are 200-450 ps at room temperature. A difference in behaviour with dopant polarity is noted, with p-type material exhibiting longer minority carrier lifetimes.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
We studied the two-step photon absorption (TSPA) process in InAs/GaAs quantum-dot superlattice (QDSL) solar cells. The photoluminescence (PL) and its excitation spectrum (PLE) showed the contribution of the higher excited states (ESs) forming the miniband of the QDSLs above the in homogeneously distributed ground states (GSs). TSPA of subbandgap photons efficiently occurs when electrons are pumped from the valence band (VB) to the higher ESs. When the higher ESs were resonantly excited, the superlinear excitation power dependence of the PL intensity appeared. Moreover, time-resolved PL showed that the electron lifetime is extended. These results demonstrate that the excited electron and hole separately relax into QDSLs, and thereby, enhancing the second sub-bandgap absorption.
IEEE, 2015, 2015 IEEE 42ND PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC), English[Refereed]
International conference proceedings
The microscopic magnetic properties of high-quality GdN thin films have been investigated by electron spin resonance (ESR) and ferromagnetic resonance (FMR) measurements. Detailed temperature dependence ESR measurements have shown the existence of two ferromagnetic components at lower temperatures, which was not clear from the previous magnetization measurements. The temperature, where the resonance shift occurs for the major ferromagnetic component, seems to be consistent with the Curie temperature obtained from the previous magnetization measurement. On the other hand, the divergence of line width is observed around 57K for the minor ferromagnetic component. The magnetic anisotropies of GdN thin films have been obtained by the analysis of FMR angular dependence observed at 4.2K. Combining the X-ray diffraction results, the correlation between the magnetic anisotropies and the lattice constants is discussed. (C) 2015 AIP Publishing LLC.
AMER INST PHYSICS, Jan. 2015, JOURNAL OF APPLIED PHYSICS, 117 (4), 043909 - 1~6, English[Refereed]
Scientific journal
We have studied detailed carrier generation process in the two-step photon absorption and influence of thermal carrier escape in quantum-dot intermediate-band solar cells (QD-IBSC). The photocurrent created by the two-step photon absorption shows saturation as the inter-band excitation intensity becomes strong, and the inter-band excitation intensity showing the saturation behavior strongly depends on the inter-subband excitation intensity. To interpret this phenomenon, we carried out a theoretical simulation based on carrier dynamics considering carrier generation, energy relaxation and thermal carrier escape. The results indicate that the photocurrent saturation is caused by filling the intermediate states. The shift of the saturation point depending on the inter-subband excitation intensity is caused by the shift of the quasi-Fermi level for the intermediate states.
SPIE-INT SOC OPTICAL ENGINEERING, 2015, PHYSICS SIMULATION AND PHOTONIC ENGINEERING OF PHOTOVOLTAIC DEVICES IV, 9358, English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
International conference proceedings
We report upconversion photoluminescence (UCPL) in GaAs/AlAs multiple quantum wells. UCPL from the AlAs barrier is caused by the resonant excitation of the excitons in the GaAs well. When the quantum well has sufficient miniband width, UCPL is hardly observed because of the small exciton oscillator strength. The excitation-energy and excitation-density dependences of UCPL intensity show the exciton resonant profile and a linear increase, respectively. These results demonstrate that the observed UCPL caused by the saturated two-step excitation process requires a large number of excitons. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Nov. 2014, APPLIED PHYSICS LETTERS, 105 (18), pp. 1 - 3, English[Refereed]
Scientific journal
We propose a high-conversion-efficiency solar cell (SC) utilizing the hot carrier (HC) population in an intermediate-band (IB) of a quantum dot superlattice (QDSL) structure. The bandgap of the host semiconductor in this device plays an important role as an energy-selective barrier for HCs in the QDSLs. According to theoretical calculation using the detailed balance model with an air mass 1.5 spectrum, the optimum IB energy is determined by a trade-off relation between the number of HCs with energy exceeding the conduction-band edge and the number of photons absorbed by the valence band-IB transition. Utilizing experimental data of HC temperature in InAs/GaAs QDSLs, the maximum conversion efficiency under maximum concentration (45 900 suns) has been demonstrated to increase by 12.6% as compared with that for a single-junction GaAs SC. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Oct. 2014, APPLIED PHYSICS LETTERS, 105 (17), pp. 1 - 5, English[Refereed]
Scientific journal
We investigated the effects of an increase in the barrier height on the enhancement of the efficiency of two-step photo-excitation in InAs quantum dot (QD) solar cells with a dot-in-well structure. Thermal carrier escape of electrons pumped in QD states was drastically reduced by sandwiching InAs/GaAs QDs with a high potential barrier of Al0.3Ga0.7As. The thermal activation energy increased with the introduction of the barrier. The high potential barrier caused suppression of thermal carrier escape and helped realize a high electron density in the QD states. We observed efficient two-step photon absorption as a result of the high occupancy of the QD states at room temperature. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Aug. 2014, JOURNAL OF APPLIED PHYSICS, 116 (6), pp. 063510 - 1-5, English[Refereed]
Scientific journal
The polarized optical gain characteristics of highly stacked InAs/GaAs quantum dots (QDs) with a thin spacer layer fabricated on an n(+)-GaAs (001) substrate were studied in the sub-threshold gain region. Using a 4.0-nm-thick spacer layer, we realized an electronically coupled QD superlattice structure along the stacking direction, which enabled the enhancement of the optical gain of the [001] transverse-magnetic (TM) polarization component. We systematically studied the polarized electroluminescence properties of laser devices containing 30 and 40 stacked InAs/GaAs QDs. The net modal gain was analyzed using the Hakki-Paoli method. Owing to the in-plane shape anisotropy of QDs, the polarization sensitivity of the gain depends on the waveguide direction. The gain showing polarization isotropy between the TM and transverse-electric polarization components is high for the [110] waveguide structure, which occurs for higher amounts of stacked QDs. Conversely, the isotropy of the [similar to 110] waveguide is easily achieved even if the stacking is relatively low, although the gain is small. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Jun. 2014, JOURNAL OF APPLIED PHYSICS, 115 (23), 233512 - 1-5, English[Refereed]
Scientific journal
We studied the efficient indirect excitation of Gd3+ ions in AlN thin films. C-axis oriented polycrystalline thin films of Al0.997Gd0.003N/AlN were grown on fused silica substrates using a reactive radio-frequency magnetron sputtering technique. The intra-orbital electron transition in Gd3+ showed a narrow luminescence line at 3.9 eV. The photoluminescence (PL) excitation (PLE) spectrum exhibited a peak originating from efficient indirect energy transfer from the band edge of AlN to Gd3+ ions. The PLE peak shifted and the PL intensity showed a dramatic change when the AlN band gap was varied by changing the temperature. Energy scanning performed by changing the band-gap energy of AlN with temperature revealed several resonant channels of energy transfer into the higher excited states of Gd3+. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, May 2014, JOURNAL OF APPLIED PHYSICS, 115 (17), 173508 - 1-6, English[Refereed]
Scientific journal
Using the near-infrared (NIR) absorbance spectroscopy, electronic transitions and spin polarization of the GdN epitaxial film have been investigated; and the GdN epitaxial film was grown by a reactive rf sputtering technique. The GdN film exhibited three broad bands in the NIR frequency regimes; and those bands are attributable primarily to the minority and majority spin transitions at the X-point and an indirect transition along the Gamma-X symmetric direction of GdN Brillouin zone. We experimentally observe a pronounced red-shift of the indirect band gap when cooling down below the Curie temperature which is ascribed to the orbital-dependent coulomb interactions of Gd-5dxy electrons, which tend to push-up the N-2p bands. On the other hand, we have evaluated the spin polarization of 0.17 (+/- 0.005), which indicates that the GdN epitaxial film has almost 100% spin-polarized carriers. Furthermore, the experimental result of GdN electronic transitions are consistent with the previous reports and are thus well-reproduced. The Arrott plots evidenced that the Curie temperature of GdN film is 36K and the large spin moment is explained by the nitrogen vacancies and the intra-atomic exchange interaction. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, May 2014, JOURNAL OF APPLIED PHYSICS, 115 (20), 203717 - 1-5, English[Refereed]
Scientific journal
[Refereed]
We report pulse modulation caused by the exciton quantum beat in a GaAs/AlAs multiple quantum well. The modulation was evaluated by measuring the cross-correlation signal, which is the second harmonic light generated by the probe pulse reflected from the sample and the gate pulse. The intensity of the correlation-signal decreases owing to the generation of the exciton quantum beat, and recovers with dephasing of the quantum beat oscillation. Moreover, we found that the decrease caused by the quantum beat is larger than that by changing the refractive index due to the exciton generation. These results indicate that quantum beats can be a potential mechanism to enable low-power operation of ultrafast optical switches.
IOP PUBLISHING LTD, Mar. 2014, JOURNAL OF PHYSICS D-APPLIED PHYSICS, 47 (10), 105101 - 1~5, English[Refereed]
Scientific journal
We studied time-resolved carrier recombination in InAs/GaAs quantum dot (QD) solar cells. The electric field in a p-i-n diode structure spatially separates photoexcited carriers in QDs, strongly affecting the conversion efficiency of intermediate-band solar cells. The radiative decay lifetime is dramatically reduced in a strong electric field (193 kV/cm) by efficient recombination due to strong carrier localization in each QD and significant tunneling-assisted electron escape. Conversely, an electric field of the order of 10 kV/cm maintains electronic coupling in the stacked QDs and diminishes tunneling-assisted electron escape. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Feb. 2014, JOURNAL OF APPLIED PHYSICS, 115 (8), 083510 - 1-5, English[Refereed]
Scientific journal
We report the fabrication of cyanine dye molecule thin films by a layer-by-layer (LBL) method. In the LBL thin film, the photoluminescence properties can be controlled by the separation between the donor and acceptor dye molecule layers. While the distance dependence of the energy-transfer rate changes around 2 nm, which is comparable with the lengths of the molecules, the energy-transfer rate as evaluated from the photoluminescence decay time shows a maximum value of approximately 15 ns(-1). The thin films fabricated by the LBL method will be therefore applicable for ultrafast optical switches with higher repetition rate. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Feb. 2014, JOURNAL OF APPLIED PHYSICS, 115 (8), 083503 - 1~4, English[Refereed]
Scientific journal
We have grown an epitaxial two-dimensional nitrogen (N) atomic sheet in GaAs by using the site-controlled N delta-doping technique. We observed a change of the electronic states in N delta-doped GaAs from the isolated impurity centers to the delocalized impurity band at 1.49 eV with increasing N-doping density. According to the excitation-power-and temperature-dependent photoluminescence (PL) spectra, the emission related to localized levels below the impurity band edge was dominant at low excitation power and temperature, whereas the effects of the localized levels can be neglected by increasing the excitation power and temperature. Furthermore, a clear Landau shift of the PL-peak energy was observed at several Tesla in the Faraday configuration, in contrast to the case in the impurity limit. (C) 2014 AIP Publishing LLC.
AMER INST PHYSICS, Jan. 2014, APPLIED PHYSICS LETTERS, 104 (4), 041907 - 1~4, English[Refereed]
Scientific journal
[Refereed]
International conference proceedings
[Refereed]
Scientific journal
We have developed a technique to control the stacking direction of InAs/GaAs quantum dots (QDs) grown on GaAs(001) by varying the direction of the In flux. Transmission-electron microscope images of the stacked QDs reveal that the stacking direction tilts along the [110] direction according to the projection of the In flux direction on the (-110) and does not tilt in the [-110] direction. This anisotropic tilting behavior of the stacked QDs is considered to be caused by an anisotropic migration of In atoms on the (001) growth front. The linear polarization feature of the edge-emitted photoluminescence (PL) demonstrates a strong anisotropy of the strain distribution attributable to the tilted direction of the stacked QDs. According to multidirectional observations of the polarized PL, anisotropic valence band mixing was caused by strain symmetry lowering owing to the tilted stacking direction. (C) 2013 AIP Publishing LLC.
AMER INST PHYSICS, Jul. 2013, JOURNAL OF APPLIED PHYSICS, 114 (3), 033517 - 1-5, English[Refereed]
Scientific journal
We studied state-filling-dependent intraband carrier dynamics in InAs/GaAs self-assembled quantum dots using two-color photoexcitation spectroscopy. The photoluminescence (PL) intensity was observed to be dramatically reduced by selectively pumping carriers from the intermediate state to the continuum state located above the conduction band edge, and the PL-intensity reduction decreased with an increase in the continuous-wave excitation power. We analyzed the observed state-filling-dependent intraband carrier dynamics by detailed modeling of carrier excitation and relaxation processes in which the two-photon absorption for the interband transition, Pauli blocking, and saturable absorption for the intraband transition is considered. © 2013 AIP Publishing LLC.
14 Jun. 2013, Journal of Applied Physics, 113 (22), 223511 - 1-5, English[Refereed]
Scientific journal
We have studied the electronic states of closely stacked InAs/GaAs quantum dots (QDs) with a 4.0-nm spacer layer using linearly polarized photoluminescence (PL) and time-resolved PL measurements. An increase in the stacking-layer number (SLN) leads to an increase in the linear polarization anisotropy in the (001) plane; the [-110]-polarization component becomes dominant. These SLN-dependent polarization characteristics result from the valence-band mixing induced by the vertically coupled electronic states. The PL spectrum of the stacked QDs shows clear blueshifts with an increase in the excitation power because of the band filling. In addition, the radiative recombination lifetime has been found to obey the T-1/2 dependence, which directly confirms the one-dimensional translational motion of excitons in the closely stacked QDs.
AMER PHYSICAL SOC, Jun. 2013, PHYSICAL REVIEW B, 87 (23), 2353323 - 1-6, English[Refereed]
Scientific journal
The spin-states splitting and spin ordering in the band structure of GdN thin films have been studied using optical absorbance spectroscopy and magnetometer. Remarkably, the optical absorbance measurements indicate a giant splitting in the spin-states near-infrared frequency regime, through which the spin-up and spin-down states of the GdN films have been evaluated. Both the spin-up and spin-down states split subsequently wider, which attributes to a combining effect from the nitrogen vacancies, and the population of electronic states pertaining to the spins associated with 4f states of Gd3+ ions. While spin-splitting energy enhances, magnetic-hysteresis loops suggest a sharp magnetic switching feature. (C) 2013 AIP Publishing LLC.
AMER INST PHYSICS, Jun. 2013, APPLIED PHYSICS LETTERS, 102 (22), 222408 1 - 4, English[Refereed]
Scientific journal
The physical properties of amorphous In-Ga-Zn-O (a-IGZO) films deposited by DC sputtering under various sputtering pressures were investigated. The sputtering pressure was found to influence various physical properties. Lower sputtering pressures resulted in film densification and decreased both surface roughness and hydrogen concentration. In addition, transistor performance characteristics such as saturation mobility and sub-threshold swing improved as the sputtering pressure decreased. These results yield insight into the correlation between thin film transistor (TFT) performance and deposition conditions. (c) 2013 The Japan Society of Applied Physics
IOP PUBLISHING LTD, Mar. 2013, JAPANESE JOURNAL OF APPLIED PHYSICS, 52 (3), 03BA01 - 5, English[Refereed]
Scientific journal
Temperature dependent optical Tauc plots of AlN/GdN/AlN heterostructures have showed two optically induced transitions, and those optical transitions could be attributed to the minority and majority spin band energy. In contrast, temperature dependent magnetization measurements of GdN thin film provide direct evidence of spin ordering below 39 K, and which is also evidenced by Arrott plots.
AMER INST PHYSICS, 2013, PHYSICS OF SEMICONDUCTORS, 1566, 325 - +, English[Refereed]
International conference proceedings
We have studied time-resolved intra band transition from the intermediate state to the continuum state of the conduction band in InAs/GaAs self-assembled quantum dots (QDs) embedded in a one-dimensional photonic cavity structure using a two-color photoexcitation spectroscopy. The photonic gap was tuned to enhance the excitation from the intermediate state to the conduction band, whose energy is selected to be less than the interband transition energy between the intermediate state and the quantized hole state. The photoluminescence intensity was observed to be dramatically reduced by selectively pumping carriers in the intermediate state. This effect has been analyzed by modeling detailed carrier relaxation process.
IEEE, 2013, 2012 IEEE 38TH PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), VOL 2, English[Refereed]
International conference proceedings
We have studied time-resolved intra band transition from the intermediate state to the continuum state of the conduction band in InAs/GaAs self-assembled quantum dots (QDs) embedded in a one-dimensional photonic cavity structure using a two-color photoexcitation spectroscopy. The photonic gap was tuned to enhance the excitation from the intermediate state to the conduction band, whose energy is selected to be less than the interband transition energy between the intermediate state and the quantized hole state. The photoluminescence intensity was observed to be dramatically reduced by selectively pumping carriers in the intermediate state. This effect has been analyzed by modeling detailed carrier relaxation process.
IEEE, 2013, 2012 IEEE 38TH PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), VOL 2, English[Refereed]
International conference proceedings
We report the effects of excitation of exciton polaritons on their propagation in GaAs (110 nm)/Al0.3Ga0.7As double heterostructure thin films by measuring the cross-correlation signal, which was recorded as the intensity of the second harmonic light generated by the gate pulse and the probe pulse reflected from the sample. When the probe energy is tuned at the lowest exciton energy, the signal profile changes due to the appearance of nonlinear dispersion. On the other hand, the signal profile shows a complicated change under the non-resonant probe condition, in which the energy is the center energy of two exciton states. These results originate from a change in the propagation velocity of the exciton polariton due to the pump. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4772717]
AMER INST PHYSICS, Jan. 2013, JOURNAL OF APPLIED PHYSICS, 113 (1), 074305 - 1-4, English[Refereed]
Scientific journal
AlN/GdN/AlN double heterostructures were grown on c-sapphire substrates using a reactive rf sputtering method under high vacuum conditions. The optical absorption spectrum of the GdN shows a clear fundamental band edge of GdN around 800 nm this transition is attributed to the minority spin band energy of GdN at the X point. Nitrogen vacancy centers cause a blue-shift of the optical band edge of GdN, which could be ascribed to both the band filling, and the electron-hole interactions resulting from the free carriers generated by nitrogen vacancies. Temperature-dependent magnetization measurements demonstrate a clear change in the magnetization values of GdN with respect to the N 2 partial pressure. Nitrogen vacancy centers in the thin GdN film raise the Curie temperature from 31 K to 39 K, which has been accurately measured by the Arrott plots. © 2013 EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg.
2013, European Physical Journal B, 86 (2), 52 - 1-4, English[Refereed]
Scientific journal
We report the cooperative phenomena of magneto-optical effect in AlN/GdN/AlN heterostructure grown by reactive rf magnetron sputtering technique performed under a base pressure less than 5x10(-6) Pa. The ultra-high vacuum conditions during growth of GdN enable to curtail the oxophilicity character. The temperature dependent optical absorbance measurements have been carried out to evaluate the direct optical band gaps at the X point through the Tauc plots for the heterostructure. We observed for the first time that the optical absorbance studies demonstrate an exceptional splitting in valance and conduction bands in GdN below the critical temperature. The splitting energy is slightly increased with increase of temperature range of 30-55 K and the difference is merely Delta E=28 meV. Furthermore, the splitting energy drastically increases from 30 K to 3 K and the difference is Delta E=102 meV. This startling increase convincing that there is rapid increase of magnetic moments caused by long range correlation of spins.
IOP PUBLISHING LTD, 2013, 15TH INTERNATIONAL CONFERENCE ON THIN FILMS (ICTF-15), 417, 012053 - 1-4, English[Refereed]
International conference proceedings
We have studied time-resolved intraband transition from the intermediate state to the continuum state of the conduction band in InAs/GaAs self-assembled quantum dots embedded in a one-dimensional photonic cavity structure using a two-color photoexcitation spectroscopy. The photonic gap was tuned to enhance the excitation from the intermediate state to the conduction band, whose energy is selected to be less than the interband transition energy between the intermediate state and the quantized hole state. The photoluminescence intensity was observed to be dramatically reduced by selectively pumping carriers in the intermediate state. This effect has been analyzed by modeling detailed carrier relaxation process. © 2013 Copyright SPIE.
2013, Proceedings of SPIE - The International Society for Optical Engineering, 8620, 862008 - 1-7, English[Refereed]
International conference proceedings
The present study reports on the correlation between the local atomic structure and cathodoluminescent properties of Al1-xGdxN thin films grown by reactive rf magnetron sputtering at ultra-high vacuum conditions. Those thin films were characterised using X-ray absorption fine structure (XAFS) and cathodoluminescence (CL). From the CL measurements, we have observed a narrow intense ultraviolet emission at 318 nm which is originated from the intra-orbital f-f transition in Gd3+ ions. In order to understand the local atomic structure around the Al1-xGdxN (x=0.1 to 6.0 mol%) thin film, XAFS measurements have been carried out. Analysis of the local atomic structural results showed that both the large distance among Gd atoms and nitrogen vacancies in Al1-xGd xN lattice significantly contribute to the richness in the ultraviolet emission intensity.
Institute of Physics Publishing, 2013, Journal of Physics: Conference Series, 417 (1), 012049 - 1-6, English[Refereed]
International conference proceedings
We have controlled the electronic states of closely-stacked InAs/GaAs quantum dots with a 4.0 nm spacer layer and investigated the optical gain characteristics. With an increase in the stacking-layer number (SLN), the [001] transverse-magnetic (TM) polarization component increases as well as the linear polarization anisotropy in the (001) plane becomes remarkable. These SLN-dependent polarization characteristics result from the valence-band mixing induced by the vertically-coupled electronic states in stacked QDs. We have systematically studied polarized electroluminescence properties of a semiconductor-optical amplifier devise containing 30-stacked InAs/GaAs QDs. The net modal gain was analyzed by using the Hakki-Paoli method. The injection current dependence of the gain spectra shows a state filling effect and a change in the contribution of the TM polarization component. The polarization insensitive gain feature within +/-1 dB has been achieved in the low injection current condition. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2013, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 10, NO 11, 10 (11), 1492 - 1495, English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
Microwave photoconductivity decay (mu-PCD) method was applied to evaluate the effects of chemical composition and Ar+ plasma induced damage on the bulk and the surface states in amorphous In-Ga-Zn-O (a-IGZO) films. It was found that the peak reflectivity signal in the photoconductivity response increased with decreasing the Ga content, and had a strong correlation with the a-IGZO transistor performances. In addition, the peak reflectivity signals obtained after various Ar+ plasma treatment duration were well correlated with the transistor characteristics. With Ar+ plasma treatment, the peak reflectivity signal decreased in accordance with degradation of transistor characteristics. The mu-PCD method was found to be a very useful tool not only to evaluate the bulk and the surface states, but also to predict the performance of a-IGZO transistors subjected to various plasma processes in the production.
IEICE-INST ELECTRONICS INFORMATION COMMUNICATIONS ENG, Nov. 2012, IEICE TRANSACTIONS ON ELECTRONICS, E95C (11), 1724 - 1729, English[Refereed]
Scientific journal
We studied the photoconductivity responses in amorphous In-Ga-Zn-O (a-IGZO) films using a time-resolved microwave photoconductivity decay (mu-PCD) technique. The a-IGZO film characteristics are correlated with three components in the photoconductivity response: the peak value and two decay constants. The peak value originated from the density of the photo-generated free carriers through carrier generation and recombination processes during laser pulse irradiation. Power law characteristics indicated that the peak values are attributed to recombination process related to the exponential distribution of the conduction band tail states. After the laser pulse was turned off, the reflectivity signal decreased rapidly, indicating fast recombination of the photo-generated carriers. This fast decay component is suggested to be related to the recombination processes through the deep level states. Following the fast decay, a slow decay with a decay constant on the order of microseconds appeared. This slow decay was attributed to the re-emission of trapped carriers with an activation energy of similar to 0.2 eV. In addition, both the fast and slow decays for the wet annealed a-IGZO film were longer than those of the as-deposited a-IGZO film. The decay constants are considered to reflect the density of the subgap states that act as trapping or recombination centers. The mu-PCD method provides a useful estimation of the film quality, such as the density of the defect states, and the physical properties of electronic devices using a-IGZO films. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4751433]
AMER INST PHYSICS, Sep. 2012, JOURNAL OF APPLIED PHYSICS, 112 (5), English[Refereed]
Scientific journal
Magneto-optical properties of GdN thin films have been investigated by employing temperature dependent optical circular dichroism spectroscopy and angular dependent resonance field measurement. Spin-splitting in the band structure of GdN thin films has been evaluated by optical circular dichroism absorbance spectra, and the manifested spin-splitting energy ascribed to the difference between majority and minority spin band states in GdN. The plot of left circular polarization and right circular polarization bandgap reflects the half-hysteresis loop (positive side) trend, which is evidenced by magnetization measurements. The angular dependent resonance field measurements showed strong magnetic anisotropy along in-plane of GdN, which is attributed to the disturbance in the spin alignment in GdN. We demonstrate that the ferromagnetic properties depend on the film thickness. These results provide a pathway to control the spin ordering using circularly polarized light and the magnetic anisotropy. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4746265]
AMER INST PHYSICS, Aug. 2012, APPLIED PHYSICS LETTERS, 101 (7), 072403 - 1-5, English[Refereed]
Scientific journal
We have studied the time-resolved intraband transition from the intermediate state to the continuum state of the conduction band in InAs/GaAs self-assembled quantum dots ( QDs) embedded in a one-dimensional photonic cavity structure using two-color photoexcitation spectroscopy. The resonant energy of the photonic cavity was tuned to enhance the intraband transition with an energy smaller than the interband transition energy between the intermediate state and the quantized hole states. The interband photoluminescence intensity was observed to be drastically reduced due to the pumping out of carriers in the intermediate state using near-infrared laser light. We proposed a model describing the carrier relaxation process in the InAs/GaAs QD system, where the two-photon absorption and the Pauli blocking in QDs are considered.
AMER PHYSICAL SOC, Jul. 2012, PHYSICAL REVIEW B, 86 (3), 035301 - 1-7, English[Refereed]
Scientific journal
An exceptional kind of spin splitting in the band structure of AlN/GdN/AlN double heterostructures has been studied by employing temperature-dependent spectroscopy. This spin splitting can be attributed to both the band-gap shrink and the difference between minority and majority band energies in GdN below the Curie point; these results have been established by evaluating the optical band gaps at the X-point. The temperature-dependent magnetization measurements that provide direct evidence of the magnetic ordering below 32 K and it is described by long-range spin correlation in GdN. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4727903]
AMER INST PHYSICS, Jun. 2012, APPLIED PHYSICS LETTERS, 100 (23), 232410 - 1-4, English[Refereed]
Scientific journal
We studied the deep-ultraviolet emission properties of Al0.999Gd0.001 N thin films pumped by an electron beam. The Al0.999Gd0.001 N thin films were grown on fused silica substrates using an ultra-pure reactive sputtering technique. The intra-orbital electron transition of the Gd3+ ions in Al0.999Gd0.001 N showed an extremely narrow luminescence line at 318 nm. We fabricated field-emission devices using an Al0.999Gd0.001 N phosphor thin film and analyzed the dependence of the device characteristics on the injected current and acceleration voltage. The maximum output power was 1.0 mW/cm(2). The excitation cross section was of the order of 10(-13) cm(2) and was found to depend on the acceleration voltage. These results indicate that injected high-energy electrons multiply excite Gd3+ ion. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4705416]
AMER INST PHYSICS, Apr. 2012, JOURNAL OF APPLIED PHYSICS, 111 (8), 083526 - 1-4, English[Refereed]
Scientific journal
We have investigated the properties of multi-stacked layers of self-organized In0.4Ga0.6As quantum dots (QDs) on GaAs (311) B grown by molecular beam epitaxy. We found that a high degree of in-plane ordering of QDs structure with a six-fold symmetry was maintained though the growth has been performed at a higher growth rate than the conventional conditions. The dependence of photoluminescence characteristics on spacer layer thickness showed an increasing degree of electronic coupling between the stacked QDs for thinner spacer layers. The external quantum efficiency for an InGaAs/GaAs quantum dot solar cell (QDSC) with a thin spacer layer thickness increased in the longer wavelength range due to additive contribution from QD layers inserted in the intrinsic region. Furthermore, a photocurrent production by 2-step photon absorption has been observed at room temperature for the InGaAs/GaAs QDSC with a spacer layer thickness of 15 nm. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3699215]
AMER INST PHYSICS, Apr. 2012, JOURNAL OF APPLIED PHYSICS, 111 (7), 074305 - 1-4, English[Refereed]
Scientific journal
The physical properties of amorphous In-Ga-Zn-O (a-IGZO) films deposited by DC sputtering with various sputtering pressure were investigated. In accordance with improvement of the transistor performances such as saturation mobility (mu(SAT)) and sub-threshold swing with a lowering the sputter pressure, we found that the sputtering pressure affected various physical properties of a-IGZO film. The lower sputtering pressure caused a film densification, a decreasing the surface roughness and small hydrogen concentration in the films.
JAPAN SOCIETY APPLIED PHYSICS, 2012, 2012 19TH INTERNATIONAL WORKSHOP ON ACTIVE-MATRIX FLATPANEL DISPLAYS AND DEVICES (AM-FPD): TFT TECHNOLOGIES AND FPD MATERIALS, 147 - 150, English[Refereed]
International conference proceedings
Photonic devices employing semiconductor quantum dots (QDs) are anticipated to play an important role within power-efficient optical networks. In this chapter, we consider the prospects for signal processing using all-optical QD switches. Vertical cavity structures have been developed to enhance the light- QD interaction and accordingly the optical nonlinearity of QDs which leads to low
Springer New York, 01 Jan. 2012, Quantum Dot Devices, 197 - 222, English[Refereed]
In book
We developed ultra-violet field-emission devices using rare-earth nitrides of Al 1-xGd xN grown by a reactive radio-frequency magnetron sputtering technique. The Al 1-xGd xN phosphor film excited by high-energy electrons shows a resolution limited, narrow intra-orbital luminescence from Gd 3+ ions at 318 nm. The devise characteristics depend on injected current and acceleration voltage, which were analyzed by considering multiple excitation process of injected high-energy electrons. © 2011 Materials Research Society.
2012, Materials Research Society Symposium Proceedings, 1342, 87 - 92, English[Refereed]
International conference proceedings
We study the quantum beats and relaxation dynamics of exciton center-of-mass motion confined in GaAs thin films by a reflection-type pump-probe technique. By using spectrally narrowed probe pulses with energies comparable with the exciton energy separation, oscillations caused by quantum beats between the confined excitons and ultrafast responses which are shorter than their lifetime appear. This appearance of quantum beats does not result from the so-called detection process. Our results demonstrate that the reduction of the destructive interference of the probe pulse in the sample is a key factor to observe the excitonic quantum beats. (C) 2012 American Institute of Physics. [doi:10.1063/1.3676429]
AMER INST PHYSICS, Jan. 2012, JOURNAL OF APPLIED PHYSICS, 111 (2), English[Refereed]
Scientific journal
We have studied the broadened emission lines of CdTe/Cd0.75Mn0.25Te tilted superlattices (TSLs) in contrast to the sharp emission lines of the nonmagnetic CdTe/Cd0.74Mg0.26Te TSLs by using near-field scanning optical microscopy. The broadening of the photoluminescence (PL) spectra reflect the statistical fluctuation in the magnetization of Mn spins in the exciton magnetic polaron (EMP). The EMP PL strongly depends on the temperature; the line width of the EMP PL spectrum becomes narrow and the spatial distribution of the EMP PL intensity has been found to be reduced with rising the temperature from 5 to 11 K, because of annihilation of the EMP. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2012, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 9, NO 2, 9 (2), English[Refereed]
International conference proceedings
Recently, there has been an increasing interest in broad-band light sources to develop a biomolecular imaging technique called optical coherence tomography (OCT). We fabricated superluminescent diodes (SLDs) using three kinds of quantum dot (QD) layers with different emission wavelength in the active region. The emission wavelength was controlled by reducing the strain in QDs by using In0.1Ga0.9As strain-reducing layer. The SLD device showed a broad electroluminescence spectrum with the center wavelength of 1104 nm and the spectral line-width of 122 nm at the injection of 40 mA, which corresponds to the theoretical axial resolution of 4.4 mu m. To estimate the actual resolution of the OCT system using fabricated SLD, we measured the interference signal in the Michelson interferometer. An axial resolution of 5.4 mu m, which is close to the theoretical limit, was obtained. (C) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2012, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 9, NO 12, 9 (12), 2473 - 2476, English[Refereed]
International conference proceedings
We performed ESR and magnetization measurements to make clear ferromagnetic properties of GdN thin films. We found two kinds of ferromagnetic phases one starts to develop below approximately 50K, and another one below approximately 30K. The Curie temperature estimated from the Arrott plot was 29.0K. The ratio of the 50-K-class-ferromagnetic phase to the 30-K-class-phase becomes high with the increase in the free carrier density, which suggests that the transition of the 50-K-class-ferromagnetic phase can be attributed to be the RKKY interaction. On the other hand, the Curie temperature depends on lattice expansion in the growth direction. This indicates that the 30-K-classferromagnetic phase obeys the superexchange interaction. Furthermore, we found that the band gap is dramatically reduced with the ferromagnetic spin ordering. The reduction of the band gap energy depends on magnetization, and the relationship between them was ruled by the Zeeman splitting. © 2011 The Society of Materials Science, Japan.
Nov. 2011, Zairyo/Journal of the Society of Materials Science, Japan, 60 (11), 1004 - 1008, Japanese[Refereed]
Scientific journal
We carried out direct impurity doping in InAs/GaAs quantum dots (QDs) by selecting the self-assembled growth steps. The photoluminescence (PL) intensity of the Si-doped QDs is enhanced, and thermal quenching of the PL intensity is found to be considerably suppressed, whereas such improvement was not confirmed in Be-doped QDs. The excitation energy dependences of the PL intensity and the time-resolved PL indicate a reduction in the nonradiative recombination probability during the thermalization of carriers generated by high-energy photons. From these results, excess electrons in doped QDs neutralize and, therefore, inactivate the nonradiative recombination centers created by electron traps. (C) 2011 American Institute of Physics. [doi:10.1063/1.3660794]
AMER INST PHYSICS, Nov. 2011, JOURNAL OF APPLIED PHYSICS, 110 (10), English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We investigated the narrowband ultraviolet emission properties of Al(0.94)Gd(0.06)N phosphor thin films pumped by an electron beam. An extremely narrow luminescence line, which was less than 1 nm from the intra-orbital f-f transition in Gd(3+) ions, was confirmed at 318 nm. The corresponding emission efficiency was improved by decreasing the growth temperature. The extended X-ray absorption fine structure analysis of the local atomic structure revealed that a low-temperature growth led to the formation of a uniform atomic configuration around Gd, which was found to play a key role in improving the luminescence intensity of the films. (C) 2011 American Institute of Physics. [doi:10.1063/1.3658845]
AMER INST PHYSICS, Nov. 2011, JOURNAL OF APPLIED PHYSICS, 110 (9), English[Refereed]
Scientific journal
We report the relaxation dynamics from above-barrier exciton states to the lowest one in multi-stacked quantum dots (QDs). The photoluminescence decay time increases because of the excitation of higher exciton states, which is attributed to the wider miniband width of above-barrier excitons and the localization of the envelope functions in the barrier layers. The existence of the above barrier minibands makes carrier transport along the growth direction possible and eliminates a difficulty with close QD stacking. These results demonstrate an effective approach to achieve high efficiency QD devices. (C) 2011 American Institute of Physics. [doi:10.1063/1.3660210]
AMER INST PHYSICS, Nov. 2011, JOURNAL OF APPLIED PHYSICS, 110 (9), English[Refereed]
Scientific journal
We report the saturation of Forster resonance energy-transfer (FRET) between two optically nonlinear cyanine dyes in polymer thin films, where the energy donor and acceptor have small Stokes shift energies. Our combinations of dyes show the energy transfer rate of inversely proportional to the square of the distance between the energy donor and acceptor dyes. This result quite differs from the normal FRET results. From speculation based on the number of excited acceptor dye, our FRETs are saturated even at such a long distance approximately 10 nm between the energy donor and acceptor because of the optical excitation of acceptor dyes in addition to FRET process. (C) 2011 American Institute of Physics. [doi:10.1063/1.3653228]
AMER INST PHYSICS, Oct. 2011, JOURNAL OF APPLIED PHYSICS, 110 (8), English[Refereed]
Scientific journal
We studied the spatial localization of excitons bound to nitrogen (N) pairs in N delta-doped GaAs to make clear origin of bound exciton lines. An extremely high uniformity of the emission wavelength was achieved for the exciton bound to the N pairs because of the uniform strain field in the N delta-doped layer fabricated in the (001) plane in the atomically controlled way. The magneto-photoluminescence spectra in the Faraday configuration showed a mixing of the bright-and dark-exciton components in the exciton fine structure and diamagnetic shift. The spatial distribution of the excitons localized at different N pairs was estimated using the diamagnetic shift coefficient and confirmed by the radiative lifetime of the bright-exciton component. According to the estimated spatial distribution of bound-exciton wave function, it was found that the exciton for the 1.444-eV line is localized stronger than that for the 1.493-eV line. The strong electron confinement for the 1.444-eV line results in the reduction of exciton-phonon interaction. (C) 2011 American Institute of Physics. [doi:10.1063/1.3654015]
AMER INST PHYSICS, Oct. 2011, JOURNAL OF APPLIED PHYSICS, 110 (8), English[Refereed]
Scientific journal
Recent experimental measurements, without any theoretical guidance, showed that isotropic polarization response can be achieved by increasing the number of quantum-dot (QD) layers in a QD stack. Here we analyze the polarization response of multilayer QD stacks containing up to nine QD layers by linearly polarized photoluminescence (PL) measurements and by carrying out a systematic set of multimillion atom simulations. The atomistic modeling and simulations allow us to include correct symmetry properties in the calculations of the optical spectra, a factor critical to explain the experimental evidence. The values of the degree of polarization (DOP) calculated from our model follows the trends of the experimental data. We also present detailed physical insight by examining strain profiles, band edges diagrams, and wave function plots. Multidirectional PL measurements and calculations of the DOP reveal a unique property of InAs QD stacks that the TE response is anisotropic in the plane of the stacks. Therefore, a single value of the DOP is not sufficient to fully characterize the polarization response. We explain this anisotropy of the TE modes by orientation of hole-wave functions along the [(1) over bar 10] direction. Our results provide a new insight that isotropic polarization response measured in the experimental PL spectra is due to two factors: (i) TM001-mode contributions increase due to enhanced intermixing of HH and LH bands, and (ii) TE110-mode contributions reduce significantly due to hole-wave function alignment along the [(1) over bar 10] direction. We also present optical spectra for various geometry configurations of QD stacks to provide a guide to experimentalists for the design of multilayer QD stacks for optical devices. Our results predict that the QD stacks with identical layers will exhibit lower values of the DOP than the stacks with nonidentical layers.
AMER PHYSICAL SOC, Sep. 2011, PHYSICAL REVIEW B, 84 (11), English[Refereed]
Scientific journal
We report the effects of depolarization on the excitonic Rabi oscillation in GaAs thin films measured in the 2k(1) - k(2) direction of a degenerate four-wave-mixing signal. The Rabi frequency, measured by changing the k(2) pulse intensity, varies with the k(1) pulse intensity; the Rabi frequency decreases with an increase in the k(1) power. This decrease originates from the reduction in the field intensity of the k(2) pulse, which consists of the local field and depolarization terms. Cancellation of the k(2) field due to depolarization leads to the decrease in the Rabi frequency. (C) 2011 American Institute of Physics. [doi:10.1063/1.3624667]
AMER INST PHYSICS, Aug. 2011, JOURNAL OF APPLIED PHYSICS, 110 (4), English[Refereed]
Scientific journal
We have studied the possibility to utilize semiconductor quantum dots (QDs) as an optical phase shifter within a vertical geometry for ultrafast information processing. From theoretical analyses, an optical phase nonlinearity in QD structures has been predicted which can be enhanced through the use of an vertical optical cavity. Asymmetric cavity structures with 16/30 periods of GaAs/AlGaAs layers for the front/back mirrors have been fabricated to demonstrate a practical device with significant nonlinear characteristics for optical switching. A phase shift of 18 has been initially observed with a tilted pump scheme. This observation paves the way toward a Mach-Zehnder optical switch using QDs inside a vertical cavity. (C) 2011 American Institute of Physics. [doi:10.1063/1.3596704]
AMER INST PHYSICS, Jun. 2011, APPLIED PHYSICS LETTERS, 98 (23), English[Refereed]
Scientific journal
We studied polarization anisotropy observed in photoluminescence from closely stacked InAs/GaAs quantum dots (QDs). As the number of stacked layers was increased, the anisotropy in the (001) plane became drastically larger and the [001]-polarization component became larger than the [110] component when observed from the [(1) over bar 10] direction. However, the polarization intensity of the [(1) over bar 10] component remained stronger than that of the [001] component in the stacked QDs. Such varied polarization anisotropies depending on the observation direction have been found to result from the valence-band mixing in the vertically coupled electronic states. (C) 2011 The Japan Society of Applied Physics
JAPAN SOC APPLIED PHYSICS, Jun. 2011, APPLIED PHYSICS EXPRESS, 4 (6), English[Refereed]
Scientific journal
We studied the optical and magnetic properties in epitaxial AlN/GdN/AlN double heterostructures grown using reactive sputtering under ultrapure conditions. The indirect and direct optical transitions in a 95-nm-thick GdN film were found to be 0.95 and 1.18 eV, respectively. The considerable size effects of the optical band gap were observed with a decrease in the GdN thickness. The AlN/GdN/AlN double heterostructures clearly exhibited ferromagnetic states at low temperature. The short-range correlation of spins began to develop below similar to 60 K, and long-range ordering that obeyed the Arrott relation was confirmed below similar to 30 K. Because of the film-size independence for the ferromagnetic ordering, the cooperative correlation length in GdN was considered to be shorter than 30 nm. Furthermore, we found that the band gap is dramatically reduced with the ferromagnetic spin ordering.
AMER PHYSICAL SOC, Apr. 2011, PHYSICAL REVIEW B, 83 (15), English[Refereed]
Scientific journal
Field-emission characteristics of a carbon nanotube (CNT)/elastomer composite have been investigated. We performed theoretical calculations of the field distribution in a field emission device structure with the side-electron configuration of the composite sheet. According to the calculation results, the electric field is found to be concentrated at the edge of the composite sheet which leads to an enhancement of the local electric field at the CNT tips protruding from the composite. Furthermore, we calculated the trajectories of emitted electrons. From the obtained results, bright luminescence over 37000 cd/m(2) from green phosphor was obtained by optimizing the electrode structure. (C) 2011 American Institute of Physics. [doi:10.1063/1.3567913]
AMER INST PHYSICS, Apr. 2011, JOURNAL OF APPLIED PHYSICS, 109 (7), English[Refereed]
Scientific journal
We have investigated the narrowband ultraviolet (UV) emission characteristics of rare-earth nitrides A(1-x)Gd(x)N grown by reactive magnetron sputtering in an ultra-pure process. Gd3+ ions in the alloy films efficiently emit UV luminescence at 317 nm. The transition occurs from the P-6(7/2) excited state to the S-6(7/2) ground state in the 4f orbital. The crystallographic properties of the alloy phosphor thin film are sensitive to the growth temperature. With a decrease in the growth temperature, the emission efficiency increases. Furthermore, introducing a buffer layer before growing the phosphor layer has been found to enhance the emission intensity considerably.
KOREAN ASSOC CRYSTAL GROWTH, INC, Mar. 2011, JOURNAL OF CERAMIC PROCESSING RESEARCH, 12, S73 - S77, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We have studied the detailed fine structure splitting of the photoluminescence lines exhibiting the superlinear excitation power dependence in nitrogen delta-doped GaAs. The symmetric splitting energy observed between the 1.493 and 1.509 eV lines suggests that these two lines originate from the same impurity center because the mixing of the bright- and dark-exciton components depends on the electron-hole exchange energy and the local-strain field. The excitation power dependence of these two lines indicates that the 1.509 eV line is attributed to the biexciton luminescence corresponding to the 1.493 eV line. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, Feb. 2011, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 248 (2), 464 - 467, English[Refereed]
Scientific journal
Microwave photoconductivity decay method was applied to evaluate the effects of Ar+ plasma irradiation on amorphous In-Ga-Zn-O films. The peak reflectivity signals of photoconductivity response obtained after various Ar+ plasma exposure time were correlated with transistor characteristics. With Ar+ plasma irradiation, the peak reflectivity decreases in accordance with degradation of transistor characteristics.
INST IMAGE INFORMATION & TELEVISION ENGINEERS, 2011, IDW'11: PROCEEDINGS OF THE 18TH INTERNATIONAL DISPLAY WORKSHOPS, VOLS 1-3, 103 - 106, English[Refereed]
International conference proceedings
Two-photon transition modelling is developed to study quantum mechanism and simulate device operation in intermediate band solar cell (IBSC). The interband-intranband transition, the detailed balance and carrier transport are coupled with each other. IB formation mechanism is studied within one-band envelope-function framework (Kronig-Penney type). Well-designed GaInAs/InP superlattice structures have been proved to separate IB from valence band (VB) and conduction band (CB), which is the precondition of IBSC operations. Further, we calculate two-photon absorption spectra and firstly combine quantum transitions into recent drift-diffusion and detail balanced model. With this model, we have studied a novel IBSC consist of In0.53Ga0.47As/InP superlattices (SLs). Our results show the interband-intraband transition determines the conversion efficiency. With well-designed quantum structure, the efficiency in 1.2 μm thick SLs is 46.13% under the maximum concentration. However, as the well or barrier thickness increases to 10 nm, the absorption peak of the intraband transition gradually redshifts and narrows, so the efficiency correspondingly decreases to below 40%. © 2011 IEEE.
2011, Conference Record of the IEEE Photovoltaic Specialists Conference, 002625 - 002628, English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
We have developed a technique to fabricate quantum dot (QD) solar cells with direct doping of Si into InAs QDs in GaNAs strain-compensating matrix in order to control the quasi-Fermi level of intermediate QD states. The Si atoms were evenly incorporated into QDs during the assembling stage of growth such that a uniform array of partially filled QDs has been obtained. Nonradiative recombination losses were also reduced by Si doping and a photocurrent increase due to two-step photon absorption was clearly measured at room temperature detected under filtered air-mass 1.5 solar spectrum. (C) 2011 American Institute of Physics. [doi:10.1063/1.3533423]
AMER INST PHYSICS, Jan. 2011, JOURNAL OF APPLIED PHYSICS, 109 (2), English[Refereed]
Scientific journal
Magnetic semiconductor GdN thin film has been studied by a conventional X-band electron spin resonance (ESR). Electron paramagnetic resonance (EPR) of GdN is observed at 100 K while the ferromagnetic resonance (FMR) is clearly observed at 4.2 K, which is confirmed by the typical angular dependence of FMR. The result will be discussed in connection with the magnetic properties obtained previously by our SQUID magnetometer measurement.
AMER INST PHYSICS, 2011, PHYSICS OF SEMICONDUCTORS: 30TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, 1399, English[Refereed]
International conference proceedings
The net generation balance equation is incorporated into the Poisson equation and the continuty equation to deduce the IB quasi-Fermi Ef(IB) and filling factor f. The QD state density is not enough high to pin the IB quasi-Fermi level Ef(IB) at the position of the IB level E-IB so that Ef(IB) depends on the QD position and the operation voltage. In the case of the quasi-uniform absorption (the weak ab-sorption and the same absorption coefficient constants of sub-bandgap photons), a rough approximation is that Ef(IB) approximately parallels to E-IB, and clamps in some equilibrium position. In addition, in the case of the nonuniform absorption, the proper ratio alpha(IC0)/alpha(VI0) can effectively enhance the conversion efficiency. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 2, 8 (2), English[Refereed]
International conference proceedings
We fabricated broadband superluminescent diodes (SLDs) for optical coherence tomography (OCT). We used three kinds of quantum dot (QD) layers with different emission peak wavelengths in the active region of SLD. The emission wavelength was controlled by reducing the strain in QDs; by using the In0.1Ga0.9As strain-reducing layer, the peak wavelength shifted toward the longer-wavelength side, and the photoluminescence peak intensity becomes strong in contrast to QDs on GaAs. By stacking these strain-controlled QD layers, the SLD device shows a broad electroluminescence spectrum with the center wavelength of 1130 nm and the spectral linewidth of approximately 240 nm at the injection of 1A caused by the increased emission intensity from the excited states. This corresponds to an resolution of 2.3 mu m in OCT. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 2, 8 (2), English[Refereed]
International conference proceedings
We report on the intraband relaxation properties of photoexcited carriers in ordinary stacked quantum dots (QDs) and QD chains in which QDs are interconnected along the growth direction via electron envelope functions. The detection-energy dependence of the photoluminescence (PL) decay time indicates the in-plane interaction between QDs even at 50 K by carrier transfer. From the excitation-energy dependence of the PL intensity, we found the change in the intraband relaxation process due to the transfer process in the QD chain sample with longer exciton lifetime than in the stacked QD sample. Our results indicate that the change in the intraband relaxation process depends on the exciton lifetime. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 1, 8 (1), English[Refereed]
International conference proceedings
We studied effects of the miniband structure to control the nonlinear optical response of excitons in GaAs/AlAs superlattices. The excitation-power dependence of the degenerate four-wave-mixing signal shows different saturation power in the samples with the thinner and thicker barriers, while the dependence of dephasing time is almost independent of the barrier width. The analysis of the excitation-power dependence of the photoluminescence spectrum indicates the biexciton generation at lower excitation power in the sample with the thicker barrier width. These results demonstrate that the saturation of the four-wave-mixing signal intensity of the exciton comes from the contribution of the biexcitons. Our results support a possibility that the nonlinear optical response of excitons can be controlled by controlling the barrier width. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 1, 8 (1), English[Refereed]
International conference proceedings
We report on the dependence of exciton-polariton propagation on film thickness in GaAs thin films using a reflection-type pump-probe technique. The rise time of the transient signal under exciton excitation conditions increases with an increase in the film thickness. In order to reveal the origin of the change in signal rise time, we have compared the propagation velocities estimated from values of the signal rise time and effective film thickness with the calculated group velocity of the exciton-polaritons in bulk GaAs crystals. The propagation velocities are almost consistent with the group velocity in the bulk crystals. Therefore, we conclude that the propagation of exciton-polaritons in a confined system coincides with that in the bulk crystal. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 2, 8 (2), English[Refereed]
International conference proceedings
We studied the ferromagnetic phase transition and the resultant change in the optical band gap of GdN thin films grown by a reactive sputtering technique in an ultra-high vacuum process. The GdN thin film exhibited two phases of spin ordering; the short correlation of spins starts to develop below similar to 60 K, and the long-range ferromagnetic ordering emerges below the Curie temperature of 37 K. GdN has been confirmed to be an indirect band gap semiconductor. We found that the band-gap is dramatically reduced with the ferromagnetic spin ordering. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 2, 8 (2), English[Refereed]
International conference proceedings
We have studied sharp emission lines created by interacting between the GaAs host-matrix conduction-band edge and nitrogen-related localized levels in nitrogen delta-doped GaAs by using magneto-photoluminescence spectroscopy. According to the decreased diamagnetic coefficient of 75 mu eV/T-2 at the 1.515-eV line, the interaction between the conduction-band edge and localized levels has been confirmed. Furthermore, we have observed a linear polarization anisotropy for these emission lines. This polarization splitting demonstrates that the electronic states of the nitrogen pair couple with the GaAs conduction-band edge. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2011, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 2, 8 (2), English[Refereed]
International conference proceedings
We have studied the magnetic-field evolution of the fine structure splitting of the exciton bound to nitrogen (N) pairs in GaAs in the Faraday configuration. With applying the magnetic field, the photoluminescence (PL) spectrum splits into several signals and changes their intensities. The observed magneto-PL spectra indicate the mixing between the split exciton states having the orthogonal linear polarization components in the zero-magnetic field, which demonstrates the characteristic Zeeman effects of the anisotropic exciton structure bound to the N pairs.
AMER INST PHYSICS, 2011, PHYSICS OF SEMICONDUCTORS: 30TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, 1399, English[Refereed]
International conference proceedings
Spatially resolved thermal conductivity of Cu6Sn5 intermetallic compounds (IMCs) formed in Sn-Ag-Cu lead free solder has been investigated by using a periodically modulated thermoreflectance (TR) method. The high spatial resolution has been achieved by focusing a modulated laser beam. The temperature response on the irradiated surface has been analyzed by calculating the phase lag of the TR signal as a function of the thermal diffusion length. We found that the boundary of IMCs influences the phase lag. Furthermore, the thermal conductivity of Cu6Sn5 was selectively measured by the TR method considering three-dimensional thermal diffusion model. The estimated thermal conductivity of Cu6Sn5 is 39 W/ (mK) which is lower than 54 W/ (mK) of Sn-3.5Ag-0.5Cu. Thus the micro TR method is a powerful method to characterize the thermal conductivity of not only IMCs but also various complex materials.
JAPAN INST METALS, Nov. 2010, JOURNAL OF THE JAPAN INSTITUTE OF METALS, 74 (11), 740 - 745, Japanese[Refereed]
Scientific journal
The effects of absorption coefficients were incorporated in a detailed balance model to analyze the intermediate-band (IB) configuration in quantum dot (QD) solar cells. Our results show that the optimum IB level, EIB, depends on the ratio of two subbandgap absorption coefficient constants, alpha(IC0)/alpha(VI0). Efficiency contour plots have been calculated to determine the optimum values of EIB and alpha(IC0)/alpha(VI0). In many cases, a large alpha(IC0) results in high conversion efficiency, especially for thin QD solar cells. Optimizing QD shape and size is a promising method to increase alpha(IC0). Increasing the QD total thickness partially addresses the urgent demand for a large alpha(IC0). (C) 2010 American Institute of Physics. [doi:10.1063/1.3516468]
AMER INST PHYSICS, Nov. 2010, APPLIED PHYSICS LETTERS, 97 (19), English[Refereed]
Scientific journal
We propose an all-optical switch based on self-assembled InAs/GaAs quantum dots (QDs) within a vertical cavity. Two essential aspects of this novel device have been investigated, which includes the QD/cavity nonlinearity with appropriately designed mirrors and the intersubband carrier dynamics inside QDs. Vertical-reflection-type switches have been fabricated with an asymmetric cavity that consists of 12 periods of GaAs/Al(0.8)Ga(0.2)As for the front mirror and 25 periods for the back mirror. All-optical switching via the QD excited states has been achieved with a time constant down to 23 ps, wavelength tunability over 30 nm, and ultralow power consumption less than 1 fJ/mu m(2). These results demonstrate that QDs within a vertical cavity have great advantages to realize low-power-consumption polarization-insensitive micrometer-sized switching devices for the future optical communication and signal processing systems.
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC, Nov. 2010, IEEE JOURNAL OF QUANTUM ELECTRONICS, 46 (11), 1582 - 1589, English[Refereed]
Scientific journal
We have investigated the narrowband ultraviolet (UV) emission characteristics of Al0.94Gd0.06N grown by reactive magnetron sputtering in an ultra-pure process. A resolution limited, narrow band luminescence line from Gd3+ ions has been observed at ∼320nm. The crystallographic properties of the Al0.94Gd0.06N thin films are sensitive to the growth temperature. With a decrease in the growth temperature, the emission efficiency has been found to increase considerably. According to the crystallographic properties investigated by extended X-ray absorption fine structure analysis, fluctuation of the column-Ill sublattices around the Gd3+ ions plays a key role to enhance the luminescence intensity. © 2010 The Society of Materials Science.
Sep. 2010, Zairyo/Journal of the Society of Materials Science, Japan, 59 (9), 666 - 670, Japanese[Refereed]
Scientific journal
We carry out Si doping in InAs/GaAs quantum dots (QDs) by selecting appropriate steps of the self-assembling growth process. The self-assembling growth process of QDs consists of nucleation, assembling, self-limiting, and dissolving steps. The electrical conductivity of the QDs doped at the various growth steps has been investigated by conductive atomic force microscopy. The two-dimensional current images demonstrate that the spatial carrier distribution remarkably depends on the growth steps. When Si impurities are introduced into QDs during the assembling step, carriers are preferentially incorporated in the QDs. Furthermore, the doped QDs lead to enhancement of the photoluminescence intensity and to suppression of the temperature quenching of the intensity. (c) 2010 American Institute of Physics. [doi:10.1063/1.3483252]
AMER INST PHYSICS, Sep. 2010, JOURNAL OF APPLIED PHYSICS, 108 (6), English[Refereed]
Scientific journal
We have developed a technique to control the polarization dependence of quantum dot (QD)-semiconductor optical amplifiers (SOAs) using vertically stacked self-assembled InAs QDs with moderately thick intermediate layers. By increasing the number of stacking layers, the transverse magnetic polarization component of electroluminescence (EL) from the cleaved edge surface of the SOA has been enhanced dramatically. Broadband and almost isotropic EL with a polarization difference of less than 1.2 dB has been demonstrated in a 1.3 mu m optical communication band for nine-layer stacked QDs in the active region of the SOA. (C) 2010 American Institute of Physics. [doi:10.1063/1.3441403]
AMER INST PHYSICS, May 2010, APPLIED PHYSICS LETTERS, 96 (21), English[Refereed]
Scientific journal
We have investigated the carrier tunneling process in a quantum-dot (QD) tunnel injection structure, which employs a GaAs(1-x)N(x) quantum well (QW) as a carrier injector. The influence of the barrier thickness between the GaAs(1-x)N(x) well and InAs dot layer has been studied by temperature-dependent photoluminescence. Although the 2.5 nm barrier sample exhibits the best tunneling efficiency, a 3.0 nm thickness for the barrier is optimum to retain good optical properties. The carrier capture time from the GaAs(1-x)N(x) QW to QD ground states has been evaluated by time-resolved photoluminescence. The result indicates that efficient carrier tunneling occurs at temperatures above 150 K due to the temperature dependent nature of phonon-assisted processes.
AMER INST PHYSICS, Apr. 2010, APPLIED PHYSICS LETTERS, 96 (15), English[Refereed]
Scientific journal
We have investigated the effects of temperature on the photoluminescence (PL) characteristics of excitons in ordinary stacked quantum dots (QDs) and QD chains in which QDs are interconnected along the growth direction. While the temperature dependence of the PL intensity of both samples is similar, that of the PL decay time is different. In addition, the PL decay times of both samples monitored at 150 K clearly depend on the detection energy. This result is attributed to lateral QD coupling. From these results, in ordinary stacked QDs, the exciton transfer owing to the lateral coupling is the only cause of the increase in the PL decay time. On the other hand, in QD chains, the interconnection along the chain direction as well as the lateral coupling is considered to cause the change in the PL characteristics and induce the extremely long exciton lifetime. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3366711]
AMER INST PHYSICS, Apr. 2010, JOURNAL OF APPLIED PHYSICS, 107 (7), English[Refereed]
Scientific journal
We have theoretically studied the emission-line width in Mn-composition modulated Cd1-xMnxTe quantum wires by using the multiband effective mass theory and fluctuation-dissipation theorem. The calculated emission-line width exhibits a broadening because of a statistical fluctuation in the magnetization of Mn spins in the exciton magnetic polaron. The line width is sensitive to both the temperature and the magnetic field in the Voigt configuration, which exhibits remarkable anisotropy depending on the external magnetic field direction. The anisotropic behavior is a typical feature of the one-dimensional system resulting from heavy-hole and light-hole mixing.
AMER INST PHYSICS, Feb. 2010, JOURNAL OF APPLIED PHYSICS, 107 (4), English[Refereed]
Scientific journal
We have investigated at the first time an all-optical switch using self-assembled InAs/GaAs quantum dots (QDs) within a vertical cavity structure. The optical nonlinearity of the QD switch has been optimized by an asymmetric cavity to achieve the maximum differential reflectivity. Optical switching via QD excited states exhibits a fast decay with a time constant down to 23 ps and a wavelength tunability over 30 nm. By compared to the theoretical design, the absorption strength of QD layers within the cavity has been determined.
IEEE, 2010, 2010 22ND INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS (IPRM), English[Refereed]
International conference proceedings
This paper descibes a net generation balance model to study the qasi-Fermi level split and the intermediate band (IB) filling. Our simulations reveal that the QD state density is not enough high to pin the IB quasi-Fermi level (Ef(IB)) at the position of the IB level (E-IB), and the filling factor (f) is determined by the absorption-recombination process of sub-bandgap photons. In the quasi-uniform absorption (equivalent absorption coefficients), a rough approximation is that Ef(IB) parallel with E-IB, and is clamped in the equilibrium position. In the nonuniform absorption case (inequivalent absorption coefficients), our simulations suggest that optimizing a(IC0)/a(VI0) ratio can effectively enhance the conversion efficiency.
IEEE, 2010, 35TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE, 1808 - 1813, English[Refereed]
International conference proceedings
An all-optical switching device has been proposed by using self-assembled InAs/GaAs quantum dots (QDs) within a vertical cavity structure for ultrafast optical communications. This device has several desirable properties, such as the ultra-low power consumption, the micrometre size, and the polarization insensitive operation. Due to the three-dimensional confined carrier state and the broad size distribution of self-assembled InAs/GaAs QDs, it is crucial to enhance the interaction between QDs and the cavity with appropriately designed 1D periodic structure. Significant QD/cavity nonlinearity is theoretically observed by increasing the GaAs/AlAs pair number of the bottom mirror. By this consideration, we have fabricated vertical-reflection type QD switches with 12 periods of GaAs/Al0.8Ga0.2As for the top mirror and 25 periods for the bottom mirror to give an asymmetric vertical cavity. Optical switching via the QD excited state exhibits a fast switching process with a time constant down to 23 ps, confirming that the fast intersubband relaxation of carriers inside QDs is an effective means to speed up the switching process. A technique by changing the light incident angle realizes wavelength tunability over 30 nm for the QD/cavity switch.
SPIE-INT SOC OPTICAL ENGINEERING, 2010, QUANTUM DOTS AND NANOSTRUCTURES: SYNTHESIS, CHARACTERIZATION, AND MODELING VII, 7610, English[Refereed]
International conference proceedings
This paper describes a technique to control the polarization property in quantum dot (QD)-semiconductor optical amplifiers (SOAs) using vertical stacking of self-assembled InAs QDs. QD-SOAs have been expected to realize high saturation power, multi-channel processing, and high-speed response. However, in conventional QDs, the significant polarization dependence in the optical gain caused by the flattened QD shape has been a serious problem. One of the well-known approaches to realize the polarization-independent gain relies on columnar QDs, in which InAs QDs layers are closely stacked with very thin (several monolayers) intermediate layers. The isotropic shape of columnar QDs realizes a polarization-independent gain. On the other hand, in this paper, we propose a different approach, where QDs are vertically stacked with moderately thick intermediate layers. Therefore each QDs layer is well separated geometrically and high precision control of overall QD shape is expected. Vertically aligned InAs QDs are known to create the electronically coupled states, where we expect the enhancement of the optical transition probability along the vertical direction. We have achieved such vertical stacking of QDs up to 9 layers by optimizing the amount of GaAs and InAs deposition. The 9-stacked QDs have shown transverse-magnetic-mode dominant emission in edge photoluminescence in the 1.3 mu m telecommunication wavelength region. Our results have suggested that the electronically coupled QDs can be a powerful tool to realize the polarization-independent QD-SOAs
SPIE-INT SOC OPTICAL ENGINEERING, 2010, PHYSICS AND SIMULATION OF OPTOELECTRONIC DEVICES XVIII, 7597, English[Refereed]
International conference proceedings
We report on the intra band relaxation properties of photoexcited carriers in ordinary stacked quantum dots (QDs) as well as OD chains in which QDs are interconnected along the growth direction. We found that the effect of lateral coupling on the intraband relaxation process in the stacked OD sample is less than that in the OD chain sample. This affection depends on the exciton lifetime. However, by comparison with our previous report, it is deduced that the exciton transfer is not so fast process. Therefore, we consider that it is possible to extract the carriers generated by visible light before the diffusion occurring in the in-plane direction.
IEEE, 2010, 35TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE, English[Refereed]
International conference proceedings
We investigated the effect of direct doping of quantum dots (QDs) with Si on the performance of QD solar cells (QDSCs). In order to control the Fermi level of intermediate band (IB) region, 25 layers of stacked InAs/GaNAs QDs were directly doped with Si impurity during the self-assembling stage of growth. A QDSC with Si doping shows an improved quantum efficiency (QE) in shorter wavelength region, which is from p-GaAs emitter layer. Further, the fact that applied external bias does not affect QE spectrum as well as photocurrent in QDSC with Si direct doping suggests that carrier collection has been enhanced in QD region as a result of reduction of recombination.
IEEE, 2010, 35TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE, 1834 - 1837, English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
In this paper, we report a control of the polarization property in quantum dot semiconductor optical amplifiers (QD-SOAs) using vertically-stacked, electronically-coupled InAs/GaAs QDs grown by molecular beam epitaxy. By optimizing the number of stacked layers and intermediate GaAs thickness, the 9-stacked QDs demonstrated the polarization-insensitive operation within 1.2 dB in the 1.3-mu m optical communication band. Our results demonstrate that the electronically-coupled QDs are useful to realize the polarization-insensitive QD-SOAs.
IOP PUBLISHING LTD, 2010, QUANTUM DOTS 2010, 245, English[Refereed]
International conference proceedings
An all-optical switching device has been proposed by using self-assembled InAs/GaAs quantum dots (QDs) within a vertical cavity structure for ultrafast optical communications. This device has several desirable properties, such as the ultra-low power consumption, the micrometre size, and the polarization insensitive operation. Due to the three-dimensional confined carrier state and the broad size distribution of self-assembled InAs/GaAs QDs, it is crucial to enhance the interaction between QDs and the cavity with appropriately designed 1D periodic structure. Significant QD/cavity nonlinearity is theoretically observed by increasing the GaAs/AlAs pair number of the bottom mirror. By this consideration, we have fabricated vertical-reflection type QD switches with 12 periods of GaAs/Al0.8Ga0.2As for the top mirror and 25 periods for the bottom mirror to give an asymmetric vertical cavity. Optical switching via the QD excited state exhibits a fast switching process with a time constant down to 23 ps, confirming that the fast intersubband relaxation of carriers inside QDs is an effective means to speed up the switching process. A technique by changing the light incident angle realizes wavelength tunability over 30 nm for the QD/cavity switch.
SPIE-INT SOC OPTICAL ENGINEERING, 2010, QUANTUM DOTS AND NANOSTRUCTURES: SYNTHESIS, CHARACTERIZATION, AND MODELING VII, 7610, English[Refereed]
International conference proceedings
We theoretically studied anisotropic linear optical polarization properties in CdTe/Cd(0.75)Mn(0.25)Te quantum wires (QWRs) by using the multi-band effective mass method. In this QWR system. the spatial distribution of the Mn composition influences both the lateral quantum confinement and the sp-d exchange coupling. The calculated expectation value of the hole spin demonstrates that the hole spin is reoriented along the external magnetic field when applying the magnetic field parallel to the QWR. The hole-spin reorientation causes anisotropic behavior in the Zeeman shift and the linearly polarized optical transitions, which sensitively depends on the Mn spatial distribution. Such characteristic features appeared in the QWR have been demonstrated experimentally and compared with the theoretical calculations. (C) 2009 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE BV, Dec. 2009, JOURNAL OF LUMINESCENCE, 129 (12), 1448 - 1453, English[Refereed]
Scientific journal
The temperature response of the thermal conductivity (lambda) of metal thin films has been investigated by the thermoreflectance (TR) method. The phase lag of the TR signals depends on the thermal diffusivity when the heating area is small, while on the thermal effusivity when the heating area is large. This enables us to evaluate lambda by analyzing the three-dimensional thermal propagation in the film on the substrate. We show that by analyzing the TR signals, lambda of Cu-Pt alloy thin films formed on glass substrates can be estimated. The estimated lambda drastically decreases with an increase in the Pt concentration. Furthermore, we discuss these results by considering the crystallographic properties of the abovementioned thin films investigated by transmission electron microscopy and x-ray diffraction. (C) 2009 American Institute of Physics. [doi:10.1063/1.3265994]
AMER INST PHYSICS, Dec. 2009, REVIEW OF SCIENTIFIC INSTRUMENTS, 80 (12), English[Refereed]
Scientific journal
A new side electron emission device (SEED) was fabricated with carbon nanofiber/aluminum (CNF/Al) composites prepared by the elastomer precursor method. In the SEED, a cross-sectional side face of the CNF/Al composite plate was perpendicularly placed onto an anode surface by inserting an insulating spacer. Above a certain threshold voltage in a vacuum, field electrons were obtained from the side face of the composite emitter. With increasing content of CNFs in the composite, the threshold voltage decreased and emission currents increased. The current of -8 mu A was kept stable up to 93 h under a continuous application of 1 kV. This improved stability as compared to a conventional field emission device was attributed to a reduced damage of CNFs in the SEED structure. (C) 2009 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE SA, Nov. 2009, THIN SOLID FILMS, 518 (2), 530 - 533, English[Refereed]
Scientific journal
Self-assembled InAs/GaAs quantum dots (QDs) incorporated in an asymmetric GaAs/Al(0.8)Ga(0.2)As vertical cavity have been employed as an optical nonlinear medium for reflection-type all-optical switches. Switching time down to 23 ps together with wavelength tuning range over 30 nm have been achieved in this structure. An angle-dependent behavior of the switching time has been observed, which suggests there is a coupling mechanism between the ground and excited states in QDs with different sizes.
AMER INST PHYSICS, Jul. 2009, APPLIED PHYSICS LETTERS, 95 (2), English[Refereed]
Scientific journal
A novel thermal conductivity measurement technique combining a periodically modulated thermoreflectance method with numerical simulation has been developed to precisely estimate the thermal conductivity of sub-micrometer thickness metal films. Numerical simulation about the surface temperature response was carried out assuming that the sample surface is irradiated by variable heating area in micrometer order using an amplitude modulated laser beam. Analyzed results show that the phase lag of the reflectance signal depends on not only the thermal effusivity but also on the thermal diffusivity of the film in local heating. Hence, the thermal conductivity determined by the thermal effusivity and the thermal diffusivity can be evaluated by the dependence of the phase lags on the heating area. This technique was applied for Cu (1-x)Pt x (0≦X≦ 1.63 at%) films with 300 nm thickness deposited on glass substrates. The evaluated thermal conductivity varies from 340 W/ (mK) to 97 W/ (mK) with increasing Pt concentration. We found that the thermal conductivity of the Cu thin film becomes less than 90% of that of the bulk value (∼400 W/(mK)). Moreover, the evaluated thermal conductivity was confirmed to correspond well to the electric conductivity with the Wiedemann-Franz law. © 2009 The Japan Institute of Metals.
Jun. 2009, Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 73 (6), 434 - 438, Japanese[Refereed]
Scientific journal
Self-assembled InAs/GaAs quantum dots (QD) incorporated in a GaAs/AlAs Fabry-Perot cavity have been employed as an optical nonlinear source for vertical-reflection type switches. Switching times of 32 similar to 80 ps have been achieved in this novel structure. All-optical switching using excited QD states shows better performance due to fast carrier relaxation between QD energy states. These results demonstrate potential application of QD materials in ultra-fast all-optical switching devices.
IEEE, 2009, 2009 IEEE 21ST INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE & RELATED MATERIALS (IPRM), 406 - +, English[Refereed]
International conference proceedings
[Refereed]
Scientific journal
[Refereed]
Research institution
We have investigated the propagation effects on the transient response of confined excitons in GaAs thin films by a reflection-type pump-probe technique. The spectrally integrated signal demonstrated slower rise than the pulse width in the negative time region. Moreover, reflectivity change spectra indicate that the response in the negative time region originates from the effect of the confined excitons and that the signal rise time at each exciton state is different. The propagation velocities estimated from the rise times and the film thickness correspond to the group velocities of the exciton polariton in bulk crystals. Therefore, the origin of the responses in the negative time region is the pulse modulation caused by the propagation effect of exciton polariton. In addition, it was confirmed that this propagation disappears with an increase in temperature due to the spatial decoherence of excitons. These results demonstrate that the propagation effect of exciton polariton on optical response in femtosecond time scale has a considerable influence in the realization of ultrafast optical devices. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2009, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, SUPPL 1, 6, S139 - S142, English[Refereed]
International conference proceedings
We demonstrate the control of the exciton dynamics in self-assembled InAs quantum dots (QDs) by introducing a nitridation layer and a GaAs spacer layer on the QD surface. The PL intensity and decay time decrease owing to the introduction of the nitridation layer. Moreover, by inserting the GaAs spacer layer between the QD surface and the nitridation layer, the PL intensity of and decay time increase. These changes in PL characteristics correspond to that of the non-radiative recombination rate caused by crystal defects. Our results imply that the exciton response time of InAs QDs can be controlled by the thickness of the spacer layer. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
WILEY-V C H VERLAG GMBH, 2009, PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, SUPPL 1, 6, S146 - S149, English[Refereed]
International conference proceedings
We demonstrated mercury-free narrow-band deep-ultraviolet luminescence from field-emission devices with Al(1-x)Gd(x)N thin films. The Al(1-x)Gd(x)N thin films were grown on fused silica substrates by a radio frequency reactive magnetron sputtering method. The deposited film shows a strong c-axis preferential orientation. A resolution limited, narrow intra-4f luminescence line from Gd(3+) ions has been observed at 315 nm. The luminescence spectrum depends on the growth temperature of the thin film, and the intensity varies as a function of the GdN mole fraction.
AMER INST PHYSICS, Nov. 2008, APPLIED PHYSICS LETTERS, 93 (21), English[Refereed]
Scientific journal
We demonstrate the possibility of ultrafast optical control of excitons confined in GaAs thin films. The intensity of a two-beam degenerate four-wave-mixing signal changes with an increase in the power of each pulse. The signal intensity monotonically decreases after reaching the maximum. Peaks appear at different excitation powers for k(1) and k(2) pulses, which suggests that the decrease in the signal intensity is caused by excitonic Rabi oscillations. Our results demonstrate the possibility of ultrafast control of the exciton population by using optical pulses. (C) 2008 The Japan Society of Applied Physics
IOP PUBLISHING LTD, Nov. 2008, APPLIED PHYSICS EXPRESS, 1 (11), English[Refereed]
Scientific journal
The emission wavelength of InAs quantum dots (QDs) capped by GaAs is found to be systematically controlled by doping nitrogen on the QDs surface with a thin spacer layer in between QDs and the nitrogen-doped layer. Cross-sectional transmission electron microscope images of the nitrogen-doped QD indicate that the nitrogen-doped layer acts as a blocking layer for In segregation. Furthermore, the in-plane linear polarization of the emission has been demonstrated to be controlled by the spacer layer thickness.
AMER INST PHYSICS, Nov. 2008, JOURNAL OF APPLIED PHYSICS, 104 (10), English[Refereed]
Scientific journal
Self-assembling process of InAs/GaAs quantum dots has been investigated by analyzing reflection high-energy electron diffraction chevron images reflecting the crystal facet structure surrounding the island. The chevron image shows dramatic changes during the island formation. From the temporal evolution of the chevron tail structure, the self-assembling process has been found to consist of four steps. The initial islands do not show distinct facet structures. Then, the island surface is covered by high-index facets, and this is followed by the formation of stable low-index facets. Finally, the flow of In atoms from the islands occurs, which contributes to flatten the wetting layer. Furthermore, we have investigated the island shape evolution during the GaAs capping layer growth by using the same real-time analysis technique. (c) 2008 American Institute of Physics.
AMER INST PHYSICS, Oct. 2008, JOURNAL OF APPLIED PHYSICS, 104 (7), English[Refereed]
Scientific journal
Anisotropic magneto-optical effects in CdTe/CdMnTe quantum wire structures have been studied theoretically by using the multiband effective-mass method. The Mn spatial distribution influences not only the lateral quantum confinement of the carrier wave function but also the exchange coupling of spins between the carrier and Mn ions. The anisotropic configuration between the spin of holes confined in the wire and the Mn spin oriented by the magnetic field causes anisotropy in the magnetic-field dependence of the valence-band structure, and this results in the anisotropic Zeeman shift and linear polarization properties of the optical transition depending on the spin configuration.
AMER PHYSICAL SOC, Aug. 2008, PHYSICAL REVIEW B, 78 (7), English[Refereed]
Scientific journal
We have investigated detailed field emission characteristics of side electron emission from carbon nanofiber (CNF)/elastomer nanocomposite sheet. Strong electron emission from the cross-sectional cutting side of the CNF/elastomer nanocomposite sheet has been confirmed even for cured nanocomposites. The threshold voltage is less than 200V and the saturation current has been found to increase gradually with the applied voltage. Utilizing the side electron emission configuration, highly efficient, indium-tin-oxide free, flexible field emission device has been demonstrated. (C) 2008 The Japan Society of Applied Physics.
IOP PUBLISHING LTD, Jul. 2008, APPLIED PHYSICS EXPRESS, 1 (7), English[Refereed]
Scientific journal
A side electron emission device was made of a carbon nanofiber/elastomer composite sheet. Instead of a conventional field emission configuration, electron emitters consisting of cross-sectional sides of the composite sheet were put in position perpendicular to the phosphor/anode surface by inserting an insulating spacer. Light emission of 4200 cd/m(2) at 1 kV was achieved by intense electron emission from the cross section since the carbon nanofibers preferentially orient parallel to the sheet plane and stick out of the cross section. This simple device structure enabled us to fabricate a flexible, transparent field emission device. (c) 2008 American Institute of Physics.
AMER INST PHYSICS, Jun. 2008, APPLIED PHYSICS LETTERS, 92 (24), English[Refereed]
Scientific journal
We report the excitonic photoluminescence (PL) characteristics in multiple stacked quantum dots (QDs) fabricated by using a strain compensating technique. The PL characteristics of QD excitons vary according to the spacer layer thickness; with decreasing spacer layer thickness, the PL intensity decreases and the PL decay time becomes longer. Furthermore, the intensity ratio of the transverse-magnetic to transverse-electric modes in the PL emission from the cleaved edge surface increases. As the spacer layer thickness decreases, the degree of overlap of the electron envelope functions owing to tunneling becomes larger, which consequently interconnects the QDs along the growth direction. This interconnection induces a large change in the oscillator strength of the QD excitons and the PL characteristics. Therefore, we concluded that the optical characteristics can be controlled drastically by changing the spacer layer thickness. (C) 2008 American Institute of Physics.
AMER INST PHYSICS, Jun. 2008, JOURNAL OF APPLIED PHYSICS, 103 (11), English[Refereed]
Scientific journal
We have studied the fine structure polarization splitting of exciton emission lines related to isoelectronic centers in an nitrogen-doped GaAs. The nitrogen doping has been performed in atomically controlled way using the (3 X 3) nitrogen stable surface of GaAs(001), which forms a series of distinct, strong, narrow bandwidth luminescence lines. The localized bound excitons have been found to consist of four signals, which can be selected by linear polarization. Magnetic-field-induced change in the splitting shows a quadratic dependence of the bright exciton splitting owing to the in-plane Zeeman interaction. Our calculations of the optical selection characteristics considering both the J-J coupling and local-field effects demonstrate the polarization splitting depending on the symmetry of the isoelectronic center.
AMER PHYSICAL SOC, May 2008, PHYSICAL REVIEW B, 77 (19), English[Refereed]
Scientific journal
Photoreflectance (PR) spectroscopy unaffected by photoluminescence and light scattering has been developed for performing precise characterization of the electronic band structure of semiconductors and semiconductor nanostructures. Dual chopping of both the pump and probe lights eliminates the unexpected components included in the signal when detecting the sum frequency or difference frequency component by using a lock-in detection system. The obtained PR signal contains no background and is considered to be an ideal electromodulated reflectance. (C) 2008 American Institute of Physics.
AMER INST PHYSICS, Apr. 2008, REVIEW OF SCIENTIFIC INSTRUMENTS, 79 (4), English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We have studied the exciton fine structures of nitrogen isoelectronic centers in GaAs. Atomically controlled nitrogen doping into GaAs realizes a series of distinct, strong, narrow bandwidth bound-exciton luminescences. The exciton fine structure has been found to consist of four signals, which can be selected by the linear polarization. Our calculations have succeeded in reproducing the optical selection characteristics when considering both the J-J coupling and local-field effects in the C(2 nu) symmetry.
IEEE, 2008, 2008 IEEE 20TH INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS (IPRM), 231 - 233, English[Refereed]
International conference proceedings
We performed an electron tomography for a single InAs quantum dot (QD) embedded in GaAs. A comprehensive three-dimensional image of indium distribution has been reconstructed by using a high-angle annular dark-field scanning transmission electron microscope. This was achieved by using a special nanopillar specimen prepared by a focused ion beam technique. The real structure of the embedded single QD has been found to have a complicated anisotropic structure reflecting the QD structure before being capped.
AMER INST PHYSICS, Jan. 2008, APPLIED PHYSICS LETTERS, 92 (3), English[Refereed]
Scientific journal
We developed mercury-free narrow-band deep-ultraviolet luminescence devices which were accomplished by performing field-emission excitation of Al1-xGdxN. The narrow band emission is a typical feature of the intra-orbital electron transition in the rare-earth Gd3+ ions. AlN, GdN and Al1-xGdxN thin films were grown on fused silica substrates by using the reactive sputtering technique. A resolution limited, narrow band luminescence line from Gd3+ ions has been observed around 315 nm. Detailed luminescence characteristics depending on the GdN mole fraction and the growth temperature have been investigated.
IOP PUBLISHING LTD, 2008, IUMRS-ICA 2008 SYMPOSIUM AA. RARE-EARTH RELATED MATERIAL PROCESSING AND FUNCTIONS, 1, English[Refereed]
International conference proceedings
We studied a technique of atomically controlled nitridation doping on GaAs(0 0 1) using (3 x 3) nitrogen (N)-stabilized reconstruction. Ordering of the N-stabilized surface has been found to depend on the (2 x 4)-reconstructed structures of GaAs(0 0 1). Nitridation transforms the (2 x 4) surfaces into the (3 x 3) by way of a new intermediate (3 x 4) surface. From these results, we proposed a model of the nitridation process on the GaAs(0 0 1) surface. Furthermore, layer-by-layer growth of a GaAs-capping layer has been confirmed on the nitrided surface. The atomically doped N-related isoelectronic centers show strong emission lines of excitons bound to N pairs ordered along [1 1 0]. (c) 2006 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE BV, Apr. 2007, JOURNAL OF CRYSTAL GROWTH, 301, 34 - 37, English[Refereed]
Scientific journal
We have studied emission-wavelength extension of nitrided InAs/GaAs quantum dots (QDs) with different sizes. Nitrided QDs have been shown to suppress In segregation during the capping layer growth. The emission wavelength reaches 1.3 mu m at room temperature. Effects of the strain on the structural and optical properties of QDs have been investigated by photoluminescence spectroscopy and transmission electron microscopy. The nitrogen-incorporation process into the InAs QDs depends on the QD size at the moment of nitrogen irradiation. The large QDs are covered by a thin nitrided layer, while the small QDs tend to form nitrogen-containing alloys. (c) 2006 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE BV, Apr. 2007, JOURNAL OF CRYSTAL GROWTH, 301, 709 - 712, English[Refereed]
Scientific journal
We succeeded in observing atomic scale images of undamaged single InAs quantum dots (QDs) embedded in a GaAs matrix using a combined use of high resolution transmission electron microscope (HRTEM) and focused ion beam (FIB) system for the first time. The QD can be viewed from multidirections, and a conclusive and comprehensive interpretation of the size and shape anisotropy has been achieved. Asymmetry of the structural properties has been confirmed between the [ I 10] and [-110] crystallographic directions. The embedded QD is elongated along the [-110] axis. The strain-field pattern is also asymmetric according to the shape anisotropy. Our results will enable the investigation of exact structural anisotropy and their influence on the atomlike properties of QDs.
IEEE, 2007, 2007 INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS, CONFERENCE PROCEEDINGS, 579 - 581, English[Refereed]
International conference proceedings
We have studied bound-exciton states of isoelectronic centers in nitrogen doped GaAs by photoluminescence (PL) spectroscopy. The nitrogen doping has been performed in atomically controlled way using the (3x3) nitrogen stable surface on GaAs(001), which has succeeded in forming a series of distinct, strong, narrow bandwidth PL lines. The PL lines have been attributed to recombinations from excitons bound to nitrogen pairs ordered along [110]. Magneto PL have been performed to reveal the ground states.
AMER INST PHYSICS, 2007, PHYSICS OF SEMICONDUCTORS, PTS A AND B, 893, 249 - +, English[Refereed]
International conference proceedings
We have theoretically studied the anisotropic magnetic-field evolution of the valence-band states in CdMnTe quantum wires by using a multiband effective-mass method. The Zeeman diagram depends on the direction of the magnetic field against the wire direction. The optical transition probability has been found to show a dramatic change in the polarization because of the valence-band mixing. The calculated magneto-optical properties are carefully compared with experimental results observed in CdTe/CdMnTe tilted superlattices.
AMER INST PHYSICS, 2007, PHYSICS OF SEMICONDUCTORS, PTS A AND B, 893, 1245 - +, English[Refereed]
International conference proceedings
Self-assembling process of InAs/GaAs quantum dots (QDs) has been investigated by analyzing reflection high-energy electron diffraction (RHEED) images. During the island formation, the chevron diffraction of the RHEED shows dramatic changes depending on the As pressure. The self-assembling process has been found to consist of four steps. Initially islands are preferentially covered by high-index facets, which transform into low-index surfaces as the growth proceeds, and then the islands are covered by stable low-index facets. In this growth step, the island size becomes uniform, because of the self-limited growth. In the next step, we found indium flow back from the islands into the wetting layer, which causes shrinkage of the island size as well as formation of giant islands. This indium flow back can be controlled by As pressure.
IEEE, 2007, 2007 INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS, CONFERENCE PROCEEDINGS, 303 - 306, English[Refereed]
International conference proceedings
The authors succeeded in observing atomic scale images of undamaged single InAs quantum dots (QDs) embedded in the GaAs matrix using high resolution transmission electron microscope equipped with focused ion beam system. The QD can be viewed from multidirections, and a conclusive and comprehensible determination of the size and the shape anisotropy has been realized. Asymmetry of the structural properties has been confirmed between the [110] and [-110] crystal directions. The embedded QD is elongated along the [-110] axis. The strain-field pattern is also asymmetric according to the shape anisotropy. The results will enable the investigation of the exact structure anisotropy influencing the atomlike properties of QDs. (c) 2007 American Institute of Physics.
AMER INST PHYSICS, Jan. 2007, APPLIED PHYSICS LETTERS, 90 (4), English[Refereed]
Scientific journal
We report the emission properties of the low temperature grown Si-doped AlN thin films by reactive radio-frequency magnetron sputtering technique. With increasing Si-doping concentration, the emission characteristics have been improved. The low threshold electric field of 4.4 V/mu m, and the saturation current density of 0.74 mA/cm(2) has been obtained. According to analysis of the I-V characteristics, it is found that the low effective work function causes the high emission performance. The luminance by using blue 2 phosphor exceeds 700 cd/m(2). (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
WILEY-V C H VERLAG GMBH, 2007, PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 4 NO 7 2007, 4 (7), 2490 - +, English[Refereed]
International conference proceedings
Multilayered self-assembled quantum dot (SAQD) structures are indispensable for increasing the SAQD density in practical device applications. The electronic and optical natures of these structures are affected by the spacer-layer thickness; the electronic states in SAQDs can couple vertically with decreasing the thickness. We have confirmed the control of optical emission from such coupled SAQDs, which form a SAQD-superlattice structure. The transverse-magnetic mode of photoluminescence (PL) from the coupled SAQD has been found to be enhanced. The detailed PL analyses have shown bimodal effective size distribution consisting of coupled and uncoupled SAQDs. Also, the relaxation time of the coupled SAQDs has been shown to be longer than that of the uncoupled SAQDs. The present coupled SAQD structure will provide a useful technique of controlling SAQD emission properties.
IEEE, 2007, 2007 INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS, CONFERENCE PROCEEDINGS, pp. 197-200, 197 - 200, English[Refereed]
International conference proceedings
Anisotropic magnetic-field evolution of the valence-band states in ideal Cd1-xMnxTe quantum wire structures have been studied theoretically by using multiband effective-mass method. The heavy- and light-hole bands show significant mixing owing to both the one-dimensional quantum confinement and the p-d exchange interaction. Because of the anisotropy of the initial quantization condition determined by the one-dimensional confinement, the Zeeman diagram of the valence bands exhibits anisotropic characteristics depending on the direction of the external magnetic field. According to the magnetic-field evolution of the valence-band states, the optical transition probability shows a dramatic change in the polarization.
AMERICAN PHYSICAL SOC, Dec. 2006, PHYSICAL REVIEW B, 74 (24), English[Refereed]
Scientific journal
Carbon nanotube (CNT)/elastomer nanocomposites (CECs) are flexible and easy to fabricate accordng to the required size and form. We succeeded in realizing a uniform dispersion of CNTs in the elastomer matrices of natural rubber (NR). Intense electron emission from the CEC sheets has been confirmed; the threshold electric field is about. 1 V/mu m, and the saturation current density reaches 10 mA/cm(2). We discuss composite structures consisting of electrically conductive CNT networks dispersed in the insulating NR matrix. Local electric field is enhanced at the CEC surface, and the low threshold field is attributed to the sharp tips and side walls of bent CNTs that appeared on the surface.
INST PURE APPLIED PHYSICS, Nov. 2006, JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 45 (42-45), L1186 - L1189, English[Refereed]
Scientific journal
We have succeeded in homogeneously dispersing multi-walled carbon nanotubes (MWNTs) into an aluminum (Al) matrix by a novel elastomer precursor method. In thus prepared composite, the disentangled MWNTs were tightly bound to the Al matrix via oxygen-mediated AlN interfacial layer. The morphology of the composite surface was controlled by different polishing procedures and their field electron emission characteristics were investigated using a mesh-gate triode-type device. The MWNT/Al plate with well-rugged surface emitted, electrons over a threshold electric field of 3 V/mu m. The current density of 1 mA/cm(2) was obtained at 6 V/mu m and the luminance reached 400 cd/m(2) under operation at 8 V/mu m.
INST PURE APPLIED PHYSICS, Jul. 2006, JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 45 (24-28), L650 - L653, English[Refereed]
Scientific journal
We have studied bound exciton states of isoelectronic centers of nitrogen-doped GaAs by photoluminescence (PL) spectroscopy. The nitrogen doping has been performed in an atomically controlled way using the (3x3) nitrogen stable surface on GaAs(001), which has succeeded in forming a series of distinct, strong, narrow bandwidth PL lines. The PL lines have been attributed to recombinations of excitons bound to nitrogen pairs ordered along [110]. Magneto PL demonstrates the Zeeman-level diagrams of the triplet state influenced by the defect anisotropy. The PL features of GaAs:N have been compared with the results for InxGa1-xAs:N
AMERICAN PHYSICAL SOC, Jul. 2006, PHYSICAL REVIEW B, 74 (3), English[Refereed]
Scientific journal
Polarization insensitivity of InAs/GaAs quantum dot (QD) optical amplifier has been demonstrated by controlling the dot shape. The height of the QD has been controlled by stacking closely InAs islands to form a columnar QD. Room-temperature polarized amplified spontaneous emission from the columnar QDs has been investigated by using variable stripe-length method. With increasing the aspect ratio, transverse-magnetic-mode-dominant optical gain has been achieved. We obtained almost polarization insensitive optical gain for QDs with seven stacking layers. (c) 2006 American Institute of Physics.
AMER INST PHYSICS, May 2006, APPLIED PHYSICS LETTERS, 88 (21), English[Refereed]
Scientific journal
Highly sensitive control of anisotropic optical polarization in CdMnTe quantum wires has been studied theoretically using multi-band effective mass method. A magnetic field dramatically changes the transition probability via the sp-d exchange interaction. © 2006 Optical Society of America.
2006, Conference on Lasers and Electro-Optics and 2006 Quantum Electronics and Laser Science Conference, CLEO/QELS 2006, English[Refereed]
International conference proceedings
Anisotropic magneto-optical effects have been studied theoretically by using multi-band effective mass method. We focus on a model of an ideal CdMnTe quantum wire surrounded by infinite potential barriers. The mixing of heavy- and light-hole bands is caused by both the one-dimensional quantum confinement and the sp-d exchange interaction. As a result of the valence-band mixing characteristic to the one-dimensional diluted magnetic semiconductor, the Zeeman splitting in the magnetic field parallel to the wire direction becomes smaller than that in the perpendicular magnetic field. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.
2006, Physica Status Solidi C: Conferences, 3 (3), 667 - 670, English[Refereed]
International conference proceedings
Nitrided InAs quantum dots (QDs) have been shown to suppress In-segregation in QDs and achieve emission at 1.3 mu m. Effects of strain on structural and optical properties of QDs have been demonstrated through transmission electron microscope and photoluminescence analyses.
IEEE, 2006, 2006 INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS CONFERENCE PROCEEDINGS, 201 - +, English[Refereed]
International conference proceedings
Anisotropic magneto-optical effects have been studied theoretically by using multi-band effective mass method. We focus on a model of an ideal CdMnTe quantum wire surrounded by infinite potential barriers. The mixing of heavy- and light-hole bands is caused by both the one-dimensional quantum confinement and the sp-d exchange interaction. As a result of the valence-band mixing characteristic to the one-dimensional diluted magnetic semiconductor, the Zeeman splitting in the magnetic field parallel to the wire direction becomes smaller than that in the perpendicular magnetic field. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
WILEY-VCH, INC, 2006, PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 3 NO 3, 3 (3), 667 - +, English[Refereed]
International conference proceedings
We have investigated the electronic band structure of a long-range-ordered Ga0.5In0.5P/GaAs heterointerface by optical measurements and a semi-empirical calculation. Raman-scattering spectra of the ordered Ga0.5In0.5P/GaAs samples show plasmon-phonon coupled modes induced by dense electron accumulation at the heterointerface, in contrast to that of the unordered sample which shows the spectrum of bulk GaAs. Furthermore, the Franz-Keldysh oscillation observed in the photoluminescence-excitation spectrum indicates a strong interface electric field. According to the results of a comparison between the experiment and a semi-empirical calculation based on Poisson's law, it is found that the spatial distribution of the accumulated electron density is modified strongly by the conduction-band discontinuity and the interface field, depending on the order parameter.
JAPAN SOC APPLIED PHYSICS, Oct. 2005, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 44 (10), 7390 - 7394, English[Refereed]
Scientific journal
We have investigated spontaneously accumulated two-dimensional electrons at the long-range ordered Ga 0.5In 0.5P/GaAs interface as a function of the order parameter. Raman-scattering and photoluminescence measurements reveal that the accumulated electron density and interface built-in electric field depend systematically on the order parameter. These results agree well with self-consistent calculations taking into account electronic band structure with the two-dimensional electrons. © 2005 American Institute of Physics.
30 Jun. 2005, AIP Conference Proceedings, 772, 387 - 388, English[Refereed]
International conference proceedings
We have investigated cleaved-edge photoluminescence (PL) polarization properties of InAs/GaAs quantum dot (QD) traveling-type semiconductor optical amplifiers (SOAs). Transverse-electric (TE) and transverse magnetic (TM) mode PL intensities of the devices have been examined. TE-mode PL intensity of QD-SOA is observed to be much stronger than TM-mode. The results indicate that the valence band edge of the QDs is heavy-hole like. Temperature dependence on the PL polarization properties of QD-SOA has been carried out and analyzed. It is observed that an enhancement of TM-mode PL intensity of QD-SOA at higher temperature is due to the fact that the inhomogeneous thermal strain induced effect.
JAPAN SOC APPLIED PHYSICS, Apr. 2005, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 44 (4B), 2528 - 2530, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We have studied anisotropic exchange interactions in (CdTe)(0.5)(Cd0.75Mn0.25Te)(0.5) tilted superlattices fabricated by fractional monolayer growth onto a 1 degrees off vicinal surface. Compositionally modulated wire structures in the (0 0 1) plane have been confirmed by polarized PL measurements, which shows the lateral quantization perpendicular to the wire direction. The Zeeman shift in the Voigt configuration depends on the direction of the external magnetic field in the (0 0 1) plane. Linear-polarization measurements of the magneto-PL reveal reorientation of the hole spin in the CdTe-rich wire into the external field direction. Moreover, in the magnetic field parallel to the wire direction, valence-band mixing occurs, which results in the anisotropic Zeeman shift. (C) 2004 Elsevier B. V. All rights reserved.
ELSEVIER SCIENCE BV, Feb. 2005, JOURNAL OF CRYSTAL GROWTH, 275 (1-2), E2221 - E2224, English[Refereed]
Scientific journal
We have studied hole-spin reorientation in CdTe/CdMnTe nano-wire structures grown on CdMgTe (001) vicinal surface. Experimental results have been compared with calculations based on ideal CdMnTe QWR model, using multiband effective mass method.
2005, IQEC, International Quantum Electronics Conference Proceedings, 2005, 265 - 266, English[Refereed]
International conference proceedings
We have studied bound-exciton states of isoelectronic centers in nitrogen (N) doped GaAs by photoluminescence (PL) spectroscopy. The nitrogen doping has been performed in atomically controlled way using the (3×3) nitrogen stable surface on GaAs(001), which has succeeded in forming a series of distinct, strong, narrow bandwidth PL lines. The PL lines have been attributed to recombinations from excitons bound to N-pair centers along 〈110〉 directions. Nonlinear optical response caused by a triplet quenching has been confirmed.
2005, IQEC, International Quantum Electronics Conference Proceedings, 2005, 261 - 262, English[Refereed]
International conference proceedings
Emission wavelength extension into > 1.3 mu m region by atomic-layer nitridation of InAs QDs has been analyzed using AFM and TEM. We found that the nitridation increases the QD size and aspect ratio and modifies the strain distribution.
IEEE, 2005, 2005 International Conference on Indium Phosphide and Related Materials, 52 - 55, English[Refereed]
International conference proceedings
New atomic-layer nitridation process performed just after growth of InAs quantum dots produces red shift in the photolummescence (PL) by more than 100 nm. Emission at > 1.3 mu m was achieved at room temperature with no severe efficiency degradation.
IEEE, 2005, 2005 International Conference on Indium Phosphide and Related Materials, 355 - 358, English[Refereed]
International conference proceedings
We have studied dynamics of exciton magnetic polarons in CdTe/CdMnTe quantum wires. Anisotropic ultrafast evolution of the exciton magnetic polaron formation process has been found for magnetic fields parallel and perpendicular to the wire direction.
SPRINGER-VERLAG BERLIN, 2005, ULTRAFAST PHENOMENA XIV, 79, 263 - 265, English[Refereed]
International conference proceedings
We have studied long-wavelength emission in 1.3-mum optical communication range from nitrided InAs/GaAs quantum dots (QDs). Atomic-layer nitridation just after the growth of InAs QDs realizes a remarkable redshift of the photoluminescence peak by more than 150 nm. Growth temperature plays a key role in achieving room-temperature emission from the QDs. The emission wavelength can be adjusted by controlling the growth conditions of the initial InAs QDs. As compared with conventional QDs grown without nitridizing the QD surface, it is found that the nitridation results in larger dots with a large aspect ratio. (C) 2005 American Institute of Physics.
AMER INST PHYSICS, Jan. 2005, JOURNAL OF APPLIED PHYSICS, 97 (2), English[Refereed]
Scientific journal
We have studied anisotropic exchange interaction in (CdTe)(0.5)(Cd0.75Mn0.25Te)(0.5) tilted superlattices fabricated by fractional monolayer growth onto a 1 degrees off vicinal surface. The Zeeman shift in the Voigt configuration depends on the direction of the external magnetic field in the (001) plane. When applying the external magnetic field parallel to the wire direction, linear polarization of the magneto-PL reveals reorientation of hole spins into the external field direction. Moreover, in the parallel magnetic field the valence-band mixing occurs for fields larger than similar to 3.5 T, which results in anisotropic Zeeman shifts.
AMER INST PHYSICS, 2005, Physics of Semiconductors, Pts A and B, 772, 1353 - 1354, English[Refereed]
International conference proceedings
We have studied anisotropic Zeeman shift of magneto-photoluminescence (PL) from (CdTe)0.5(Cd0.75Mn0.25Te)0.5 tilted superlattices fabricated by fractional monolayer growth onto a 1° off vicinal surface of CdTe0.74Mg0.26Te(001). Compositionally modulated wire structures in the (001) plane have been confirmed by polarized PL. The Zeeman shift of the (CdTe)0.5(Cd0.75Mn 0.25Te)0.5 tilted superlattices is about 150 times of that of a nonmagnetic system of (CdTe)0.5(Cd0.74Mn 0.26Te)0.5 tilted superlattices in the Faraday configuration, which is caused by the exchange interaction between excitons and Mn ions. The magneto-PL depends on the direction of the external magnetic field in the (001) plane the Zeeman shift in the perpendicular field to the wire direction is larger than that in the parallel field. Furthermore, we demonstrate a reorientation of hole spins in the magnetic field parallel to the wire. The observed anisotropic Zeeman shift is attributed to the one-dimensional spin quantization, with the total angular momentum being projected along the confinement axis in the wire structure.
Jun. 2004, Physical Review B - Condensed Matter and Materials Physics, 69 (23), 1 - 233308, English[Refereed]
Scientific journal
We have studied anisotropic Zeeman shift of magneto-photoluminescence (PL) from (CdTe)(0.5)(Cd0.75Mn0.25Te)(0.5) tilted superlattices fabricated by fractional monolayer growth onto a 1(degrees) off vicinal surface of CdTe0.74Mg0.26Te(001). Compositionally modulated wire structures in the (001) plane have been confirmed by polarized PL. The Zeeman shift of the (CdTe)(0.5)(Cd0.75Mn0.25Te)(0.5) tilted superlattices is about 150 times of that of a nonmagnetic system of (CdTe)(0.5)(Cd0.74Mn0.26Te)(0.5) tilted superlattices in the Faraday configuration, which is caused by the exchange interaction between excitons and Mn ions. The magneto-PL depends on the direction of the external magnetic field in the (001) plane; the Zeeman shift in the perpendicular field to the wire direction is larger than that in the parallel field. Furthermore, we demonstrate a reorientation of hole spins in the magnetic field parallel to the wire. The observed anisotropic Zeeman shift is attributed to the one-dimensional spin quantization, with the total angular momentum being projected along the confinement axis in the wire structure.
AMERICAN PHYSICAL SOC, Jun. 2004, PHYSICAL REVIEW B, 69 (23), English[Refereed]
Scientific journal
We report polarization properties of InAs self-assembled quantum dots (QD) observed from cleaved-edge photoluminescence (PL) of the dots. Transverse-electric (TE) and transverse-magnetic (TM) mode intensities were monitored for dots having In composition of x = 0 and 0.13. TE-mode intensity for dots with x = 0 is much larger than TM-mode intensity. On the other hand, for x = 0.13, TM-mode intensity is dominant, i.e., the polarization is inverted. The results indicate that the polarization anisotropy of the dots in the active region of the waveguide structure can be controlled by the capping layer In compositions.
INST PURE APPLIED PHYSICS, Apr. 2004, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 43 (4B), 1978 - 1980, English[Refereed]
Scientific journal
We have studied the polarization properties of cleaved-edge photoluminescence (PL) from InAs/GaAs self-assembled quantum dots. Transverse-electric (TE) and transverse-magnetic (TM) mode PL intensities have been analyzed for the dots having 8 nm InxGa1-xAs capping layer with indium (In) composition of x=0 and 0.13. Polarization results show a dramatic change with the capping layer In compositions; TE-mode dominant PL is observed for dots with x=0, on the other hand, TM-mode dominant PL for dots with x=0.13. This polarization change has been attributed to the dot shape change using transmission electron microscopy images. These results suggest that the optical polarization anisotropy of the quantum dots can be controlled by manipulating the capping layer In composition. (C) 2004 American Institute of Physics.
AMER INST PHYSICS, Mar. 2004, APPLIED PHYSICS LETTERS, 84 (11), 1820 - 1822, English[Refereed]
Scientific journal
We observed anisotropic large peak-energy shift of photoluminescence (PL) from CdTe/Cd0.75Mn0.25Te quantum wires (QWRs). The large PL-peak-energy shift is caused by the exchange interaction between excitons in the non-magnetic QWR and Mn ions in the DMS barrier. The exchange interaction is enhanced when magnetic field is perpendicular to the QWR. (C) 2003 Elsevier B.V. All rights reserved.
ELSEVIER SCIENCE BV, Mar. 2004, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 21 (2-4), 345 - 348, English[Refereed]
Scientific journal
We have studied anisotropic exchange interaction in (CdTe) 0.5(Cd0.75Mn0.25Te)0.5 tilted superlattices fabricated by fractional monolayer growth onto a 1° off vicinal surface of Cd0.74Mg0.26Te (001). The (CdTe) 0.5(Cd0.75Mn0.25Te)0.5 tilted superlattices have been confirmed by polarized photoluminescence to be equivalent to compositionally modulated quantum wires consisting of CdTe-rich and Cd0.75Mn0.25Te-rich wires. The Stokes shift for the CdTe-rich wires is remarkable at less than 10K. The large Stokes shift is due to exciton-magnetic polaron formation and non-magnetic localization. The exciton magnetic polaron formation is a result of the exchange interaction between excitons and Mn ions. The exchange interaction causes the large Zeeman shift of the CdTe-rich wires. The Zeeman shift depends on the direction of the magnetic field in the (001) plane the Zeeman shift in the magnetic field parallel to the wire direction is smaller than that in the perpendicular field. We demonstrate reorientation of hole spins in the parallel magnetic field by polarized magneto-photoluminescence measurements. The reorientation of the hole spins causes the valence-band mixing, which results in the small Zeeman shift in the parallel magnetic field.
Society of Materials Science Japan, 2004, Zairyo/Journal of the Society of Materials Science, Japan, 53 (12), 1346 - 1350, Japanese[Refereed]
Scientific journal
[Refereed]
Scientific journal
[Refereed]
Scientific journal
A technique to grow InAs quantum dots (QDs) to extend the emission wavelength into 1.3 mum range has been developed. We performed nitridation after growing InAs QDs by molecular-beam epitaxy. During nitridation, the reflection high-energy electron diffraction keeps chevron patterns, as well as streak rods, coming from the wetting layer. A longer-wavelength emission line with a narrower spectral linewidth compared with those of InAs QDs has been observed. (C) 2003 American Institute of Physics.
AMER INST PHYSICS, Nov. 2003, APPLIED PHYSICS LETTERS, 83 (20), 4152 - 4153, English[Refereed]
Scientific journal
We performed Fourier transformed photoreflectance (PR) spectroscopy on GaAs/Ga0.5In0.5P heterojunction bipolar transistor wafers. The use of Fourier transformation of the PR spectrum resolves the signals coming from the emitter-base and base-collector interfaces. The evaluated interface electric fields were compared with the capacitance obtained from capacitance-voltage measurements. The result for the base-collector interface is consistent with the Poisson equation. On the other hand, the atomic ordering in the Ga0.5In0.5P emitter plays an important role in determining the characteristics of the emitter-base interface. (C) 2003 American Institute of Physics.
AMER INST PHYSICS, Nov. 2003, JOURNAL OF APPLIED PHYSICS, 94 (10), 6487 - 6490, English[Refereed]
Scientific journal
We have investigated the photoluminescence (PL) polarization properties of InAs/GaAs self-assembled quantum dots (QDs). An 8 nm InxGa1-xAs capping layer was overgrown on InAs QDs in order to modify the strain distribution in the dots. TE and TM mode PL polarizations of samples with capping layer indium composition of x = 0 and x = 0.13 were detected and analyzed. The TE/TM ratio shows heavy-hole dominant optical transition for samples with x = 0. On the other hand, samples with x = 0. 13 show light-hole dominant optical transition. These results indicate valence band state inversion through in-plane strain distribution dependent on the capping layer composition.
WILEY-V C H VERLAG GMBH, Jul. 2003, PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 238 (2), 229 - 232, English[Refereed]
Scientific journal
Transitions in GaAs(001) surface reconstruction have been studied by using reflectance anisotropy spectroscopy. The transition between c(4x4) and (2x4) exhibits a 20 degreesC wide hysteresis cycle under As-4 flux of 2x10(-7) Torr beam equivalent pressure. The width of the hysteresis becomes smaller under higher As-4 pressure, i.e., at higher temperature and at higher speed of the temperature change. On increasing the temperature, the c(4x4) surface changes slowly into (2x4) in about 2 h. The transition is a reversible reaction with different activation energies.
AMER PHYSICAL SOC, May 2003, PHYSICAL REVIEW B, 67 (19), English[Refereed]
Scientific journal
Ultrafast response of the diffraction efficiency of a photorefractive multiple quantum well(PRMQW) has been investigated by pump-probe spectroscopy. We evaluated the temporal evolution of the diffraction efficiency of the PRMQW using a differential transmission spectrum. The results were compared with the output-widening factor of diffracted pulses. A good agreement obtained between our evaluation results and the results. of electric-field cross correlation has confirmed the applicability of our technique in characterizing the diffraction efficiency of the PRMQW.
INST PURE APPLIED PHYSICS, Apr. 2003, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 42 (4B), 2329 - 2331, English[Refereed]
Scientific journal
[Refereed]
Scientific journal
We have investigated excitonic luminescence from (formula presented) quantum wires (QWR’s) grown on vicinal substrates. The temperature dependence of the radiative lifetime of one-dimensional exciton in the QWR’s was measured using time-resolved spectroscopy. The results are compared with that of two-dimensional exciton in (formula presented) quantum well (QW). The radiative lifetimes of one-dimensional exciton in the QWR’s and two-dimensional exciton in the QW increase with T but show clearly different behavior. The observed radiative lifetime in the QWR’s obeys (formula presented) in a wide temperature range, confirming the one-dimensional nature in exciton thermalization. On the other hand, the radiative lifetime in the QW is linear with T. Furthermore, we observed clear biexciton formation at (formula presented) in the QWR’s. The biexciton binding energy estimated from the line-shape analysis of the luminescence spectra for the QWR’s is 5.2 meV. © 2003 The American Physical Society.
04 Feb. 2003, Physical Review B - Condensed Matter and Materials Physics, 67 (8), English[Refereed]
Scientific journal
We have investigated excitonic luminescence from CdTe/Cd0.74Mg0.26Te quantum wires (QWR's) grown on vicinal substrates. The temperature dependence of the radiative lifetime of one-dimensional exciton in the QWR's was measured using time-resolved spectroscopy. The results are compared with that of two-dimensional exciton in CdTe/Cd0.74Mg0.26Te quantum well (QW). The radiative lifetimes of one-dimensional exciton in the QWR's and two-dimensional exciton in the QW increase with T but show clearly different behavior. The observed radiative lifetime in the QWR's obeys T-1/2 in a wide temperature range, confirming the one-dimensional nature in exciton thermalization. On the other hand, the radiative lifetime in the QW is linear with T. Furthermore, we observed clear biexciton formation at less than or similar to10 K in the QWR's. The biexciton binding energy estimated from the line-shape analysis of the luminescence spectra for the QWR's is 5.2 meV.
AMER PHYSICAL SOC, Feb. 2003, PHYSICAL REVIEW B, 67 (8), English[Refereed]
Scientific journal
We performed photoreflectance (PR) spectroscopy in order to investigate the fundamental band gap of GaAs1-xBix alloys. The temperature dependence of the band gap energy was evaluated by analyzing of the Franz-Keldysh oscillation in the PR spectra. With increasing Bi content, the band gap energy of GaAs1-xBix alloy is reduced, which shows a large optical bowing. The temperature coefficient of the band,gap decreases appreciably in alloys with increasing Bi content. For x = 0.026, the temperature coefficient near room temperature is -0.15 meV/K which is 1/3 of the value for GaAs.
INST PURE APPLIED PHYSICS, Feb. 2003, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 42 (2A), 371 - 374, English[Refereed]
Scientific journal
We have developed a new contactless characterization technique for GaAs/Ga0.5In0.5P heterojunction bipolar transistor (HBT) wafers using photoreflectance (PR) spectroscopy. The use of Fourier transformation (FT) of the PR spectrum succeeds in resolving the signals coming from the emitter-base and base-collector interfaces. The evaluated interface electric fields were compared with capacitance obtained from capacitance-voltage (C-V) measurements and interpreted by considering atomic ordering in the Ga0.5In0.5P emitter.
IEEE, 2003, 2003 INTERNATIONAL CONFERENCE INDIUM PHOSPHIDE AND RELATED MATERIALS, CONFERENCE PROCEEDINGS, 531 - 533, English[Refereed]
International conference proceedings
Polarization anisotropy of photoluminescence (PL) from the cleaved edge surface of columnar InAs/GaAs self-assembled quantum dots (QDs) has been investigated. The columnar QDs were fabricated by closely stacking the Stranski-Krastanov-mode InAs-island layers. PL peak energy and anisotropy of the PL polarization sensitively depends on the stacking layer number. Whereas the single-island-layer sample shows strong transverse-electric (TE)-mode PL, the PL-intensity ratio of TE-mode PL to transverse-magnetic (TM)-mode PL decreases with increasing stacking layer number. The polarization inversion of TE/TM-mode PL-intensity ratio has been accomplished beyond the stacking layer number of 9. The polarization spectra of the columnar QDs with >9 stacking layers indicate that TM-mode becomes dominant near the ground state transition.
WILEY-VCH, INC, 2003, 2ND INTERNATIONAL CONFERENCE ON SEMICONDUCTOR QUANTUM DOTS, 0(4),1137-1140, 1137 - 1140, English[Refereed]
International conference proceedings
The magneto-optical properties in CdTe/CdMgTe quantum wires (QWRs) grown on a vicinal substrate were investigated. With increasing magnetic field, the exciton photo luminescence (PL) shows a slight energy shift, The energy shift of the exciton-PL peak can be described by the exciton Zeeman splitting and the diamagnetic shift. The effective g factor obtained from the Zeeman splitting for the QWRs were found to be larger than for CdTe/CdMgTe quantum well, indicating size dependence to the effective g factor in the QWRs. Furthermore, it was found that the biexciton formation is suppressed by magnetic field, and the suppression behaviour is dependent on the direction of magnetic field to the QWRs.
IOP PUBLISHING LTD, 2003, COMPOUND SEMICONDUCTORS 2002, 174, 173 - 177, English[Refereed]
Scientific journal
[Refereed]
[Refereed]
We studied two-dimensional properties of electrons accumulated at the GaAs side of Ga0.5In0.5P/GaAs-single heterointerface. Long-range ordering in Ga0.5In0.5P causes the electron accumulation at the GaAs side of the heterointerface. Photoluminescence (PL) spectra of GaAs have been systematically measured for undoped unordered and ordered Ga0.5In0.5P/GaAs samples. A PL spectrum of the ordered sample shows signals related to the quantized electron state in a triangular potential buried at the heterointerface and the Fermi-edge singularity, in contrast that the unordered sample shows a typical PL spectrum of a high-quality bulk GaAs. Magneto-PL spectra indicate that the reduced exciton masses between parallel and perpendicular to the heterointerface are anisotropic. We found clear optical Shubnikov-de Haas (SdH) oscillations in both the PL intensity and the transition energy under the perpendicular magnetic field. These PL features demonstrate that the electrons accumulated at the heterointerface act as two-dimensional electron gas (2DEG). The sheet-carrier density of the 2DEG is deduced from the period of the observed SdH oscillation and it found to be ∼1.20 X 1012 cm-2.
15 Nov. 2002, Physical Review B - Condensed Matter and Materials Physics, 66 (19), 1953171 - 1953177[Refereed]
Scientific journal
We have studied in situ Stranski-Krastanov growth surface of (In,Ga)As grown by molecular-beam epitaxy on GaAs (001) using reflectance-difference (RD) spectroscopy and reflection high-energy electron diffraction. The surface of the two-dimensional wetting layer shows various structures depending on the InAs coverage and the growth temperature. At relatively low substrate temperature, the growth transition from two-dimensional to three-dimensional occurs on the (2 x 3) surface of (In,Ga)As, whereas at high-temperature the transition occurs on the (2 x 4) surface of InAs. Comparing the measured RD spectra with the calculations based on the tight-binding surface-linear-response method, we found that both [110]-In and [110]-As dimers are necessary for the (2 x 3) and (2 x 4) surfaces to explain the observed RD spectra. Time-resolved measurements demonstrate that disappearance of excess As surface triggers the islanding process. Furthermore, the In-dimer-related signal shows a redshift near the growth transition due to the strain relaxation.
15 Nov. 2002, Physical Review B - Condensed Matter and Materials Physics, 66, 1953121 - 1953126[Refereed]
[Refereed]
We studied two-dimensional properties of electrons accumulated at the GaAs side of Ga0.5In0.5P/GaAs-single heterointerface. Long-range ordering in Ga0.5In0.5P causes the electron accumulation at the GaAs side of the heterointerface. Photoluminescence (PL) spectra of GaAs have been systematically measured for undoped unordered and ordered Ga0.5In0.5P/GaAs samples. A PL spectrum of the ordered sample shows signals related to the quantized electron state in a triangular potential buried at the heterointerface and the Fermi-edge singularity, in contrast that the unordered sample shows a typical PL spectrum of a high-quality bulk GaAs. Magneto-PL spectra indicate that the reduced exciton masses between parallel and perpendicular to the heterointerface are anisotropic. We found clear optical Shubnikov-de Haas (SdH) oscillations in both the PL intensity and the transition energy under the perpendicular magnetic field. These PL features demonstrate that the electrons accumulated at the heterointerface act as two-dimensional electron gas (2DEG). The sheet-carrier density of the 2DEG is deduced from the period of the observed SdH oscillation and it found to be similar to1.20x10(12) cm(-2).
AMER PHYSICAL SOC, Nov. 2002, PHYSICAL REVIEW B, 66 (19), English[Refereed]
Scientific journal
The linear-polarization character of photoluminescence (PL) from the cleaved edge surface of columnar InAs/GaAs self-assembled quantum dots (QDs) has been investigated. The columnar QDs were fabricated by closely stacking the Stranski-Krastanov-mode InAs-island layers. Anisotropy of the PL polarization depends on the stacking layer number. The single-island-layer sample shows strong transverse-electric (TE)-mode PL. With increasing stacking layer number, the PL-intensity ratio of TE-mode PL to transverse-magnetic (TM)-mode PL decreases. Then. the TE/TM-mode PL-intensity ratio is inverted beyond the stacking layer number of 9. Our results suggest that a polarization-independent transition can be accomplished by controlling the stacking layer number.
INST PURE APPLIED PHYSICS, Oct. 2002, JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 41 (10B), L1143 - L1145, English[Refereed]
Scientific journal
A novel semi-classical theory of exciton-polaritons in quantum wells (QWs) is presented. Time-resolved coherent optical spectra of QWs are described by the light coupling with ensembles of localized quantum dot-like exciton states. The ratio between reflection and resonant Rayleigh scattering (RRS) intensity gives a direct measure of the density of these excitonic dots. Good agreement with experimental data for time-resolved angle-dependent reflection and RRS from a GaAs single QW is achieved.
Apr. 2002, Physica Status Solidi (A) Applied Research, 190 (3), 703 - 707, English[Refereed]
International conference proceedings
The radiative decay of one-dimensional (113) excitons in Cd0.74Mg0.26Te/CdTe tilted superlattices (TSLs) grown on vicinal substrates is studied. The temperature dependence of the radiative lifetime of ID excitons in the TSLs is measured using time-resolved photolumineseence spectroscopy, and is compared with that of two-dimensional (2D) excitons in Cd0.74Mg0.26Te/CdTe quantum wells (QWs). Radiative lifetimes of 1D excitons in the TSLs and 2D excitons in the QWs increase with T but show clearly different behaviours. The observed radiative lifetimes in the TSLs and QWs are expressed as 100T(1/2) psK(-1/2) and 11TpsK(-1), respectively, from which the intrinsic radiative lifetime of the k similar to 0 excitons is found to be 72 ps (1D) and 5 ps (2D). The decrease of the exciton coherence length imposed by the lateral confinement in the TSLs causes the large intrinsic radiative lifetime in the TSLs.
WILEY-V C H VERLAG GMBH, Apr. 2002, PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 190 (3), 699 - 702, English[Refereed]
Scientific journal
Photoluminescence (PL) study for the long-range ordered Ga0.5In0.5P/GaAs heterointerface was performed to investigate effects of a spontaneous electron accumulation on the GaAs-PL spectrum. In contrast to sharp GaAs-signals from the disordered sample, a broad PL spectrum was observed for the ordered sample. A new structure ascribed to the Fermi edge was found at the higher-energy side of the fundamental GaAs-PL peak. From PL-excitation results, we suggest that a two-dimensional electron gas in a triangular potential is induced at the ordered Ga0.5In0.5P/GaAs heterointerface. Furthermore, magneto-PL results indicate that quantized levels in the triangular potential at the heterointerface interact with the Fermi surface. (C) 2002 Elsevier Science B.V. All rights reserved.
ELSEVIER SCIENCE BV, Mar. 2002, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 13 (2-4), 329 - 332, English[Refereed]
Scientific journal
We investigated two-dimensional properties of electrons accumulated at long-range ordered Ga0.5In0.5P/GaAs heterointeface by magneto-photolumineseence (PL) measurements. The disordered Ga0.5In0.5P/GaAs sample shows a typical GaAs-PL spectrum for the bulk GaAs grown by metalorganic vapor-phase epitaxy. On the other hand, GaAs-PL spectrum for the ordered sample with order parameter η of 0.30 shows transitions related to a quantized electron state in a triangular potential buried at the heterointerface and emission of the Fermi-edge singularity. The observed PL spectrum for the ordered sample demonstrates that a two-dimensional electron gas is induced at the Ga0.5In0.5P/GaAs heterointerface. In magneto-PL measurements, anisotropy of the reduced mass between parallel and perpendicular to the heterointerface was confirmed. Furthermore, the clear optical Shubnikov-de Haas oscillation was found in PL transition energy under the perpendicular magnetic field. The sheet-cartier density of 2DEG is deduced from the period of the observed Shubnikov-de Haas oscillation to be ∼1.20 × 1012 cm-2.
2002, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 515 - 518[Refereed]
International conference proceedings
We studied two-dimensional properties of electrons accumulated at the GaAs side of (formula presented)-single heterointerface. Long-range ordering in (formula presented) causes the electron accumulation at the GaAs side of the heterointerface. Photoluminescence (PL) spectra of GaAs have been systematically measured for undoped unordered and ordered (formula presented) samples. A PL spectrum of the ordered sample shows signals related to the quantized electron state in a triangular potential buried at the heterointerface and the Fermi-edge singularity, in contrast that the unordered sample shows a typical PL spectrum of a high-quality bulk GaAs. Magneto-PL spectra indicate that the reduced exciton masses between parallel and perpendicular to the heterointerface are anisotropic. We found clear optical Shubnikov-de Haas (SdH) oscillations in both the PL intensity and the transition energy under the perpendicular magnetic field. These PL features demonstrate that the electrons accumulated at the heterointerface act as two-dimensional electron gas (2DEG). The sheet-carrier density of the 2DEG is deduced from the period of the observed SdH oscillation and it found to be (formula presented). © 2002 The American Physical Society.
2002, Physical Review B - Condensed Matter and Materials Physics, 66 (19), 1 - 7, English[Refereed]
Scientific journal
Excitonic luminescence from CdTe/Cd0.74Mg0.26Te quantum wires (QWRs) grown on vicinal substrates was investigated. The temperature dependence of the radiative lifetime was measured. The observed radiative lifetime in the QWRs obeys T-1/2 above 10 K. At low temperature, however, a new photoluminescence (PL) signal appears at lower energy side of the exciton PL due to biexciton photogeneration. By taking account of the biexciton effect, the radiative lifetime of the exciton have been confirmed to obey the T-1/2 dependence in a wide temperature range, confirming the one-dimensional nature in exciton thermalization.
IOP PUBLISHING LTD, 2002, COMPOUND SEMICONDUCTORS 2001, (170), 519 - 524, English[Refereed]
Scientific journal
Reflectance-difference (RD) spectroscopy is employed to study in situ the Stranski-Krastanov (S-K) growth surface of (In, Ga)As on GaAs (001) during molecular-beam epitaxy and simultaneously characterized by high energy electron diffraction. At relatively low substrate temperature, the growth transition from two dimensional to three dimensional growth occurs on the (20) surface of (In,Ga)As, while at high temperature the transition occurs on the (2x4) surface of InAs. Time resolved measurements were performed for RD intensities related to the In and As dimers near the growth transition. The growth transition occurs when the [-110]-As dimer related signal saturates. Furthermore, a red shift of the In-dimer related signal was observed near the growth transition because of relaxation of the misfit strain.
IOP PUBLISHING LTD, 2002, COMPOUND SEMICONDUCTORS 2001, (170), 525 - 530, English[Refereed]
Scientific journal
We have studied in situ Stranski-Krastanov growth surface of (In, Ga)As grown by molecular-beam epitaxy on GaAs (001) using reflectance-difference (RD) spectroscopy and reflection high-energy electron diffraction. The surface of the two-dimensional wetting layer shows various structures depending on the InAs coverage and the growth temperature. At relatively low substrate temperature, the growth transition from two-dimensional to three-dimensional occurs on the (formula presented) surface of (In, Ga)As, whereas at high-temperature the transition occurs on the (formula presented) surface of InAs. Comparing the measured RD spectra with the calculations based on the tight-binding surface-linear-response method, we found that both [110]-In and (formula presented)-As dimers are necessary for the (formula presented) and (formula presented) surfaces to explain the observed RD spectra. Time-resolved measurements demonstrate that disappearance of excess As surface triggers the islanding process. Furthermore, the In-dimer-related signal shows a redshift near the growth transition due to the strain relaxation. © 2002 The American Physical Society.
01 Jan. 2002, Physical Review B - Condensed Matter and Materials Physics, 66, 1 - 6[Refereed]
We have investigated the lowest emission state in tilted superlattices as a function of their tilt angle. The II-VI tilted superlattices, CdTe/CdxMg1−xTe and CdTe/CdxMn1−xTe, were obtained by molecular beam epitaxy on vicinal substrates misoriented by 1°, which corresponds to a 186–Å terrace width. The tilt sensitivity of the optical properties is shown by both theoretical calculations and experimental results. The one-dimensional character is studied experimentally by optical spectroscopy in both excitation regimes: continuous wave and time-resolved spectroscopy. In continuous–wave photoluminescence spectra, an energy redshift of about 15 meV is observed when the superlattice is vertical. Such behavior is accounted for quantitatively by a theoretical approach that uses a periodic modulation potential to describe the lateral confinement and that takes into account the intermixing between Cd atoms and Mn (Mg) ones. In time-resolved spectroscopy, a temperature dependence of the decay time that is typical of exciton thermalization in one-dimensional systems is observed. Both these results, the energy shift and the lifetime dependence, are very sensitive to the one-dimensional character, that is, to the tilt angle of the tilted superlattice, as calculated theoretically. © 2001 The American Physical Society.
02 Apr. 2001, Physical Review B - Condensed Matter and Materials Physics, 63 (16), English[Refereed]
Scientific journal
Carrier relaxation and recombination in long-range-ordered (Al0.5Ga0.5)0.5In0.5P have been studied by selectively excited photoluminescence (PL) spectroscopy. We observed sharp resonant PL peaks under near-resonant excitation. The set of resonant PL peaks evolves according to excitation energy. The excess excitation energies for the resonant PL peaks agree well with the LO-phonon energies related to the In-P, Ga-P, and Al-P bonds of the ordered sample. Furthermore, the LA resonance caused by zone-folding effects was observed. These resonant PL intensities show different excitation energy dependence, which precludes the possibility of resonant Raman scattering. High dense excitation reveals an excited state near the X level. This suggests mixing of electron wave functions in the Γ and X states. Energy relaxation of excited carriers from the pseudodirect X state to the Γ ground state causes the resonant PL. Time-resolved spectroscopy was employed to study the carrier relaxation mechanism. © 2001 The American Physical Society.
13 Mar. 2001, Physical Review B - Condensed Matter and Materials Physics, 63 (12), English[Refereed]
Scientific journal
We found plasmon-phonon coupled modes and electric-field-induced mode in Raman-scattering spectra of long-range ordered Ga0.5In0.5P and GaAs heterointerface, Raman shifts of the coupled modes enable us to estimate an exact carrier density accumulated at the interface. Photoluminescence excitation spectra of GaAs luminescence show Franz-Keldysh oscillations induced by internal electric field in the ordered Ga0.5In0.5P. These results suggest that the long-range ordering in Ga0.5In0.5P is considered to play an important role in the carrier accumulation at the heterointerface.
SPRINGER-VERLAG BERLIN, 2001, PROCEEDINGS OF THE 25TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, PTS I AND II, 87, 453 - 454, English[Refereed]
International conference proceedings
Reflectance-difference spectroscopy (RDS) is employed to study in situ the Stranski-Krastanov (S-K) growth surface of InAs on GaAs (001) during molecular-beam epitaxy and simultaneously characterized by RHEED. We found three-type time evolutions of (In,Ga)As wetting layer depending on substrate temperature. The surface structures of the wetting layer were studied by comparing experimentally observed RD spectra measured at various InAs coverage with calculations by the ab initio pseudopotential method in a local density approximation and the tight-binding surface-linear-response method.
SPRINGER-VERLAG BERLIN, 2001, PROCEEDINGS OF THE 25TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, PTS I AND II, 87, 365 - 366, English[Refereed]
International conference proceedings
Reflectance-difference spectroscopy (RDS) is employed to study in situ the (4x2), (2x4), and (4x4) reconstructions of (001) InAs surfaces prepared in ultrahigh vacuum by molecular-beam epitaxy and simultaneously characterized by RHEED. The (001) InAs surface displays a similar phase diagram to the case of the (001) GaAs surfaces; an In-rich (4x2) structure and As-rich structures of (2x4) and (4x4). However, characteristic spectral features in terms of electronic excitations involving surface dimers of In and As axe different from those of the (001) GaAs surfaces.
SPRINGER-VERLAG BERLIN, 2001, PROCEEDINGS OF THE 25TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, PTS I AND II, 87, 353 - 354, English[Refereed]
International conference proceedings
Carrier relaxation and recombination in long-range ordered (Al0.5Ga0.5)(0.5)In0.5P have been studied by selectively excited PL spectroscopy. We found phonon assisted sharp resonant photoluminescence (PL) lines in long-range ordered (LRO) (Al0.5Ga0.5)(0.5)In0.5P by selectively excited PL spectroscopy. The observation of the resonant PL demonstrates energy relaxation from the excited state (X level) to the ground state (Gamma level) by inelastic phonon scattering.
SPRINGER-VERLAG BERLIN, 2001, PROCEEDINGS OF THE 25TH INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS, PTS I AND II, 87, 218 - 219, English[Refereed]
International conference proceedings
We performed photoreflectance (PR) and Raman-scattering measurements of long-range ordered Ga0.5In0.5P/GaAs heterointerfaces to investigate effects of internal electric field on carrier-modulation mechanism. PR spectrum of an ordered Ga0.5In0.5P/GaAs heterointerface shows the Franz-Keldysh oscillation due to a strong internal electric field. However, the PR-signal amplitude for the ordered sample is ∼1/20 of that for a disordered sample. Raman-scattering results of the ordered Ga0.5In0.5P/GaAs heterointerfaces reveal plasmon-phonon coupled modes due to the spontaneous electron accumulation. We suggest that the electron accumulation reduces the mean electric field for the PR modulation.
2001, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 330 - 333[Refereed]
International conference proceedings
Initial stages of self-assembled growth of InAs dots on GaAs(001) and a postgrowth evolution of the deposited surface have been investigated by reflectance-difference (RD) spectroscopy and reflection high-energy electron diffraction (RHEED). A significant change in the RD spectrum occurs even at 0.1-monolayer (ML) deposition of InAs. With increasing InAs deposition, the As-dimer-elated RD sign is inverted, which indicates that the original As dimer along the [110] direction of the c(4×4) As-rich GaAs(001) surface becomes dimerized along the [-110] direction. Postgrowth behavior has been studied at 480 °C after 1.9-ML deposition of InAs. During postgrowth, the As-dimer-related RD signal returns to signals observed at lower InAs deposition. This behavior gives evidence that the InAs coverage is reduced by postgrowth. Furthermore, positive offsets that increase in amplitude with photon energy appear in the RD spectra of the postgrown samples.
Jun. 2000, Applied Surface Science, 159, 503 - 507[Refereed]
Scientific journal
In situ investigation of two-dimensional InAs layer, i.e. wetting layer, during the growth in the Stranski-Krastanov mode has been performed by using reflectance-difference (RD) spectroscopy and reflection high-energy electron diffraction (RHEED). RD spectra shows a dramatic change even at 0.1-monolayer (ML) deposition of InAs, which corresponds to a change of the surface reconstruction from the c(4×4) of the As-rich GaAs (0 0 1) to a (1×3) surface reconstruction. With advanced deposition, structures around 2.0 and 2.6 eV gradually change in the sign. The signal inversion at 2.6 eV indicates that the original As dimer along the [1 1 0] becomes dimerized along the [-1 1 0]. The 2.0 eV signal, which is related to electronic structures of group-III atoms and As bond, shows a different evolution during the growth. The intensity of the 2.0 eV signal shows the minimum around 1.0-ML deposition. After that, the intensity slightly increases until the start of the dot formation. This results indicates a decrease of In concentration in the wetting layer, i.e., a precursory transport process of In before the dot formation.
May 2000, Physica E: Low-Dimensional Systems and Nanostructures, 7 (3), 891 - 895[Refereed]
Scientific journal
Scientific journal
We measured photoluminescence and Raman-scattering spectra of long-range ordered Ga0.5In0.5P/GaAs heterointerface. With increasing order parameter, GaAs-PL spectrum is gradually changed from that of the bulk GaAs to anomalous spectrum with two broad peaks. In the PL-excitation measurements, we found that these broad peaks are related to localized states in GaAs and Ga0.5In0.5P layers. On the other hand, in the Raman-scattering measurements, Ga-As LO-phonon mode shows a red shift in contrast to that of the bulk GaAs, and Ga-As TO mode appears in spite of a forbidden transition. These results suggest interdiffusion of P atoms, which induces non-crystallization of the GaAs. We considered that the GaAsP alloys are constituted at the ordered Ga0.5In0.5P/GaAs heterointerface.
2000, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 154 - 157[Refereed]
Scientific journal
The diffraction of ultrashort laser pulses from static gratings in photorefractive multiple quantum wells (PRQW) has been investigated for use it as diffractive optical elements in information processing systems with ultrashort laser pulses. The PRQW used in this experiment was specially designed to exhibit broad bandwidth. The desirable spectra of the diffracted pulses from the PRQW was observed experimentally. The bandwidth for one of the PRQW devices was 13 nm.
2000, Proceedings of SPIE - The International Society for Optical Engineering, 4110, 9 - 16, English[Refereed]
Scientific journal
Up-converted photoluminescence (UPL) was observed at thelong-range ordered (Al0.5Ga0.5)0.5In0.5P/GaAs(001)heterointerface, during the excitation of GaAs. Excitation-powerdependence of the UPL intensity reflects carrier-localizationproperties caused by potential fluctuations due to a multidomainstructure in the ordered(Al0.5Ga0.5)0.5In0.5P. When we excited the GaAslayer, photoexcited carriers spatially transferred to the(Al0.5Ga0.5)0.5In0.5P layer and relaxed fromhigher lying states to lower lying states in the fluctuatedpotential. Time-resolved measurements were performed for the UPL andnormal photoluminescence (NPL) excited by an above-gap light. Weobserved a slowly rising component in the time-resolved UPL, whereasthe NPL showed an exponential decay profile. These results revealthat the carrier-relaxation processes are different near the surfaceand near the interface of the epitaxial layer.
The Japan Society of Applied Physics, 28 Feb. 1999, Jpn J Appl Phys, 38 (2), 1001 - 1003, English[Refereed]
We demonstrate inelastic phonon scattering to be the dominant intradomain carrier-relaxation mechanism in partially ordered (Al0.5Ga0.5)0.5In0.5P. Carrier relaxation and recombination in partially ordered (Al0.5Ga0.5)0.5In0.5P have been studied by selectively excited photoluminescence (PL) spectroscopy. The partial ordering of the column-III sublattices causes a multidomain structure in the epitaxial film. The strongly modulated near-resonant excitation efficiency enables selective excitation of the ordered domains with a ground-state transition energy below the excitation energy. In the selectively excited PL spectra, we observed LA-phonon resonances as well as LO-phonon resonances. The LA-phonon resonances are new phonon modes caused by zone-folding effects and alloy disordering effects in the ordered alloy. The observation of the phonon resonances in the PL spectra is discussed in analogy to hot exciton relaxation in higher-dimensional semiconductor system and proposed to be intricately bound to the inhomogeneity of the ordered domain ensemble.
1999, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 159 - 162[Refereed]
Scientific journal
We have studied linear electrooptic effects in long-range ordered (Al0.5Ga0.5)0.5In0.5P on GaAs (115)A and GaAs (001) by polarized electroreflectance spectroscopy. The electroreflectance spectra show anisotropic interference oscillations below the band gap. The amplitude of the oscillation signal linearly depends on the applied voltage modulated from the flat band. In strongly ordered (Al0.5Ga0.5)0.5In0.5P on the GaAs(001), an anisotropy of the oscillating signal caused by a difference of refractive indexes of ordinary and extraordinary direction was found. The amplitude of the [110]-polarization spectrum is larger than that of the [110] polarization. Furthermore, the anisotropy becomes large with decreasing the detection energy. The dispersion of the anisotropic refractive index below the band gap depends on order parameter. © 7999 American Institute of Physics.
American Institute of Physics Inc., 1999, Journal of Applied Physics, 86 (6), 3140 - 3143, English[Refereed]
Scientific journal
Efficient anti-Stokes photoluminescence (PL) has been observed in (Formula presented) and GaAs single heterostructure. PL of (Formula presented) was observed when photoexciting the (Formula presented) interface. The anti-Stokes PL intensity from the (Formula presented) layer is about 1% of the GaAs PL. The observed anti-Stokes PL exhibits a characteristic intensity dependence in the double-logarithmic plot, which reveals two straight lines having slopes of about 2 and 4. Time-resolved measurements show that the anti-Stokes PL is described by two components: the rapid decay caused by the two-step two-photon absorption of the excitation laser light and the slower decay by energy transfer of electron-hole recombination energy in the GaAs. We found that many-particle effects in the GaAs under high excitations cause the characteristic intensity dependence of the anti-Stokes PL. © 1999 The American Physical Society.
1999, Physical Review B - Condensed Matter and Materials Physics, 59 (23), 15358 - 15362, English[Refereed]
Scientific journal
We investigated up-converted photoluminescence (UPL) in long-range ordered (Al0.5Ga0.5)0.5In0.5P grown on GaAs (115) A and GaAs (001). A multidomain structure of the ordered epitaxial film, each domain having its own order parameter, causes a band gap fluctuation. This enhances a localization of excited carriers from the GaAs layer. The UPL intensity excited at 1.83 eV depends nonlinearly on the excitation-laser power. It was found that an excitation-power dependence of the normal PL intensity excited by an above-gap light (2.54 eV) agrees well with those of the UPL at 11 K. However, at elevated temperatures, the excitation-power dependence of the normal PL intensity becomes linear. These results suggest that the nonlinear dependencies of the UPL intensity at low temperature closely relate to localization properties of photoexcited carriers. Furthermore, we observed band-filling effects on UPL under an irradiation of the above-gap light. © 1998 American Institute of Physics.
American Institute of Physics Inc., 01 Jul. 1998, Journal of Applied Physics, 84 (1), 359 - 363, English[Refereed]
Scientific journal
Up-converted photoluminescence (UPL) signal of long-range ordered (Al0.5Ga0.5)0.5In0.5P/GaAs(001) was observed around 2.18 eV at 11 K. Excitation-power dependence of the intensity obeys a power law with a slope 1.3. The power of slope is the same as that of normal photoluminescence (NPL) intensity. On the other hand, the NPL intensity measured at an elevated temperature shows a linear response. These results suggest that the low temperature UPL depends on carrier-localization properties. Time-resolved UPL measurements show a steep rise at the higher energy side and a slow rise at the lower energy side. This result reveals a relaxation process of the photoexcited carriers from higher lying states to lower lying states.
1998, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 521 - 524[Refereed]
International conference proceedings
Circularly polarized excitation light produces spin-polarized excitons in long-range ordered Ga0.5In0.5P, because of a splitting at the valence-band maximum. We observed the spin relaxation process in ordered Ga0.5In0.5P under resonant excitation of heavy-hole excitons. The circularly polarized exciton luminescence shows a maximum anisotropy of about 35%. The decay profile of the depolarized luminescence is described by two components; the rapid decay by exciton-relaxation processes and the slower exciton recombination. An excitonic spin-relaxiation process occurres during the initial rapid decay.
1998, Conference Proceedings - International Conference on Indium Phosphide and Related Materials, 525 - 528[Refereed]
International conference proceedings
The growth mechanism of diamond films from low pressure vapor phase synthesis can not be illustrated with classical thermodynamic theory. Up to now, a lot of growth methods were reported, but the growth mechanism was not so clear. In this paper, a variety of growth methods and growth conditions were summarized, and some tries to illustrate the growth mechanism of diamond film from the consideration of quantum mechanics bond theory were carried out. Particularly, some effects of atomic H and SP3 bond on the growth mechanism of diamond film were illustrated.
1998, Proceedings of SPIE - The International Society for Optical Engineering, 3175, 465 - 469, English[Refereed]
International conference proceedings
Circularly polarized excitation light produces spin-polarized excitons in long-range ordered (Formula presented) because of a splitting at the valence-band maximum. We observed the spin-relaxation process in ordered (Formula presented) under resonant excitation of heavy-hole excitons. The circularly polarized exciton luminescence shows a maximum anisotropy of about 53%. The decay profile of the polarized luminescence is described by two components: the rapid decay by exciton-relaxation processes and the slower exciton recombination. The relaxation of the exciton-spin polarization obeys a decay with a time constant of 105 ps. © 1998 The American Physical Society.
1998, Physical Review B - Condensed Matter and Materials Physics, 57 (24), R15044 - R15047, English[Refereed]
Scientific journal
Current transport properties of thin Ag-SiO2 granular films were studied. In spite of very simple device structures (i.e., just sandwiching the granular film with Al electrodes), clear Coulomb blockade and Coulomb staircase structures were observed in the current-voltage (I-V) characteristics. The observed I-V characteristics were qualitatively explained by a double-barrier and a triple-barrier tunnel-junction model. © 1998 Academic Press Limited.
Jan. 1998, Superlattices and Microstructures, 23 (1), 173 - 176[Refereed]
Scientific journal
Structural phase transition of epitaxial growing layer is quite important to understand the atomic scale mechanism of molecular beam epitaxy (MBE). GaAs and related alloy semiconductors are typical systems which show variety of such structural transitions during MBE. Structural evolution of surface reconstruction phases and an order-disorder transition in III-V alloy semiconductors are typical cases where such phase transitions appear during epitaxial processes. In this work, a stochastic theory and the Monte-Carlo simulation have been presented to describe the structural evolution of epitaxial growth in binary system. This method, known here as the 'Monte-Carlo master equation (MCME) method', couples a master equation for epitaxial growth kinetics with an Ising Hamiltonian of growing surface. The Monte-Carlo (MC) simulation of binary growing surface with atom-correlation effects has successfully revealed the evolution of atomic structure and the formation of short-range ordering (SRO) during epitaxy. This demonstrates the usefulness of the MCME method in describing the atomic-structural dynamics as compared with a conventional theory of epitaxy based on a diffusion equation and standard nucleation theory.
Elsevier, 1997, Applied Surface Science, 113-114, 631 - 637, English[Refereed]
Scientific journal
We have investigated photoluminescence of long-range ordered ((Formula presented) P grown by metalorganic vapor-phase epitaxy on GaAs(001) and GaAs(115)A. Photoluminescence spectra were measured as functions of temperature and delay time. The fundamental edge luminescence from ((Formula presented) P on GaAs(001) shifts to the lower-energy side about 120 meV at 11 K due to the long-range ordering, relative to the luminescence from the Γ conduction-band valley in the disordered alloy. The Γ luminescence of ((Formula presented) P appears at lower energy than the indirect luminescence from the X valley. These observations give clear evidence that the ordering causes the band gap to change from indirect to direct. In the temperature dependence of the photoluminescence (PL) peak energy, there are three regions divided by a local minimum and a local maximum. Below the temperature showing the local minimum, the temperature dependence of the PL intensity is characteristic of the localization of photoexcited carriers. The origin of the localization is the band-gap fluctuation. The temperature dependence of the PL intensity shows thermal activation between the temperatures showing the local minimum and the local maximum in the PL energy. The activation energy is proportional to the energy shift at the local minimum. In time-resolved PL measurements at low temperatures, we observed a delayed emission due to the electrons trapped at metastable states. The delayed component was only observed below 15 K and the delay time varies with temperature. © 1997 The American Physical Society.
1997, Physical Review B - Condensed Matter and Materials Physics, 55 (7), 4411 - 4416, English[Refereed]
Scientific journal
The optical processes in AlInP/GaInP/AlInP quantum wells free from long-range ordering are examined by photoluminescence (PL), photoluminescence excitation (PLE), and photoreflectance (PR) measurements. The PL method observes lower transition energy than the PLE and the PR methods which observe the space-averaged transition energy. This is because PL originates from localized lower-energy states to which an exciton state relaxes. By analyzing these measurements carried on 20- and 60-Å-wide wells, the reason for this deviation is ascribed to the fluctuation of the transition energy due to the local variation of the well width by one molecular layer. The plausible share of the band offset for the conduction band against the energy gap difference at the Γ point is obtained by comparing the experimentally obtained relative position of the energy levels in AlInP barriers and the 20 Å GaInP well with the calculated ones. This is found to be 0.75 (±0.06). © 1996 American Institute of Physics.
15 Oct. 1996, Journal of Applied Physics, 80 (8), 4592 - 4598[Refereed]
Scientific journal
Ordering-induced higher-interband transitions in long-range ordered (Formula presented)(Formula presented)P alloys have been investigated by electroreflectance-polarization spectroscopy. Energy positions of the (Formula presented) transitions show strong order-parameter dependencies together with changes in their signal intensities. For the (Formula presented) transitions, we resolved three components two components shift to the lower-energy side with increasing order parameter, and the other one shifts to the higher-energy side. The (Formula presented)+(Formula presented) edge also shifts to the lower-energy side with increasing order parameter. For the (Formula presented) transitions strong change was found in its oscillator strength. In the [1¯11]-CuPt ordering in (Formula presented)(Formula presented)P, the (Formula presented) of the high-symmetry point of the zinc-blende Brillouin zone folds into the Γ¯ point in the reduced superlattice symmetry. The other three zinc-blende L points and three X points fold into the D¯ point in the reduced symmetry. Interactions in the superlattice-Brillouin zone cause such variations in the (Formula presented) and (Formula presented) transitions. The ordering-induced evolution of the transition energy is consistent with the recent theoretical prediction. © 1996 The American Physical Society.
1996, Physical Review B - Condensed Matter and Materials Physics, 54 (23), 16714 - 16718, English[Refereed]
Scientific journal
P alloys naturally constitute monolayer superlattices on GaAs(001) substrates by atomic ordering when they are grown by organometallic vapor-phase epitaxy. The spontaneous long-range ordering causes the band-gap reduction and band splitting at the valence-band maximum. When the Al composition in a ((Formula presented)(Formula presented)(Formula presented)(Formula presented)P-random alloy is larger than ∼0.4, the optical transition is indirect, and the conduction-band minimum is at (Formula presented). From electroreflectance and photoluminescence measurements, we have found for long-range ordered ((Formula presented)(Formula presented)(Formula presented)(Formula presented)P that the (Formula presented) valley crosses the (Formula presented) by the band-gap reduction. The emission from the strongly ordered alloy is optically direct. The temperature dependence of photoluminescence intensity shows that statistical potential fluctuations and localized states in the low-energy part of the exciton resonance play an important role in the direct luminescence of the long-range ordered ((Formula presented)(Formula presented)(Formula presented)(Formula presented)P. © 1996 The American Physical Society.
1996, Physical Review B - Condensed Matter and Materials Physics, 53 (23), 15713 - 15718, English[Refereed]
Scientific journal
This study is focused on photocurrent (PC) responses in the monolayer superlattices (MSLs) of long-ranged ordered Ga0.5In0.5P alloys and measured a temperature dependence of their polarization. Discussed is the differentiated PC spectra for the [110] and [11̄0] polarizations. The samples used in the experiment were ordered Ga0.5In0.5P alloys grown on an exact n+-GaAs(001) substrate by OMVPE.
American Inst of Physics, 03 Apr. 1995, Applied Physics Letters, 66 (14), 1794 - 1796, English[Refereed]
Scientific journal
We have performed electroreflectance measurements on a five-period In0.24Ga0.76As(3 nm)/GaAs(10 nm) strained-layer superlattice as a function of electric field. The applied electric field was exactly determined by the Franz-Keldysh oscillation of GaAs. We have resolved transitions between electrons confined in the In0.24Ga0.76As layer and light holes localized in the adjacent layers. The type-II Stark-ladder transitions are clearly observed. The observed field evolution of the transition energy shows a nonlinear behavior originating from an anticrossing by coupling resonantly between the first light-hole subband and unconfined energy states of light holes. © 1994 The American Physical Society.
1994, Physical Review B, 50 (4), 2420 - 2424, English[Refereed]
Scientific journal
Subsurface lattice defects in silicon induced by ion implantation were studied by the use of the photo-acoustic displacement (PAD) method based on the sensitive measurements of the surface displacement due to the absorption of laser-light energy. A definite correlation between PAD and displaced atoms density (DAD) was found because PAD reflects the change in thermal conductivity associated with the net amount of displaced atoms in the crystal lattice beneath the surface. According to the linear dependence of 1/PAD on DAD, defects below a DAD of 1014/cm2 (corresponding to implant doses of 2×1011, 8×1010, and 6×1010 ions/cm2 for 100 keV B+, P+, and As +, respectively) were concluded to be point defects. After the DAD reached 1014/cm2, the PAD showed a gentle increase, and this can be attributed to the growth of point-defect clusters. A marked dependence of the PAD on the DAD was not observed beyond a DAD of 10 16/cm2. In this region, the presence of an amorphous layer was observed by cross-sectional transmission electron microscopy. Annealing behavior due to low-temperature heating was studied by the change in temperature dependence curves of the PAD, and the results reflected the characteristics of the defects described above.
1994, Journal of Applied Physics, 76 (10), 5681 - 5689, English[Refereed]
Scientific journal
The electronic structure of n-Al0.28Ga0.72As/In0.23Ga0.77As/GaAs has been investigated by photoluminescence (PL) and photoreflectance (PR) spectroscopies. Transitions associated with the $n{=}1$ and 2 electron subbands in the In0.23Ga0.77As single quantum well were observed. Two-dimensional carrier density was evaluated in terms of the quantum confined Franz-Keldysh (FK) effect of the transition between the lowest states of electrons and heavy holes. Because of penetrations of the confined electron density into the neighboring layers, PR spectra of GaAs show FK oscillation.
The Japan Society of Applied Physics, 20 Jun. 1992, Jpn J Appl Phys, 31 (6), L756 - L758, English[Refereed]
We have investigated polarized optical gain of columnar quantum dots by using variable stripe length method. The columnar QDs were grown by closely stacking the Stranski-Krastanow-mode InAs-island layers. The aspect ratio of the QD can be controlled by changing in the stacking layer number (SLN). The optical gain sensitively depends on the SLN. With increasing the SLN, the TM-sensitive optical gain has been demonstrated. Furthermore, we obtained almost polarization insensitive optical gain for the sample with seven staking layers.
The Institute of Electronics, Information and Communication Engineers, 26 Jan. 2006, Technical report of IEICE. LQE, 105 (593), 35 - 38, JapaneseWe have investigated polarization of photoluminescence (PL) emission from the cleaved-edge surface of a wafer involving InAs self-assembled quantum dots (QDs) capped by In_xGa_<1-x>As layer. With increasing indium (In) composition x in the capping layer, the PL of QDs shifts toward the longer wavelength side and shows an enhancement of the TM-mode PL intensity at x =0.13. In order to investigate effects of light propagation on the PL polarization, we have compared electroluminescence (EL) with PL spectra and investigated the PL excitation-wavelength dependence of the PL polarization.
The Institute of Electronics, Information and Communication Engineers, 11 Dec. 2003, Technical report of IEICE. LQE, 103 (526), 5 - 8, JapaneseWe investigated excitonic luminescence from CdTe/Cd_<0.74>Mg_<0.26>Te quantum wires (QWRs) grown on vicinal substrates. The temperature dependence of the radiative lifetime of one-dimensional (1D) exciton in the QWRs was measured by using time-resolved spectroscopy, and is compared with that of two-dimensional (2D) exciton in CdTe/Cd_<0.74>Mg_<0.26>Te quantum well (QW). The radiative lifetime in the QWRs and the QW increase with T and show a clearly different behavior. The observed radiative lifetime in the QWRs and QW are expressed as 100 T^<1/2> psK^<-1/2> and 11 T psK^<-1> respectively. At low temperature < 10K, however, the radiative lifetimes deviate from the T^<1/2> dependence. In this temperature region, a new PL peak appears at the lower energy side of the exciton PL. This low energy PL peak is enhanced under a high excitation. By analyzing the PL spectra and the PL decay profiles, we discuss the origin of the new PL signal.
The Institute of Electronics, Information and Communication Engineers, 04 Oct. 2001, IEICE technical report. Electron devices, 101 (337), 13 - 18, JapaneseWe have studied initial stages of self-assembled growth of InAs quantum dots by reflectance-difference (RD) spectroscopy and photoluminescence (PL). The PL of the 1 monolayer quantum-well exciton under the low excitation power exhibits a doublet feature having an energy separation of similar to 20 meV. This separation corresponds to an energy shift by the lattice mismatch strain. In-situ RD spectra monitoring the growth indicate a structural change of the wetting layer after 1 monolayer deposition of InAs. These findings demonstrate a formation of precursor before the growth-mode transition.
IOP PUBLISHING LTD, 2000, COMPOUND SEMICONDUCTORS 1999, (166), 239 - 242, EnglishThe initial stages of self-organized InAs-dot formation on GaAs(001) have been investigated by reflectance-difference (RD) spectroscopy and reflection high-energy electron diffraction. The RD spectrum changes drastically at an InAs coverage of 0.1 monolayer (ML), which corresponds to a phase transition from the c(4x4) of the As-rich GaAs(001) to the (2x3) surface reconstruction. The RD signal at 2.56 eV is enhanced after 1.0-ML deposition of InAs. No significant change in the RD signal was observed at the onset of dot formation. Thus, the enhancement of the RD intensity at the 1.0-ML coverage indicates a phase transition of the wetting layer just before the dot formation. Furthermore, thermal annealing effects for the InAs dot structure are discussed.
IOP PUBLISHING LTD, 1999, COMPOUND SEMICONDUCTORS 1998, (162), 457 - 462, EnglishOthers
Ordering-induced higher-interband transitions in long-range ordered Ga0.5In0.5P alloys have been investigated by electroreflectance-polarization spectroscopy. Energy positions of the E(1) transitions show strong order-paratneter dependencies together with changes in their signal intensities. For the E(1) transitions, we resolved three components: two components shift to the lower-energy side with increasing order parameter, and the other one shifts to the higher-energy side. The E(1)+Delta(1) edge also shifts to the lower-energy side with increasing order parameter. For the E(2) transitions strong change was found in its oscillator strength. In the [(1) over bar 11]-CuPt ordering in Ga0.5In0.5P, the L((1) over bar 11) of the high-symmetry point of the zinc-blende Brillouin zone folds into the <(Gamma)over bar> point in the reduced superlattice symmetry. The other three zinc-blende L points and three X points Fold into the (D) over bar point in the reduced symmetry. Interactions in the superlattice-Brillouin zone cause such variations in the E(1) and E(2) transitions. The ordering-induced evolution of the transition energy is consistent with the recent theoretical prediction.
AMERICAN PHYSICAL SOC, Dec. 1996, PHYSICAL REVIEW B, 54 (23), 16714 - 16718, EnglishPhotocurrent anisotropy of long-range ordered Ga0.5In0.5P alloys has been systematically investigated. The ordered Ga0.5In0.5P is a compositional modulated superlattice of Ga0.5+eta/2In0.5-eta/2P and Ga0.5-eta/2In0.5+eta/2P monolayer planes, where eta is a long-range order parameter. The photocurrent edge of the [110] polarization is lower than that of the [1(1) over bar0$]. The observed anisotropy in the photocurrent spectra is due to a crystal-field splitting at the valence-band maximum in ordered Ga0.5In0.5P. The anisotropy shows a continous variation as a function of eta. In order to make clear the effects of the valence-band splitting on the polarized photocurrent spectra, we performed theoretical calculations in which a distribution of eta in the epitaxial film and an order-parameter dependence of oscillator strength were considered. From these calculations, it is found that oscillator strength is a key parameter in the anisotropic character. The calculated results moderately agree with the measured data. Furthermore, the epitaxial thickness dependence of the anisotropic character in photocurrent was investigated.
MINERALS METALS MATERIALS SOC, Apr. 1996, JOURNAL OF ELECTRONIC MATERIALS, 25 (4), 661 - 665, EnglishThe band-A luminescence of diamond films was systematically investigated by cathodoluminescence spectroscopy. Diamond films were grown on scratched p-type Si(001) substrate by microwave-plasma-enhanced chemical vapor deposition. Films of 3 mu m thickness were grown at 880 degrees C using 2% CH4 gas. The intensity of the band-A luminescence modulated by chopping the electron beam and detected using a lock-in detector was found to decrease with increasing modulation frequency. According to an analysis of the signal at the lock-in output, the lifetime is about 1.5 ms. With increasing excitation-electron energy it was found that the peak energy shifts to the higher energy side. Since an increase of the electron energy corresponds to an increase of the probe depth, the observed blue shift indicated that the separation of donor-acceptor pair is larger at the film surface than at the interface on the substrate. It was considered that the film thickness dependence of this emission correlates with the formation of facets at the initial growth stage and their subsequent growth.
MYU K K, 1996, DIAMOND FILMS AND TECHNOLOGY, 6 (3), 139 - 145, EnglishThe electronic coupling between a In0.21Ga0.79As single quantum well (SQW) and GaAs barriers is manifested in electroreflectance (ER). The applied electric field was exactly determined by the Franz-Keldysh oscillation of GaAs. Er spectra display an influence of electric field on optical transition strength. The transition intensity relating to the first electron subband shows a dramatic enhancement at 27 kV/cm. The energy states for electrons in the GaAs/In0.21Ga0.79As/GaAs SQW strongly couple with a continuum state via tunneling under the electric field built into this structure.
ACADEMIC PRESS (LONDON) LTD, 1994, SUPERLATTICES AND MICROSTRUCTURES, 15 (2), 137 - 140, EnglishWe have performed electroreflectance spectroscopy on a 5-period In_0.26>Ga_0.76>As(3nm), GaAs(10nm) strained layer superlattice as a function of electric field.The applied electric field was exactly determined by the Franz-Keldysh oscillation of GaAs.We have resolved transitions between electrons confined in the In_0. 26>Ga_0.76>As layer and light holes localized in the adjacent layers.The type-II Stark-ladder transitions are clearly observed. The observed field evolution of the transition energy shows a nonlinear behavior originating from an anticrossing by oupling resonantly between the first light-hole subband and vertual energy states of light holes.
The Institute of Electronics, Information and Communication Engineers, 19 Nov. 1993, IEICE technical report. Electron devices, 93 (326), 49 - 52, JapaneseScholarly book
Scholarly book
Scholarly book
Scholarly book
Scholarly book
Scholarly book
Scholarly book
Oral presentation
[Invited]
Invited oral presentation
[Invited]
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
[Invited]
Invited oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Poster presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
[Invited]
Invited oral presentation
[Invited]
Invited oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Invited oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Invited oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Invited oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
[Invited]
Invited oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
[Invited]
Invited oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Poster presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
[Invited]
Invited oral presentation
Oral presentation
Poster presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Poster presentation
Poster presentation
[Invited]
Invited oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Oral presentation
Others
Others
Others
日本物理学会
Oct. 1986 - Present応用物理学会
May 1985 - PresentSpring-8利用者懇談会正会員
May 1993 - Mar. 1999日本真空協会
Jul. 1993 - Dec. 1997日本金属学会
Jul. 1992 - Dec. 1997Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
We have studied the epitaxial growth and characteristics of InAs/GaAsSb type-II quantum dot (QD) superlattice and used it to fabricate an intermediate band (IB) solar cell, which is expected to exhibit a high efficiency. First, we have succeeded to observe a clear photocurrent production by 2-step photoabsorption process at room temperature owing to longer carrier lifetimes in type-II QDs. This effect has resulted in an improvement of short-circuit current and efficiency in IB solar cells. Second, we have studied the carrier dynamics in QD structures by ultra-fast optical spectroscopy and clarified the fundamental carrier relaxation process in direct Si-doped QDs. Third, we have studied the optical modes of emission from QD superlattice structure and showed that TM mode starts to increase in proportion to TE mode for a structure with sub-10nm spacing between QD layers indicating a clear formation of QD superlattice miniband, which is required for IB solar cells.
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Competitive research funding
Recent advance in high-quality self-assembled QDs contributes to the development of new optical devices such as QD semiconductor optical amplifiers (SOAs). For practical applications, control of the polarization property is prerequisite for developing polarization-independent SOAs. To accomplish the polarization insensitive bandedge, we propose a new approach using shape-controlled QDs. In closely stacked Stranski-Krastanov (S-K)-mode InAs QDs, namely, columnar QDs, the height has been successfully controlled, artificially, by stacking the S-K-mode growth layer, which can change the quantum-confinement direction. SOA structures with columnar QDs were grown by molecular beam epitaxy. The islands on each layer were observed to be in contact with each other in the perpendicular direction, so that the stacked island structure, as a whole, becomes columnar in shape. The diameter of the columnar QDs is about 17 nm. The height was controlled by the stacking layer number (SLN). The typical height for the SLN of 8 is about 13 nm. Linear-photoluminescence (PL) polarization spectra were measured from a cleaved, uncoated edge surface of the sample. The TE (TM)-mode PL was measured by setting an analyzer along the in-plane (growth) direction. Polarization insensitivity of semiconductor optical amplifier has been shown to be precisely controlled in closely stacked InAs/GaAs self-assembled quantum dots. The polarization insensitive bandwidth achieved is larger than 40nm. These results demonstrate that wideband polarization insensitivity has been accomplished by controlling QD shape.
Quantum dots are expected to play a key role in future optical communications due to their advantages in enhancing linear optical gain and nonlinear optical response, as well as ultrafast response speed, which result from the three dimensionally confined electron states. However, quantum dots formed by SK-mode growth have flattened shape much different from the ideal sphere, and this causes polarization sensitiveness, usually being heavily TE-polarized, and also there are no precise understanding of the effect of dot shape on the optical response speed and nonlinearity. In this study, it has been shown from polarization discriminating photoluminescence measurements that the polarization property can be controlled by optimizing the dot shape using columnar dot structure, in which SK-dot layers are stacked. Also it has been shown that the polarization properties are controlled by changing the composition of InGaAs capping layer on InAs dots primarily due to the effect of dot aspect ratio, which is enhanced by the introduction of InGaAs capping layer resulting in TM dominant polarization. This indicates that the polarization insensitiveness, which is one of the most important device characteristics in practical application, can now be controlled by designing the dot shape. Our previous results have demonstrated that quntum dot optical amplifier exhibits ultrafast absorption recovery time in the range of 1-3 ps. Also it has been shown from degenerate four-wave mixing (DFWM) experiments that large size dots show phase relaxation time larger that that for small size dots, indicating the possibility of enhanceing nonlinearity in larger dots. Combining all these results obtained, it is concluded that polarization insensitive, ultarafast and high-nonlinearity optical response can be simultaneously achieved by adopting isotropically shaped, large size dots.
UVB領域の紫外発光蛍光体および紫外発光デバイス
特願2018-82670, 23 Apr. 2018, 特開2019-189722, 31 Oct. 2019, 特許7030333, 25 Feb. 2022Patent right
紫外発光蛍光体と紫外発光デバイス及び紫外発光蛍光体の作製方法
特願2017-25385, 14 Feb. 2017, 特許6955656, 06 Oct. 2021Patent right
電池、水素光合成装置および炭素化合物光合成装置
特願2017-26222, 15 Feb. 2017, 特許6900024, 18 Jun. 2021Patent right
量子型赤外線センサ
特願2019-138335, 26 Jul. 2019, 特開2021-22662Patent right
高変換効率太陽電池およびその調製方法
特願2014-113313, 30 May 2014, 大学長, 特許6385720, 17 Aug. 2018Patent right
紫外発光デバイス及び紫外蛍光体の作製方法
特願2016-026434, 15 Feb. 2016Patent right
深紫外半導体光デバイス(韓)
10-2010-7007275, 03 Sep. 2008, 大学長, 10-1478391, 24 Dec. 2014Patent right
蛍光体結晶薄膜とその作製方法
特願2011-521822, 07 Jul. 2010, 大学長, 特許5476531, 21 Feb. 2014Patent right
量子ドットの形成方法及び半導体装置の製造方法
特願2008-200251, 01 Aug. 2008, 大学長, 特許5102141, 05 Oct. 2012Patent right
半導体装置及び半導体装置の製造方法
特願2012-198903, 10 Sep. 2012Patent right
有機フィールドエミッションデバイス
特願2006-088557, 28 Mar. 2006, 大学長, 特許5011523, 15 Jun. 2012Patent right
電子放出装置
2007-157877, 14 Jun. 2007, 大学長, 特許4822549, 16 Sep. 2011Patent right
深紫外蛍光薄膜および深紫外蛍光薄膜を用いたランプ
特願2008-79820, 26 Mar. 2008, 特開2009-238415, 15 Oct. 2009Patent right
応力測定装置
特願平10-97530, 09 Apr. 1998, 特許第3979611号, 06 Jul. 2007, 19 Sep. 2007Patent right
量子光半導体装置
2002-273178, 19 Sep. 2002, 2004-111710, 08 Apr. 2004, 特許第3854560号, 15 Sep. 2006Patent right
半導体の接合容量評価方法及び接合容量測定装置
特願2001-310782, 05 Oct. 2001, 18 Apr. 2003, 10 Mar. 2006, 特許第3777394号Patent right
量子ドット半導体素子及び該製造方法並びに量子ドット半導体素子を用いた量子ドット半導体レーザ、光増幅素子、光電変換素子、光送信機、光中継機及び光受信機
特願2003-181776, 25 Jun. 2003, 特開2005-19654, 20 Jan. 2005Patent right
β-FeSi2とその製造方法及びβ-FeSi2を含む半導体集積回路
特願2001-189001, 22 Jun. 2001Patent right